Mudrocks from the Siberian Hypostratotype of the Riphean and Vendian: Chemistry,Sm–Nd Isotope Systematics of Sources,and Formation Stages

Lithology and Mineral Resources - The chemical composition and Nd isotope systematics were obtained for mudrocks (mudstones) from sections of the Siberian hypostratotype of the Riphean and Vendian...     

Causes of Geochemical Diversity of Carbon Dioxide Water in Crystalline Rock Masses

The problem of the diversity of the geochemical types of carbon dioxide waters (CDW) in petrografically and mineralogically uniform crystalline rock masses is solved with allowance made for the effect of different boundary conditions (physicochemical parameters) on the geochemical effect of interaction in the rock–water system. The formation of the entire geochemical spectrum of CDW in crystalline rock masses is shown to be explicable on the basis of a model of interaction in granite–water systems at different mass ratios of reacting rock (S) and water (L), different temperatures T, and equilibrium concentrations of dissolved CO₂ (P _CO2).     

Late Cretaceous rift-related upwelling and melting of the Trindade starting mantle plume head beneath western Brazil

High mantle potential temperatures and local extension, associated with the Late-Cretaceous impact of the Trindade mantle plume, produced substantial widespread and voluminous magmatism around the northern half of the Paraná sedimentary basin. Our previous studies have shown that, above the central and eastern portions of the postulated impact zone where lithosphere extension is minimal, heat conducted by the plume caused large-scale melting of the more fusible parts of the subcontinental lithospheric mantle beneath the margin of the São Francisco craton and the surrounding Brasilía mobile belt. Here we combine geochemical data and field evidence from the Poxoreu Igneous Province, western Brazil to show how more intense lithospheric extension above the western margin of the postulated impact zone permitted greater upwelling and melting of the Trindade plume than further east. Laser ⁴⁰Ar/³⁹Ar age determinations indicate that rift-related basaltic magmas of the Poxoreu Igneous Province were emplaced at ? 84 Ma. Our detailed geochemical study of the mafic magmas shows that the parental melts underwent polybaric crystal fractionation within the crust prior to final emplacement. Furthermore, some magmas (quartz-normative) appear to have assimilated upper crust whereas others (nepheline- and hypersthene-normative) appear to have been unaffected by open-system crustal magma chamber processes. Incompatible trace element ratios (e.g. chondrite-normalised La/Nb?=?1) and isotopic ratios (⁸⁷Sr/⁸⁶Sr?=?0.704 and ¹⁴³Nd/¹⁴⁴Nd?=?0.51274) of the Hy-normative basalts resemble those of oceanic islands (OIB). We therefore propose that these “OIB-like” magmas were predominantly derived from convecting-mantle-source melts (i.e. Trindade mantle plume). Inverse modelling of rare-earth element (REE) abundances suggests that the initial melts were predominantly generated within the depth range of ?80–100 km, in mantle with a potential temperature of ?1500 °C.     

The age of the Lower Carboniferous conglomerate at Lligwy Bay,Anglesey

The Lower Carboniferous conglomerate at Lligwy Bay, Anglesey, is shown to be underlain as well as overlain by limestones of D₁ age so that the conglomerate is of intra-D₁ age. It is considered to have been deposited very close to a coastline.     

Extraction and recovery of precious metals from electronic waste printed circuit boards by bioleaching acidophilic fungi

Printed circuit boards contain precious metals. They are produced in large volumes, rendering them an important component of the electronic waste. In view of the heterogeneity of the metals present, reprocessing of electronic waste is a heinous task. The present study focused on leaching of valuable metals from electronic waste printed circuit boards using Aspergillus niger DDNS1. The adaptation phases began at 0.1, 0.5 and 1.0% of fine powder of printed circuit boards with 10% inoculum and were optimized with three effective factors, viz. initial pH, particle size and pulp density, to achieve the maximum simultaneous recovery of the valuable metals. The interactions of these metals were also deciphered using scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, Fourier transform infrared spectrum and atomic absorption spectroscopy. The results indicated that extraction of the precious metals was accomplished mainly through the unique organic acids originating from A. niger DDNS1. The initial pH played an important role in the extraction of the precious metals and the metals precipitate formation. The leaching rate of the metals was generally higher at low powder dosage of printed circuit boards. The toxicity of the printed circuit boards had little effect on two-step bioleaching at the pulp density of 0.1% compared to one-step bioleaching. The two-step bioleaching process was followed under organic acid-forming conditions for the maximum mobilization of metals. Thus, the precious metals from printed circuit boards could be mobilized through fungal bioleaching which promises an important industrial application in recycling of electronic wastes.     

Reconstruction of palaeosalinity using carbon isotopes and benthic associations: a comparison

Carbon and oxygen isotopes were determined on 40 recrystallized shells of Late Jurassic bivalves from the Lusitanian Basin of Portugal. In contrast with the oxygen isotopes, which exhibited considerable diagenetic distortion, the carbon isotopes are thought to preserve a record of the salinity of the Jurassic marginal marine seas in which these bivalves lived. The reconstructed palaeosalinities range from 35%o (euhaline) to 5% (oligohaline). Comparing these values with the palaeosalinity reconstructed from a palaeoecological analysis of 17 stratigraphic levels within the basin, the independently derived values agree in most cases. Strongly differing values are explained as being due to biotic factors and to diagenetic distortion of the isotopic signal; they are less likely to be due to smallscale time-averaging or insufficient microstratigraphic sampling. On the whole, the carbon isotope analyses are thought to produce reasonable palaeosalinity values, although data from infaunal, originally aragonitic bivalves appear to be less reliable than those from epifaunal bivalves with a predominantly or exclusively calcitic shell. As diagenetic alteration of the carbon isotope signal is, however, unpredictable and biotic effects on the isotopic composition are insufficiently known, palaeosalinity reconstructions based on stable isotope data should be supported by palaeoecological data.     

Réflexions sur la contingence des lois de la Nature

There are two fundamental conceptions concerning the laws of nature — these laws are eternal or they may vary in the course of time. We suggest an experiment in order to find an intermediary thesis — i.e. to discover that law, if it really exists, according to which a given law of nature varies, or, at least, to find out the direction in which this variation is performed.