Diamonds from placers in western and central Africa: A problem of primary sources

This paper discusses diamonds and their accessory minerals from the Koidu kimberlites, placers on the Bafit River in Sierra Leone, and Chikapa placers in the Democratic Republic of Congo. Minerals from the placers are characterized by fine preservation and bear no evidence of long-term transportation. In placers, garnet, ilmenite and zircon have been found, but the specific features of their chemical composition do not coincide with those of minerals from kimberlites. Diamonds from the placers are of a mantle origin, but they have no direct analogs in the known kimberlite and lamproite pipes.     

A study of energetics during an active monsoon over Indian region

The various forms of energy and energy conversions have been computed over a part of the Indian region during an active monsoon period, using the quasigeostrophic baroclinic model. The energetics of the monsoon depression have been discussed on the basis of these results.     

TURBULENCE STRUCTURE IN A STRATIFIED BOUNDARY LAYER UNDER STABLE CONDITIONS

Turbulence structure in stably stratified boundary layers isexperimentally investigated by using a thermally stratified wind tunnel. Astably stratified flow is created by heating the wind tunnel airflow to atemperature of about 50 °C and by cooling the test-section floor to asurface temperature of about 3 °C. In order to study the effect ofbuoyancy on turbulent boundary layers for a wide range of stability, thevelocity and temperature fluctuations are measured simultaneously at adownwind position of 23.5 m from the tunnel entrance, where the boundarylayer is fully developed. The Reynolds number, Re, ranges from 3.14× 104 to 1.27 × 105, and the bulk Richardson number, Ri,ranges from 0 to 1.33. Stable stratification rapidly suppresses thefluctuations of streamwise velocity and temperature as well as the verticalvelocity fluctuation. Momentum and heat fluxes are also significantlydecreased with increasing stability and become nearly zero in the lowest partof the boundary layer with strong stability. The vertical profiles ofturbulence quantities exhibit different behaviour in three distinct stabilityregimes, the neutral flows, the stratified flows with weak stability(Ri = 0.12, 0.20) and those with strong stability (Ri= 0.39,0.47, 1.33). Of these, the two regimes of stratified flows clearly showdifferent vertical profiles of the local gradient Richardson number Ri,separated by the critical Richardson number Ri cr of about 0.25. Moreover,turbulence quantities in stable conditions are well correlated with Ri.     

Organic matter of the North Atlantic

The areas that we studied in the North Atlantic (53 and 60°N) and in the Labrador Sea in the summer were characterized by a wide variability of the concentrations of dissolved and particulate organic matter and its elemental composition both in the surface and in the deep waters. The concentrations of dissolved and particulate C_org varied within 69–360 μM and 0.7–25.6 μM, respectively; the N_org and P_org contents varied within 1.4–22.2 μM and 0.02–0.86 μM, respectively. The maximal concentrations were registered in the photic layer and in the zones of mixing between the waters of different genesis. The particulate matter contribution to the total organic matter (OM) content varied from 0.5 to 15.4%. The waters of the photic layer contained more particulate C_org than those of the near-bottom layer. The values of the C/N molar ratios from the surface to the bottom over the entire aquatic area surveyed varied 5-to 6-fold; at that, the values of the C/P molar ratios varied more than tenfold. In the most productive waters, the values of the C/N ratios were close to the Redfield ratios (6–10). The values of the C/P molar ratios varied from 160 in the photic layer to 4831 in the deep waters. The pronounced non-uniformity in the spatial distribution of the OM and its elemental composition is caused not only by the penetration of the waters of different origins but also by the changes in the microplankton metabolism under mixing of these waters.     

Finite-difference migration of the field of refracted waves in studies of the deep structure of the Earth’s crust and the upper mantle based on the DSS (on the example of the <Emphasis Type="Italic">DOBRE</Emphasis> profile)

The main results of deep seismic sounding (DSS) are usually presented in the form of high-velocity models of the medium. Some model examples and the international DOBRE profile have shown that the informativeness of the data obtained can be significantly enhanced by the construction of wave images of the Earth’s crust, based on the migration of refracted and wide-angle reflected waves. The Donets Basin Refraction/Reflection Experiment (DOBRE) profile crosses the Dnieper-Donets paleorift zone in the Donbas region. Along the profile, refracted waves from the basement and the upper mantle and the reflections from the crust basement (the M boundary) are reliably traced. This wave migration has been used to construct a wave image of the structure of the Earth’s crust. As a result, a clear seismic image of the basement surface, whose depth changes along the profile from 0 to 20 km, was obtained. In near-slope parts of the basin, several major faults were identified that had not been identified previously during standard kinematic data processing. It is shown that the crust-upper mantle transition zone is a clearly reflective horizon only within the crystalline massifs; under a depression, it is represented by a lens-shaped highly-heterogeneous area. As shown in the model examples, the images obtained using such a migration accurately reflect the structural features of the medium, in spite of its complicated structure.     

