Environmental Condition of Water Bodies in the Territory of an Oil–Gas Condensate Field (the Pechora Delta)

Chemical characteristics of the surface water and algae in lakes in the Seduiyakha River basin are presented. Specific features of components of limnetic ecosystems under the influence of anthropogenic factors in the territory of an oil–gas condensate field are shown. Ambiguous response of algal communities to changes in the aquatic environment is revealed.     

Calculating Sediment Transport in the Coastal Zone of the Sea

The mathematical model described is intended for the prediction of anthropogenic sediment transport in the coastal zone of the sea. Calculation results are presented.     

Study of Heavy Metal Compound Transformations in Surface Waters

Results of studying Fe(III) hydrolysis and sorption of heavy metal compounds by organic matter of bottom sediments are discussed. The rate of Fe(III) hydrolysis is found to be largely determined by the concentration of dissolved organic substances. Values of kinetic parameters are obtained for heavy metal compounds sorption under static and dynamic conditions. Calculating the solubility of Fe, Cu, Cd, Zn, and Pb sulfides allowed the assessment of the amount of metals lost by bottom sediments due to the formation of metal complexes with dissolved organic substances contained in natural waters.     

Natural and Human-Induced Variations in Water and Sediment Runoff in the Danube River Mouth

Long-term natural and human-induced variations in water and sediment runoff in the Danube Delta head were studied on the basis of analysis of an extremely long series of observations (1840–2002). A considerable reduction of sediment runoff in the second half of the 20th century related to sediment accumulation in reservoirs was revealed. It was found that human activities had an insignificant impact on the water runoff variations and the period of 1961–2002 turned out to be abnormally water-abundant.     

On the Problem of Differential Payment for the Use of Different-Quality Surface Waters in Ukraine

The evolution of views and practical decisions regarding the problem of collecting payment for the use of surface waters with regard to their quality in the former USSR and present-day Ukraine is discussed. A simple and feasible method is proposed for differentitation of regional (basin) rates of payment for the use of surface water in Ukraine with allowance made for its quality assessed based on a system of environmental classifications.     

Water Quality Estimation Based on Histological Investigations of Fish: Case Study of Kenozero Lake

Specific hydrological and hydrochemical conditions in Kenozero Lake have led to changes in the morphology of fishes at a cellular level. The abnormalities in the function of the respiratory, digestive, and excretory systems were recorded. The degree of pathology depended on the ecological features of the fish. The pathological changes were most pronounced in the gills of the fish species (orfe, perch, and roach) characterized by active mode of life and sensible to oxygen deficiency. The changes in the epithelium of gill filaments had a compensatory significance and were aimed at increasing the area of the functional surface of the gills under the conditions of hypoxia.     

Long-Term Variations in the Vertical Thermohaline Structure in Deep-Water Zones of the Caspian Sea

Long-term variability in water temperature and salinity in August has been determined for deep-water segments of standard profiles in the Central and Southern Caspian Sea based on data of on-board observations carried out in 1956–2000. Estimates of parameters of the vertical thermohaline structure of waters were obtained for four time intervals. These estimates have been compared to the variability in the main external factors governing the formation of thermohaline regime. Appreciable long-term variations in the vertical thermohaline structure of waters, caused by a nonperiodic alternation of two main types of hydrological processes in the Caspian Sea are revealed. Qualitative characteristics of these two types are presented.     

An automated seamless mosaicing system of multi-charge coupled devices of panchromatic data

Panchromatic data of pixel resolution 5.8 m obtained from IRS-1C and IRS-1D satellites proved to be very useful for mapping purposes. One of the popular data product is the 70 km swath mosaic which is covered by a combination of 3 CCD line sensors, each with 4096 pixels. Each CCD-line sensor with different imaging times causes geometric problems of mosaicing three strips data together. In this paper, we propose the details of the design elements of system that caters to the need for accurate and automatic multi strip image registration without any second resampling of the data. The systematic geometric correction grid mapping is improved to facilitate accurate mosaicing by automatic image registration task that makes use of the overlap data within image strips and image registration is achieved up to sub-pixel level.     

New geochemical data from the Nigerian sector of the Chad basin: implications on hydrocarbon prospectivity

Organic geochemical studies have been carried out to assess the qualities of source rocks penetrated by four wells (Kemar-1, Murshe-1, Tuma-1 and Ziye-1) in the Nigerian sector of the Chad basin. The Chad basin is a large intracratonic basin in Central West Africa. Commercial hydrocarbon accumulations have been discovered in some sectors of the basin outside the Nigerian border in a structurally related contiguous basin. Fair to poor quality source rocks are inherent in the sequences penetrated by the studied wells. About 80% of all samples have their total organic carbon (TOC) contents more than 0.5 wt.%, the minimum limit for hydrocarbon generation. Juxtaposition of the hydrogen indices against the TOC and T_max indicates that the source rocks are entirely gas-prone. However, biomarker chromatograms and extract vs. TOC plots indicate the presence of oil shows in Ziye-1 well at a depth of 1210 m. Although generated hydrocarbons (wherever they have accumulated) would be overwhelmingly gaseous, gas is the energy of the future. The gas resources of this part of Nigeria's inland basins can be economically exploited through policies that will increase the tempo of gas-utilization projects and the construction of a national grid of gas pipelines with nodal points of input and output.     

Reversibility of radiocaesium sorption on illite

Adsorption of trace amounts of radiocaesium on NH₄-, K-, and Na-saturated Fithian illite and subsequent desorption by 1 M NH₄ showed that a substantial amount of radiocaesium (44%, 46%, and 91% for NH₄-, K-, and Na-illite, respectively) cannot be desorbed after only 5 min of adsorption. Our results suggest that this instantaneous fixation is caused by the collapse of the frayed edges of the clay mineral and the relatively high concentration of radiocaesium building up in solution in the batch desorption experiments. Consequently, commonly applied high-NH₄ extractions underestimate truly exchangeable amounts of radiocaesium in soils and sediments containing illitic clay minerals. The rate of desorption of trace amounts of radiocaesium from the solids using high NH₄ or Cs concentrations has a half-life of about 2 yr, reflecting radiocaesium desorption from (partially) collapsed interlayers. Extraction of radiocaesium from illite after 5 min of contact time with a Cs-selective adsorbent or a 1 × 10^-6 M CsCl solution shows that 100% of the bound radiocaesium is readily available. The desorption rate in the presence of a Cs-selective adsorbent has a half-life of about 0.2 yr. Desorption of radiocaesium from illite using different ammonium concentrations shows that radiocaesium partitioning follows reversible ion-exchange theory if the NH₄ concentration is below 1 × 10^-4 M, and sufficient time (weeks) is allowed for the reaction to proceed. Thus, radiocaesium sorption reversibility in the natural environment is much higher than generally assumed, and equilibrium solid/liquid partitioning may be assumed for the long-term modelling of radiocaesium mobility in the natural environment. In the particular case of anoxic freshwater sediments with very high NH₄ concentrations in the pore waters (up to several mmol.L^-1), collapse of the frayed edges of illite may occur, influencing radiocaesium partitioning. If collapse occurs before radiocaesium adsorbs to illite, high caesium sorption reversibility as measured by high-NH₄ extraction can be expected because further collapse of the frayed edges during the extraction procedure will be limited. This effect has indeed been observed earlier in the extraction of radiocaesium from anoxic freshwater sediments with high-NH₄ solutions and was as yet unexplained.