Modal mineralogy of carbonaceous chondrites by X‐ray diffraction and Mössbauer spectroscopy

Abstract— Carbonaceous chondrites are among the most analyzed geological materials on Earth. However, despite this attention, and unlike most terrestrial rocks, little is known on the abundance of individual phases within them. Here, we show how a combination of several novel X‐ray diffraction (XRD) techniques (including a high‐brightness X‐ray MicroSource®), and Mössbauer spectroscopy, allows a complete modal mineralogy to be ascertained from even the most highly unequilibrated, fine‐grained chondrites for all minerals of abundance >1 wt%. Knowledge of the modal mineralogy of a sample also allows us to calculate grain density. We analyzed Allende, Murchison, Tagish Lake, and Orgueil. Based on our modal data, the grain density estimates for Allende, Murchison, and Orgueil are close to literature values. In the case of Tagish Lake, there is no published grain density, although a bulk density measurement does exist. Taking our estimate of grain density, and the measured bulk density, we calculate an exceptionally high porosity of 41% for this meteorite, similar to some chondritic IDPs and in line with a porosity calculated from an entry model for the Tagish Lake fireball. Although it is an oxidized CV, magnetite is present in Allende at a level of <0.5 wt% or <0.3 vol%, a result that is substantiated by several other instrumental studies. This may be an oxidized meteorite, but that oxidation is not manifested in abundant magnetite. In addition, we note appreciable fayalitic olivine in Orgueil, detected by both XRD and Mössbauer. We employed MicroSource® XRD to look at heterogeneity in mineral abundance in Orgueil and found substantial variation, with phyllosilicates varying inversely with olivine. The data suggest that Orgueil was initially composed primarily of anhydrous materials, which have been partially, but not completely, altered. Although the data are preliminary, comparison between our XRD modal assessment, bulk chemistry, grain density, and Mössbauer data, suggests that our estimates of mineral abundance are robust. The advent of MicroSource® XRD allows similar modal data to be acquired from samples as small as a few hundred micrograms.     

Ecological-geochemical assessment of the state of the Volga source of water supply to Moscow

Long-term observational data (1992?C2009) on heavy metal (Cu, Zn, Pb, Cr, Ni, V, Mo, Co, Fe, and Mn) content of different links in the Ivankovo Reservoir ecosystem are used to consider the regularities in the distribution and behavior of heavy metals in the system anthropogenic pollution sources-reservoir and its drainage area, thus enabling the assessment of the pollution level of the Volga Source of water supply to Moscow.     

Wave propagation in the quiet solar chromosphere

In order to precise previous results about wave propagation in the quiet chromosphere (N. Mein and P. Mein, 1976), we study the behaviour of Doppler shifts and intensity fluctuations in 3 lines of Ca ii. We use the same observation as in our previous work, that is to say a sequence of spectra lasting 27 mn, taken at Sacramento Peak Observatory solar tower. Results can be summarized as follows:

1. Phase-lag between intensity fluctuations and dopplershifts is always near 90° in the Ca ii lines, even for frequencies as high as 15 mHz, and whatever is the location in the chromospheric network.
2. Magneto-acoustic waves propagating vertically in a vertical or horizontal magnetic field could account for the observations only if they were, on one hand reflected in the upper atmosphere, on the other hand propagating with a very high sound or Alfvén speed. The lower limit for the speed (70 km s^-1) does not seem to be realistic. Oblique waves could be investigated for better agreement.

     

Photometric period and rotational brightness modulation of V833 Tau

Photometric data covering 1994–2009, obtained at the Crimean Astrophysical Observatory or retrieved from the ASAS and SuperWASP catalogs, were used to analyze the brightness variations of the rapidly rotating star V833 Tau, whose activity level is close to saturation. Combined with previously published results, these data represent for the first time all stages in the development of the star’s 19- year activity cycle. The photometric period and rotational-modulation amplitude for different epochs are determined, and the qualitative pattern of the spots is considered. The photometric period is close to the orbital period, but always exceeds it, indicating that surface inhomogeneities are located far from the equatorial plane. With the high spottedness of the star, reaching 28% at the cycle maximum, the rotationalmodulation amplitude is 0.05?0.1 ^m , and increases during the growth and decline phases of the 19-year cycle. The rotational modulation is due to spots with higher latitudes than in the case of the Sun, and concentrating on active longitudes.     

Facies Structure and Quantitative Parameters of Pleistocene Sediments of the Bering Sea

Lithofacies zoning is described for the first time for the Neo- and Eopleistocene of the Bering Sea. Four lithofacies sedimentation zones are distinguished: (I) terrigenous; (II) siliceous–terrigenous; (III) siliceous, and (IV) volcanoterrigenous ones. Corresponding maps were treated using Ronov volumetric method to quantify sedimentation parameters for distinguished lithofacies zones (subzones) and types of Pleistocene sediments. It was revealed that terrigenous sediments predominate over other sediments. Accumulation of the terrigenous sediments was more intense (by 1.4 times) in the Neopleistocene than in the Eopleistocene. The sedimentation rate of siliceous sediments of the Bowers Ridge in the Eopleistocene was two times higher than in the Neopleistocene.     

Archaeal Communities of Frozen Quaternary Sediments of Marine Origin on the Coast of Western Spitsbergen

Izvestiya, Atmospheric and Oceanic Physics - The archaeal composition of permafrost samples taken during the drilling of frozen marine sediments in the area of the Barentsburg coal mine on the east...     

Experiments on numerical modeling of intense convection

Results of numerical simulations using the WRF-ARW nonhydrostatic model are presented for eight episodes of intense convection over European Russia in the summer of 2007. The calculations were performed on four nested grids with horizontal grid meshes of 27, 9, 3, and 1 km. Convection was parametrized on the first two grids and explicitly resolved on the other two. It has been found that simulations on finer grids with explicit calculation of convective flows make it possible to reproduce heavy rainfalls and strong-wind zones in the areas of intense convection. A preliminary verification of the short-range predictions of convective systems shows that the maximum 12-h precipitation totals and the maximum winds at 10 m are close, in the order of magnitude, to the observed values. Prediction of convection centers is the weakest point. Difficulties in the model verification associated with the absence of data with high space-time resolution are discussed.