Adsorptive Removal of Acid Blue 15: Equilibrium and Kinetic Study

Activated carbons prepared from sunflower seed hull have been used as adsorbents for the removal of acid blue 15 (AB‐15) from aqueous solution. Batch adsorption techniques were performed to evaluate the influences of various experimental parameters, e. g., temperature, adsorbent dosage, pH, initial dye concentration and contact time on the adsorption process. The optimum conditions for AB‐15 removal were found to be pH = 3, adsorbent dosage = 3 g/L and equilibrium time = 4 h at 30°C. The adsorption of AB‐15 onto the adsorbent was found to increase with increasing dosage. It was found from experimental results that the Langmuir isotherm fits the data better than the Freundlich and Temkin isotherms. The maximum adsorption capacity, Q_m (at 30°C) was calculated for SF1, SF2, and SF3 as 75, 125 and 110 mg g^–1 of adsorbent, respectively. It was found that the adsorption follows pseudo‐second order kinetics. The thermodynamic parameters such as ΔG°, ΔH°, and ΔS° were also evaluated. The activated carbons prepared were characterized by FT‐IR, SEM and BET analysis.     

On mass transport in deep water waves

Summary Various formulations of the mass-transport problem are compared for progressive waves in deep water. In order to calculate the mass-transport velocity as a function of depth in the main body of the fluid, it is necessary to include the effect of viscous wave attenuation. It is shown that the usual assumptions of periodicity in distance and attenuation with time or periodicity in time and attenuation with distance, are both physically unsatisfactory. The first does not specify a unique solution, and the second is incompatible with the assumption of zero surface stress. A certain critical constant tangential wind stress will maintain strictly time-periodic deep water waves. The corresponding attenuation with distance is then calculated to order ³. A constant tangential stress greater or less than the critical causes waves, necessarily decaying with distance, to grow or decay with time.     

Use of Carbonatites in the Production of Precipitated Calcium Carbonate: A Case Study from Eppawala,Sri Lanka

The study investigates the possibility of using carbonatite in the production of precipitated calcium carbonate (PCC). We made use of fresh apatite-rich carbonatites found at the phosphate mining sites at Eppawala, Sri Lanka. Analyses of the fresh carbonatite were performed with the aid of optical microscopy, powder X-ray diffraction (XRD), atomic absorption spectrophotometry (AAS), UV/visible spectrophotometry (UVVS), and thermo gravimetric analysis (TGA). Quicklime obtained from calcinations of carbonatites was used in synthesizing PCC via a lime-soda process. The end product was analyzed with XRD, TGA, AAS, and UVVS. Results revealed that the most common CO₃ ^2? phase available in fresh carbonatites is calcite (>65%). The Ca-rich CO₃ ^2? phase can be distinguished easily from other available minerals because its mode of occurrence in carbonatite matrix is different to that of other minerals. The results of TGA show that the decomposition of CO₃ ^2? phase initiates at about 340°C, which leads to lower energy consumption during calcinations. Post-magmatic hydrothermal process may have been the cause of the formation of thermally unstable CO₃ ^2? phases. Hydration of quicklime from the carbonatite yields much higher Ca²⁺ in the solution than from marble under the same experimental conditions. The synthesized PCC particles are in the calcite polymorphic form. The purity of PCC varies from 96 to 98 wt%. The maximum precipitable CaCO₃ from 1 g of quicklime is about 1.1 g. Hence, fresh carbonatites has great economic potential for the production of PCC.     

Fault structures and their geoelectric parameters in the epicentral zone of the 27 September 2003 Chuya earthquake (Gorny Altai) from resistivity data

This paper presents an integrated measurement technique based on DC methods (vertical electrical sounding, electrical resistivity tomography) which was used to identify faults and determine their geoelectric parameters in the western part of the Chuya basin. New information on the structure of the Chagan River valley located in the zone of the disastrous 27 September 2003 Chuya earthquake has been obtained from the results of these methods. Geoelectric cross-sections of the sedimentary sequence and the upper part of the basement were obtained from VES data, showing the block structure of the study area. Electrical resistivity tomography sections confirm the presence of a major fault between basement blocks of different heights and indicate the presence of faults bounding the valley on its right side and in the southwestern part.     

山东半岛典型海岸带多环芳烃分布特征、来源解析及风险评价

山东半岛海岸带面临着各类复杂的环境问题,尤其是受到了多环芳烃(PAHs)等持久性有机物的污染,本文研究了整个山东半岛典型海岸带62个站点表层沉积物中PAHs的含量及其分布特征,并对其来源和潜在风险进行解析与评价。研究表明,该地区表层沉积物中16种PAHs总含量为0.06~3191.40 ng/g(平均值262.08 ng/g),与国内外海岸带相比,山东半岛海岸带表层沉积物中PAHs整体污染状况处于较低水平,但个别站点的PAHs含量偏高。运用特征比值法、相关性分析及主成分分析法解析研究区PAHs主要来源为木柴、煤炭、油类的燃烧以及油类泄露的联合作用。采用效应区间低值法(ERL)和中值法(ERM)对PAHs进行生态风险评价,结果表明莱州湾周边所有站点及威海、青岛周边个别站点苊、芴浓度位于ERL值与ERM值之间,但多数站点对生态环境潜在负面效应很小。山东半岛典型海岸带中PAHs对生物的毒副作用尚在安全可控范围内,极少对生态环境产生负面效应。