Heavy metal concentrations in soils and plants in the vicinity of Arufu lead-zinc mine,Middle Benue Trough,Nigeria

This study focused on the influence of base metal mining on heavy metal levels in soils and plants in the vicinity of Arufu lead-zinc mine, Nigeria. Soil samples (0-15 cm depth) and plant samples were collected from cul-tivated farmlands in and around the mine, the unmineralized site and a nearby forest (the control site). The samples were analyzed for heavy metals (Fe, Zn, Mn, Cu, Pb, Cr and Cd) by Atomic Absorption Spectrophotometry (AAS). The physical properties of soils (pH and LOI) were also measured. Results showed that soils from cultivated farm-lands have neutral pH values (6.5-7.5), and low organic matter contents (10%). Levels of Zn, Pb and Cd in culti-vated soils were higher than the concentrations obtained from the control site. These heavy metals are most probably sourced from mining and agricultural activities in the study area. Heavy metal concentrations measured in plant parts decreased in the order of rice leavescassava tuberspeelings. In the same plant species, metal levels decreased in the order of ZnFeMnCuPbCrCd. Most heavy metals were found in plant parts at average concentrations normally observed in plants grown in uncontaminated soil, however, elevated concentrations of Pb and Cd were found in a few cassava samples close to the mine dump. A stepwise linear regression analysis identified soil metal contents, pH and LOI as some of the factors influencing soil-plant metal uptake.     

First Find of Ga-Bearing Minerals in Ores of Ural Massive Sulfide Deposits

Gallium-containing chlorite, mica, and magnetite (up to 14, 13, and 5–7 wt % of Ga) along with Ga hydroxides (oxyhydroxides?) were found for the first time in massive sulfide deposit in the Urals. The minerals identified within the cement of chalcopyrite–sphalerite breccias of the Shemur copper–zinc–massive sulfide deposit (Northern Urals) are associated with Ga-enriched sphalerite, chalcopyrite, and, less commonly, pyrite (33–364, 67–363, and 4–230 g/t, respectively).     

Paleoproterozoic anorogenic granitoids of the Zheltav sialic massif (Southern Kazakhstan): Structural position and geochronology

The basement of the Zheltav sialic massif (Southern Kazakhstan) is composed of different metamorphic rocks united into the Anrakhai Complex. In the southeastern part of the massif, these rocks form a large antiform with the core represented by amphibole and clinopyroxene gneissic granite varieties. By their chemical composition, dominant amphibole (hastingsite) gneissic granites correspond to subalkaline granites, while their petroand geochemical properties make them close to A-type granites. The U–Pb geochronological study of accessory zircons yielded an age of 1841 ± 6 Ma, which corresponds to the crystallization age of melts parental for protoliths of amphibole gneissic granites of the Zheltav Massif. Thus, the structural–geological and geochronological data make it possible to define the Paleoproterozoic (Staterian) stage of anorogenic magmatism in the Precambrian history of the Zheltav Massif. The combined Sm–Nd isotopic—geochronological data and age estimates obtained for detrital zircons indicate the significant role of the Paleoproterozoic tectono-magmatic stage in the formation of the Precambrian continental crust of sialic massifs in Kazakhstan and northern Tien Shan.     

Simultaneous transport of water and solutes under transient unsaturated flow conditions — A case study

The imbalance between incoming and outgoing salt causes salinization of soils and sub-soils that result in increasing the salinity of stream-flows and agriculture land. This salinization is a serious environmental hazard particularly in semi-arid and arid lands. In order to estimate the magnitude of the hazard posed by salinity, it is important to understand and identify the processes that control salt movement from the soil surface through the root zone to the ground water and stream flows. In the present study, Malaprabha sub-basin (up to dam site) has been selected which has two distinct climatic zones, sub-humid (upstream of Khanapur) and semi-arid region (downstream of Khanapur). In the upstream, both surface and ground waters are used for irrigation, whereas in the downstream mostly groundwater is used. Both soils and ground waters are more saline in downstream parts of the study area. In this study we characterized the soil salinity and groundwater quality in both areas. An attempt is also made to model the distribution of potassium concentration in the soil profile in response to varying irrigation conditions using the SWIM (Soil-Water Infiltration and Movement) model. Fair agreement was obtained between predicted and measured results indicating the applicability of the model.     

