Exhumation of high-pressure rocks of the Kokchetav massif: facts and models

The exhumation of ultrahigh-pressure (UHP) metamorphic units from depths more than 100-120 km is one of the most intriguing questions in modern petrology and geodynamics. We use the diamondiferous Kumdy-Kol domain in the Kokchetav Massif to show that exhumation models should take into consideration initially high uplift velocities (from 20 down to 6 cm/year) and the absence of the deformation of UHP assemblages. The high rate of exhumation are indicated by ion microprobe (SHRIMP) dating of zircons from diamondiferous rocks and supported by the low degree of nitrogen aggregation in metamorphic diamonds.Diamondiferous rocks in the Kumdy-Kol domain occur as steeply dipping (60°-80°) thin slices (few hundred metres) within granite-gneiss. Using geological, petrological and isotopic-geochemical data, we show that partial melting of diamondiferous metamorphic rocks occurred; a very important factor which has not been taken into account in previous models.Deformation of diamondiferous rocks at Kumdy-Kol is insignificant; diamond inclusions in garnet are often intergrown with mica crystals carrying no traces of deformation. All these facts could be explained by partial melting of metapelites and granitic rocks in the Kumdy-Kol domain. The presence of melt is responsible for an essential reduction of viscosity and a density difference (Δρ) between crustal rocks and mantle material and reduced friction between the upwelling crustal block, the subducting and overriding plates. Besides Δρ, the exhumation rate seems to depend on internal pressure in the subducting continental crustal block which can be regarded as a viscous layer between subducting continental lithosphere and surrounding mantle.We construct different models for the three stages of exhumation: a model similar to “corner flow” for the first superfast exhumation stage, an intermediate stage of extension (most important from structural point of view) and a very low rate of exhumation in final diapir+erosional uplift.     

Geology and geochemistry of archaean felsic metavolcanic rocks of the Eastern Part of the Kolar greenstone belt, Dharwar craton, India: Implications for their petrogenesis and geodynamic setting

In the Kolar greenstone belt of the Dharwar craton, felsic metavolcanics are encountered prominently in its eastern region around Surapalli and Marikoppa. These felsic volcanic rocks are essentially homogeneous and their bulk mineralogy is almost the same. They consist of phenocrysts of quartz and feldspar, set in a fine-grained quartzo-feldspathic groundmass. They are calc-alkaline rhyolite in composition, and are characterized by high SiO₂ (av. 75.74 wt.%), moderate Al₂O₃ (av. 11.84 wt.%), Na₂O (av. 3.55 wt.%), K2O (av. 3.26 wt%) contents and low Mg# (av. 6.07), Cr (av. 8 ppm), Ni (av. 8 ppm), Sr (av. 331 ppm.), Y (av. 7 ppm), Yb (av. 0.87 ppm) and Nb/Ta (av. 6.40) values, suggesting Tonalite-Trondhjemite-Granodiorite (TTG) affinity for these felsic volcanics. They are strongly fractionated [(La/Yb)_N? = 14.41–48.70] with strong LREE enrichment [(La/Sm)_N = 2.50-3.59] and strong HREE depletion [(Gd/Yb)_N = 1.34–2.77] with positive Eu anomaly. The regional geological set-up, petrographic and geochemical characteristics suggest that these felsic volcanics probably were derived by partial melting of a subducting basalt slab at shallow depth without much involvement of mantle wedge in an island arc geodynamic setting.     

On cumulus-scale transport of horizontal momentum in monsoon depression over India

A diagnostie method of cumulus parameterization is suggested in which vertical transport of horizontal momentum by cumulus-scale is derived by making use of large-scale vorticity as well as divergence budget equations. Data for composite monsoon depression over India available from our earlier studies used to test the method. As a first approximation, the results are obtained using only the vorticity budget equation.The results show that in the southwest sector of the monsoon depression, which is characterized by maximum cloudiness and precipitation, there is an excess of cyclonic vorticity in the lower troposphere and anticyclonic vorticity in the upper troposphere associated with the large-scale motion. The distribution of eddy vertical transport of horizontal momentum is such that anticyclonic vorticity is generated in the lower troposphere and cyclonic vorticity aloft. Cumulus-scale eddies thus work against the large-scale system and tend to off-set the large-scale imbalance in vorticity.     

