The distribution of oxygen and hydrogen sulfide in Black Sea waters during winter-spring period

Regularities of oxygen and hydrogen sulfide are examined, using the method of spatial isopycnic analysis. The contribution that ventilation of winter-time surface waters over the domes of cyclonic gyres makes to the transfer of O₂ towards the upper boundary of the constant pycnocline and to the oxicline layer is demonstrated. The paper provides spatial scales of this phenomenon and indicates the areas where the upper boundary of the anoxic layer in the Black Sea, relative to the conventional density, is located much higher compared with the rest of the sea. The suboxic zone is shown to be a specific feature of the O₂/H₂S distribution in the Black Sea waters, typical, at least, of the northern part of the basin. Analysis of the suboxic spatial variability in the vertical has been conducted. Translated by Vladimir A. Puchkin.     

Estimates of Extragalactic Background and Confusion Noise Parameters for the Millimetron Telescope

Astronomy Letters - The sensitivity of future far-infrared telescopes, such as Millimetron, will be limited by the confusion noise produced by distant galaxies. We have constructed a model of the...     

Metallothionein-like proteins induced by cadmium stress in the scallop Mizuhopecten yessoensis

Organisms have evolved a cellular response called stress protein response that increases their tolerance in adverse environmental conditions. Well known stress proteins that bind essential and toxic metals are metallothionein (MT). The scallop Mizuhopecten yessoensis is the most interesting organism because it is able to accumulate toxic cadmium in its digestive gland. However, in the tissue of the digestive gland of Mizuhopecten yessoensis MT (metallothioneins) have not been found. Eastern scallops, Mizuhopecten yessoensis, were collected from two locations ?? one clean and one polluted site. The concentrations of cadmium (Cd), copper (Cu) and zinc (Zn) were measured in the digestive gland. There was a significant increase in Cd concentrations in this studied tissue. We found that in the presence of cadmium Mizuhopecten yessoensis can induce high molecular proteins. The results of experiments have shown that Cd-binding ligands have a number of properties similar to MT: acetone and temperature stability; the ability to bind some metals, including Cd, Cu and Zn. Protein chromatography (FPLC, Superosa 12) from the digestive gland of scallop M. yessoensis has shown that cadmium is associated with high molecular weight Cd-binding proteins (72 kDa and 43 kDa). The major cadmium-binding protein 72 kDa is glycoprotein. In experiments we have demonstrated that Cd-binding proteins can be induced when there is cadmium exposure. The results of this study strongly suggest that the far eastern scallop Mizuhopecten yessoensis has a unique and well-developed system for the detoxification of heavy metals and it allows for biochemical systems to be maintained in a relatively stable manner in the presence of heavy metals.     

Evaluating the production and bio-stimulating effect of 5-methyl 1, hydroxy phenazine on microbial fuel cell performance

The role of endogenous redox mediators has considerable importance in electron shuttling reactions and associated performance of microbial fuel cell. Single-chamber microbial fuel cell-II with dual air-cathode assembly (area = 18.84 cm²) supported highest bacterial (Pseudomonas aeruginosa) density (6.7 × 10⁹) and active biomass [4.4 ± 0.3 mg cm^?2 (carbon content = 0.48 ± 0.1 mg cm^?2)] on anode thereby resulting in maximum production of redox metabolite, 5-methyl 1, hydroxy phenazine (301 ppm) and voltage (595 ± 5 mV) than similar cells with relatively less surface area of cathode. It was further revealed that 5-methyl 1, hydroxy phenazine production was positively correlated with chemical oxygen demand removal rate (77 ± 2.5%) and power generation (66.6 ± 2.2 mW cm^?2) efficiency of single-chamber microbial fuel cell-II. Maximum power density of 258 ± 4.5 mW cm^?2 was generated when reactor was supplemented with 2 ml crude extract of 5-methyl 1, hydroxy phenazine metabolite, whereas power output was about 229 ± 2.5 mW cm^?2 when reactor was bio-stimulated with 1 ml pure extract of 5-methyl 1, hydroxy phenazine. With this concentration, the electrochemical response of mixed culture biofilm (sediment) was enhanced by 99.3%. However, further increase in concentration of endogenous mediator proved to be limiting on reactor performance. Pyrosequencing and phylogenetic analysis on the basis of partial 16S rRNA sequences demonstrated both culturable and unculturable bacterial species in anodic biofilm and relative abundance of family Pseudomonadaceae was found to be maximum, i.e., 61.7% followed by Rhodocyclaceae 19.2%, Xanthomonadaceae 6.3% and Opitutaceae 3.18%.     