Paleozoic granitoid magmatism of the eastern part of the Central Asian Fold Belt and formation of large ore deposits

Evidence on the Paleozoic granitoids of the eastern part of the Central Asian Fold Belt (CAFB) was analyzed. A tectonic chart of orogenic belts was compiled. Sketch maps were constructed for the geodynamic settings of the formation of Paleozoic granitoids and the extensiveness of their occurrence. Two types of deep controlling structures were distinguished: zones of lithospheric faults and plumes, including the newly recognized Jiamusi-Bureya plume. It was sown that the distribution of large and superlarge Paleozoic ore deposits is related to these structures, primarily to plumes. Sites promising for large and superlarge deposits related to the Paleozoic granitoid magmatism were determined in the Russian Far East.     

Zr/Hf ratio as an indicator of fractionation of rare-metal granites by the example of the Kukulbei complex,eastern Transbaikalia

The concept of granitic melt fractionation as the main process in the concentration of rare elements in granites calls for the development of a reliable method to determine the evolutionary sequences of granite series. We propose to use for this purpose a zirconium-hafnium indicator, the Zr/Hf weight ratio in granitic rocks (Zaraisky et al., 1999, 2000). By the example of three classic regions of rare-metal deposits, eastern Transbaikalia, central Kazakhstan, and Erzgebirge (Czech Republic and Germany), it was empirically shown that the Zr/Hf ratio of granites decreases during the fractional crystallization of granite magmas in the sequence granodiorite → biotite granite → leucogranite → lithium-fluorine granite. The reason is the higher affinity of Hf compared with Zr to a granite melt. This implies that the crystallization and settling of accessory zircon will cause the progressive enrichment of Hf relative to Zr in the residual melt. As a result, the Zr/Hf ratio decreases regularly in the series of sequential phases of granite intrusion related to a single magma chamber from granodiorite to biotite granite, leucogranite, and Li-F granite (from 45-30 to 10-2). Our experimental investigations supported the preferential enrichment of haplogranite melt in Hf and zircon crystals in equilibrium with melt in Zr (T= 800°C and P = 1 kbar). The Zr/Hf indicator was tested by the example of the wellknown Kukulbei rare-metal granite complex of eastern Transbaikalia (J3), which is unique in the degree of fractionation of initial granite melt with the formation of three phases of granite emplacement and vein derivatives. An important feature of the complex is its “short” differentiation trend. It was supposed that the granite magma of the first phase is parental, and the later phases forming small intrusive bodies in large massifs of biotite granites of the first phase are sequential products of its crystallization differentiation in a magma chamber. The biotite granites of the first phase are barren. The leucocratic granites of the second phase are accompanied by tin-tungsten greisen deposits (e.g., Spokoininskoe), and the upper part of cupola-like stocks of Li-F amazonite granites of the third phase host apogranite-type tantalum deposits (Orlovka, Etyka, and Achikan). In addition to three granite phases, the Kukulbei complex includes dikes of ongonites, elvans, amazonite granites, and chamber miarolitic pegmatites. All of the granitic rocks of the complex have similar isotopic ages of 142± 0.6 Ma. The Zr/Hf ratio decreases systematically from phase 1 (40–25), to phase 2 (20–10), and phase 3 (10–2). The ongonites, elvans, and pegmatites have similar Zr/Hf ratios (15-5), falling between the ranges of leucocratic muscovite granites and Li-F granites. Compared with other granite series, the granitic rocks of the Kukulbei complex show specific petrographic and geochemical features: they are strongly enriched in Rb, Li, Cs, Be, Sn, W, Mo, Ta, Nb, Bi, and F but depleted in Mg, Ca, Fe, Ti, P, Sr, Ba, V, Co, Ni, Cr, Zr, REE, and Y. From the early to late intrusion phases, the degree of enrichment and depletion in these element groups increases regularly. This is accompanied by a significant decrease (from 40 to 2) in Zr/Hf, which can be used as a reliable indicator of genetic relations, degree of fractionation, and rare-metal potential of granites. Granites with Zr/Hf values lower than 25 are promising for prospecting for Sn, W, Mo, and Be greisen deposits, whereas the formation of Ta deposits requires Zr/Hf values lower than 10.     