The use of integrated circulation index for the description of synoptic situations in the Pacific Ocean tropics during El Niño-Southern Oscillation extreme events

The potential of Petrosyants-Gushchina integrated circulation index in respect to the problem of synoptic analysis in low latitudes is considered. The compositional models of synoptic situations, which led to the formation of extreme conditions in weather and climate over the Pacific Ocean, are constructed using the computed indices according to the data of NCEP/NCAR reanalysis for 1950–2002 separately for El Niño and La Niña events. It is demonstrated that the barometric circulation pattern of synoptic processes in tropics, being reproduced using indices, indicates the main peculiarities of atmospheric circulation in low latitudes and can be the quantitative indicator of the whole circulation system of El Niño-Southern Oscillation over the Pacific Ocean.     

Variability of sediment diatom assemblages in an upland,wind-stressed lake (Loch Fleet,Galloway, S.W. Scotland)

The variability of diatom distribution in an acidified, upland wind-stressed lake (Loch Fleet, Galloway, S. W. Scotland) was assessed by analysis of 28 surface sediment samples and 11 cores. Correspondence analysis (CA) and cluster analysis were used to illustrate the variability of the surface sediment and core samples. There was reasonable uniformity of taxa in most of the surface sediment samples, although 7 samples, as indicated by both CA and cluster analyses were atypical. Most cores recorded clearly the acidification of the lake, although percentages of individual taxa varied up to 20% between cores. Two cores had old, preacidification diatom assemblages (of indeterminate age) close to the sediment surface. These old sediments were probably the source of the re-worked diatoms found in the atypical surface sediment assemblages. Diatom trends, as CA ordinations and pH profiles, were less variable than the surface sediment assemblages. It is argued that non-uniform sediment accumulation rates and diatom deposition cause variability in surface sediment diatom samples. This variability may be reduced in core profiles by homogenization during further resuspension/deposition cycles and burial. Cores, and the associated time component they offer, may be useful in assessing the variability of surface sediment assemblages.     

Derivation of density and temperature from the Cassini–Huygens CAPS electron spectrometer

In this paper we present two methods to derive electron fluid parameters from the CAPS–ELS spectrometer on board the Cassini spacecraft currently in orbit around Saturn. In the first part of the paper we give a basic overview of the instrument and describe the challenges inherent in the derivation of density and temperature values using these techniques. We then describe a method to calculate electron moments by integrating the particle distribution function. We also describe a second technique in which we fit the electron energy spectrum with a Gaussian curve and use the peak energy of this curve to derive density and temperature values. We then compare the two methods with particular emphasis on their application to Cassini SOI observations in the saturnian environment and point out the limitations of the two techniques. We will show that results from the two very different methods are in agreement when the physical properties of the environment and of the observed electron populations have been inferred from inspection of the raw data. Finally we will suggest future developments that will remove these limitations.     

The influence of particle composition on thorium scavenging in the NE Atlantic ocean (POMME experiment)