Diamond potential versus oxygen regime of carbonatites

Physicochemical conditions of graphite and diamond formation in the carbonate-rich melts were estimated. A large body of analytical data was obtained for compositions of coexisting minerals in the studied objects (Chernigovka Massif, Ukraine, and Chagatai carbonatite complex, Uzbekistan). The carbon isotopic composition of the coexisting carbonates and graphite from these carbonatites was analyzed. New thermodynamic methods were proposed to estimate the oxygen potential in graphite- and diamond-bearing carbonatites. Oxygen fugacity in the graphite-bearing carbonatites is slightly below the quartz-fayalite-magnetite buffer. It was proved that diamond is generated in the course of reduction of carbonate components arriving from plume material into the lower subcontinental lithosphere rather than owing to partial oxidation of methane fluids. As follows from the study of olivine and nominally anhydrous minerals in kimberlites, the limited role of methane in deep mantle is determined by low water activity. Methane is generated in mantle under special conditions such as extremely low oxygen fugacity (for instance, at the base of continental lithosphere) and elevated water activity. These conditions may occur during crystallization differentiation in deep-level chambers of kimberlite and proto-kimberlite magmas.     

Radon volumetric activity and ion production in the undisturbed lower atmosphere: Ground-based observations and numerical modeling

The results of in situ ground-based observations of radon volumetric activity carried out at the Borok Geophysical Observatory of Schmidt Institute of Physics of the Earth of the Russian Academy of Sciences (58°04′ N; 38°14′ E) are presented. Modeling the characteristic diurnal variation in the ion production rate in the undisturbed midlatitude lower atmosphere above land is carried out. The Lagrangian stochastic model of turbulent transport is developed in application to determining the vertical profiles of radon activity for 222Rn and 220Rn isotopes and their radioactive decay products. The results calculated by the Lagrangian stochastic model are matched with the analytical solution for the free atmosphere. Based on the model, the estimate is obtained for the rate of radon outflow from the convective boundary layer to the free clear sky atmosphere. The implications of temperature stratification of the atmosphere for the vertical distribution of the ion production rate at the different radon emission rate are explored.     

Bootstrap based artificial neural network (BANN) analysis for hierarchical prediction of monthly runoff in Upper Damodar Valley Catchment

Estimation of runoff is a prerequisite for many applications involving conservation and management of water resources. This study is undertaken in the Upper Damodar Valley Catchment (UDVC) having a drainage area of 17513.08 km² for prediction of monthly runoff. Thirty one microwatersheds and 15 sub-watersheds were selected from a total of 716 microwatersheds in the catchment area for this study. The feasibility of using different soil attributes (particle size distribution, organic matter content and apparent density), topographic attributes (primary, secondary and compound), geomorphologic attributes (basin, relief and network indices) and vegetation attribute as Normalized Difference Vegetation Index (NDVI), on prediction of monthly runoff were explored in this study. Principal Component Analysis (PCA) was applied to minimize the data redundancy of the input variables. Ten significant input variables namely; watershed length (km), elongation ratio, bifurcation ratio, area ratio, coarse sand (%), fine sand (%), elevation (m), slope (°), profile curvature (rad/m) and NDVI were selected. The selected input variables were added in hierarchy with monthly rainfall (mm) as inputs for prediction of monthly runoff (mm) using Bootstrap based artificial neural networks (BANN). The performance of the models was tested using Spearman’s correlation coefficient (r), coefficient of efficiency (COE), Root Mean Square Error (RMSE) and Mean Absolute Error (MAE). Best performance was observed for model with monthly rainfall, slope, coarse sand, bifurcation ratio and Normalized Difference Vegetation Index (NDVI) as inputs (r = 0.925 and COE = 0.839). Increase in number of input variables did not necessarily yield better performances of the BANN models. Selection of relevant inputs and their combinations were found to be key elements in determining the performance of BANN models. Annual runoff map was generated for all the microwatersheds utilizing the weights of the best performing BANN model. This study reveals that the specific combinations of soil, topography, geomorphology and vegetation inputs can be utilized for better prediction of monthly runoff.     

On the Trajectories of Asteroid Encounters with the Earth for 2015 RN35 and Apophis

A great number of probable encounters of asteroid 2015 RN35 with the Earth have been found; many of them were unknown earlier. The main characteristics and properties of the corresponding trajectories have been obtained. Probable impacts of the asteroid Apophis with the Earth are also discussed. The results suggest that the multitudes of potential impacts of hazardous asteroids with the Earth can be and must be analyzed in more detail. Such an analysis is required to plan and implement the measures on preventing the asteroid impact hazard.     

Mediterranean outflow through the Strait of Gibraltar since 18,000 Years B.P.: Mineralogical and geochemical arguments

Data obtained from mineralogical and geochemical analyses of piston and gravity cores, recovered from an area off Lisbon (Portugal) to the Alboran Sea (Mediterranean), serve as a basis for better understanding the past 18,000 years of hydrological exchanges at Gibraltar. Tracers used in this study are smectite, kaolinite, Ta, Th, La. One of the primary sources of particles both into and out of the Mediterranean is the Guadalquivir River. These particles are transported back into the Atlantic in the Mediterranean outflow water, and deposited along the Iberian slope. No evidence for reversal of this outflow current was found in those cores, since 18,000 years B.P.