云南中甸地区晚白垩世斑岩型Mo-Cu矿床磷灰石、锆石裂变径迹年代学研究

云南中甸地区位于西南三江铜钼铅锌金多金属矿集区的南端,是一个独具特色的Cu-Mo多金属复合叠加成矿带.本文采用裂变径迹低温热年代学技术对区内晚白垩世铜厂沟、休瓦促、热林成矿斑岩体,进行了锆石、磷灰石裂变径迹分析测试,开展了晚白垩世以来的构造热史演化模拟,揭示了区内构造-岩浆成矿事件及热史演化过程.研究表明,锆石裂变径迹年龄值变化于52±2～96±5 Ma;磷灰石裂变径迹的年龄值变化于15±1～48±3 Ma,总体变化幅度不大,中心年龄与池年龄在误差范围也基本一致.通过锆石、磷灰石的裂变径迹分析,揭示出云南中甸地区自晚白垩世以来主要经历了三个阶段的构造热事件.第一阶段(96～60 Ma),主要为岩浆侵位后快速降温的热史演化阶段;第二阶段(52～39 Ma),为缓慢的降温作用过程;第三阶段(16～15 Ma),揭示了受中新世以来青藏高原隆升造山作用的影响,该区经历了快速降温的地质演化过程.综合锆石裂变径迹、磷灰石裂变径迹的热史反演结果,表明区内晚白垩世典型成矿斑岩体具有相似的隆升过程和剥蚀历史,并获得了剥蚀量与剥蚀速率的定量计算结果,为区内矿床的资源潜力评价及勘查工作提供了科学参考.     

Threshold of sediment motion under unidirectional currents

Carefully selected data for the threshold of sediment movement under unidirectional flow conditions have been utilized to re-examine the various empirical curves that are commonly employed to predict this threshold. After a review of the existing data, we employed only that data obtained from open channel flumes with parallel sidewalls where flows were uniform and steady over flattened beds of unigranular, rounded sediments. Without these restrictions, an unmanageable amount of scatter is introduced. This selected data is used to develop a modified Shields-type threshold diagram that extends the limits of the original diagram by three orders of magnitude in the grain-Reynolds number. The equally general but more easily employed Yalin diagram for sediment threshold is also examined. Although the Shields and Yalin diagrams are general in that they apply to a wide range of different liquids, in both cases somewhat different curves are obtained for threshold under air than for the liquids. The often used empirical curves of the friction velocity u_*, the velocity 100 cm above the bed u₁₀₀, the bottom stress θ_t, and Shields’ relative stress θ_t, all versus the grain diameter D, are limited in their ranges of application to certain combinations of grain density, fluid density, fluid viscosity and gravity. These conditions must be selected before the curves are generated from either the more general Shields or Yalin curves. For example, on the basis of the data selected for use in this paper, empirical threshold relationships for quartz density material in water are where the velocity u₁₀₀ measured 100 cm above the sediment bed is given in cm/sec and the grain diameter D is in cm. The limitations on any of the threshold relationships are severe. These limitations should be properly understood so that the empirical curves and relationships are not improperly employed.     

MC-ICP-MS锂同位素溶液分析技术与应用

Li同位素是一种新兴的非传统稳定同位素示踪工具,在地质学、地球化学研究中具有广阔的应用前景。目前,Li同位素溶液分析技术主要采用热电离质谱仪（TIMS）和多接收电感耦合等离子质谱仪（MC-ICP-MS）,与TIMS相比,MC-ICP-MS具有分析精度高、样品量少、测试速度快等诸多优点。本研究团队近年来建立了MC-ICP-MS高精度Li同位素分析方法,在天然样品、标准物质以及石英包裹体的Li同位素测定中都取得了良好结果。以此为依托,研究团队建立了适用于西藏本地岩石成因研究的Li同位素地质端元,并将Li同位素应用于青藏高原岩石圈结构及其隆升历史、川西碳酸岩型稀土矿床富集机制、四川呷村VMS型矿床成矿流体来源和四川甲基卡硬岩型Li矿床富集机理等方面。本文比较详细地综述了这些研究进展,旨在加深对Li同位素溶液分析技术的理解,展示其在地球化学研究中的良好应用前景。