²³⁰Th, ²³²Th and ²³⁴Th were analyzed in sinking particles collected by moored and drifting sediment traps in the NE Atlantic Ocean (POMME experiment) in order to constrain the phase(s) carrying Th isotopes in the water column. It reveals a contrasted behaviour between ²³⁴Th and ²³⁰Th. ²³⁴Th is correlated to the particulate organic carbon suggesting that it is primarily scavenged by organic compounds in the surface waters. ²³⁰Th_xs is correlated with Mn, Ba and the lithogenic fraction that are enriched in small suspended particles and incorporated in the sinking particulate flux throughout the water column. The lack of correlation between ²³⁰Th_xs and CaCO₃ or biogenic silica (bSi) indicates that CaCO₃ and bSi are not responsible for ²³⁰Th scavenging in the deep waters of this oceanic region. ²³⁰Th is generally correlated with the lithogenic content of the trapped material but this correlation disappears in winter during strong atmospheric dust inputs suggesting that lithogenic matter is not directly responsible for ²³⁰Th scavenging in the deep waters or that sufficient time is required to achieve particle–solution equilibration. MnO₂ could be the prevalent ²³⁰Th_xs-bearing phase. The narrow range of K_{d_MnO2}^Th obtained for very contrasted oceanic environments supports a global control of ²³⁰Th_xs scavenging by MnO₂ and raises the possibility that the ²³⁰Th–²³¹Pa fractionation is controlled by the amount of colloidal MnO₂ in seawater.     

Phosphorus transport in shallow groundwater in peri-urban Kampala, Uganda: results from field and laboratory measurements

To understand Phosphorus (P) sources and transport processes in the subsurface in Bwaise III Parish, Kampala, P attenuation and adsorption capacities of soils were studied in situ and from laboratory measurements. Relationships between sorption parameters and soil matrix properties, rates and mechanism of the adsorption process and soil P fractions were also investigated. P was generally higher in the wet than the dry season, but for both seasons, the maximum was 5 mgP/l. P transport mechanisms appeared to be a combination of adsorption, precipitation, leaching from the soil media and by colloids with the latter two playing an important role in the wet season. The sorption process comprised two phases with the first stage rate constants being about fourfold those of the second stage. The Langmuir isotherm described the sorption data well (R ² ≥ 0.95) with the second soil layer exhibiting the highest sorption maximum (C _max) (average value 0.6 ± 0.17 mgP/gDW). The best prediction of C _max had organic carbon, Ca, available P and soil pH. Residual P consisting mostly of organics was the main fraction in all the layers followed by inorganic HCl-P and NaOH-P in the top and middle layers, respectively. Loosely bound P (NH₄Cl-P) was the least fraction (<0.4% of total P) in all layers indicating the high binding capacity of P by the soils. The study results suggest that P dynamics is related to Ca, Fe and organic carbon content of the soils.     

Evaluating the effect of land development on sediment transport using a probability density function

An important problem in sedimentation analysis is the development of a channel section that preserves, as best as possible, the current sedimentation regime even though the flood frequency tendencies have been altered due to land development within the catchment. In order to accomplish this task, a methodology is needed that estimates sediment transport capacity for various channel configurations. Such a procedure is described which allows the computation of the total sediment transport capacity for each of several T-year return frequency runoff hydrographs. This information is used to obtain an approximate probability distribution for the total sediment transport capacity, and the mean and standard deviation of this distribution are computed.Comparing the results for the catchment in its present state with a future developed state, using a selection of new channel parameters, indicates how to improve the channel to control changes in sedimentation due to development. The analysis procedure provides a basis for estimating a new channel configuration such that the new flow conditions retain, as best as possible, the existing condition sedimentation effects, and hence retain the natural sediment supply and transport trends even though runoff flow rates have changed due to land development within the catchment.The results of Wilson Creek are typical of the several sites examined, see Table 3 below. The T=2, T=5, T=25, and T=100 year values for total sediment transport capacity, in kilotons, are 6.9, 39.4, 61.3, and 96.7 with a mean of 17.1 and standard deviation of 19.3. After development with no change in the channel the respective values increase to: 17.9, 84.6, 128.1, and 258.0 with a mean of 39.1 and standard deviation of 44.3. A new channel can be constructed which will reduce these sediment transport capacity values, after development, to 5.2, 41.0, 62.0, and 124.8 with a mean of 17.4 and standard deviation of 22.0.