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While the role of groundwater in flushing of solutes has long been recognized, few studies have explicitly studied the within‐event changes in groundwater chemistry. We compared the changes in groundwater chemistry during storm events for a wetland and hillslope position in a small (1·5 ha) glaciated, forested catchment in western New York. Flushing responses for dissolved organic carbon (DOC) and nitrogen (DON), nitrate (NO3) and sulfate (SO4) in wetland and hillslope groundwaters were also compared against the corresponding responses in stream water. Eight storm events with varying intensity, amount, and antecedent moisture conditions were evaluated. Solute flushing patterns for wetland and hillslope groundwaters differed dramatically. While DOC concentrations in wetland groundwater followed a dilution trend, corresponding values for hillslope groundwater showed a slight increase. Concentrations for NO3 in wetland groundwater were below detection limits, but hillslope groundwaters displayed high NO3 concentrations with a pronounced increase during storm events. Flushing responses at all positions were also influenced by the size of the event and the time between events. We attributed the differences in flushing to the differences in hydrologic flow paths and biogeochemical conditions. Flushing of the wetland did appear to influence storm‐event stream chemistry but the same could not be said for hillslope groundwaters. This suggests that while a variety of flushing responses may be observed in a catchment, only a subset of these responses affect the discharge chemistry at the catchment outlet. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
33.
Abstract— This paper explores two processes, sweeping secular resonance (Ward, 1981) and gas drag (Lecar and Franklin, 1997), at work during the dispersal of the solar nebula. we have two aims not previously considered for the two mechanisms: (1) to explain the likely depletion, by a factor of 1000 or so, of the rocky material in the inner belt (2.0 < a < 3.2 AU); (2) to introduce a means for providing—or contributing to—the dispersion in semimajor axis of the various asteroidal taxonomic classes. We suggest that large asteroids with birthplaces separated by an astronomical unit or more can be finally deposited, owing to drag, at the same semimajor axis. For example, we find that bodies with radii up to 100 km can be transferred by gas drag from the outer belt (a > 3.3 AU) well into the inner one, and that an object already in the inner belt as large or even larger than Vesta (r = 250 km)—thought to be the parent body of many meteorites—can be inwardly displaced by as much as an astronomical unit if the nebula dispersal times lie close to 105 years. For such times, a large fraction of the inner belt's primordial mass can be ejected, with most of it passing into the inner solar system.  相似文献   
34.
Concentrations and fluxes of mercury (Hg) species in surface waters of forested watersheds are affected by hydrological events. The mechanisms of Hg transport during these events are poorly understood and yet may influence Hg bioavailability and exposure to aquatic biota. Three storm events with varying magnitude and intensity were investigated (June, September and November 2005) at a forested watershed in the Adirondack region of New York State, USA. Concentrations of Hg species increased during these events, both above and downstream of wetlands in the watershed. While Hg flux was higher from wetland drainage, the Hg flux from the upland site exhibited a greater relative increase to elevated runoff. Hg flux was controlled by discharge; however, Hg species concentrations were not well correlated with discharge, dissolved organic carbon (DOC), or total suspended solids (TSS) through the duration of events. A counter‐clockwise hysteresis response of DOC with increasing runoff contrasted with the clockwise response for total Hg, suggesting different contributions from source areas for these solutes. Correspondence with elevated total K and NO3? (α < 0·05) during the rising limb of the hydrograph suggests rapid delivery of throughfall Hg, potentially enhanced by hillslope hollows, to the stream channel. As the watershed saturated, stream Hg appears to be derived from the soil Hg pool. Results suggest that particulate Hg did not contribute substantially to total Hg flux during events (<25%). These results emphasize the role of watershed attributes and storm characteristics in Hg transport and bioavailability. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
35.
Quantifying biogeochemical cycles of nitrogen (N) and the associated fluxes to surface waters remains challenging, given the need to deal with spatial and temporal variability and to characterize complex and heterogeneous landscapes. We focused our study on catchments S14 and S15 located in the Adirondack Mountains of New York, USA, which have similar topographic and hydrologic characteristics but contrasting stream nitrate ( ) concentrations. We characterized the mechanisms by which reaches the streams during hydrological events in these catchments, aiming to reconcile our field data with our conceptual model of factors that regulate nutrient exports from forested catchments. Combined hydrometric, chemical and isotopic (δ ) data showed that the relative contributions of both soil and ground water sources were similar between the two catchments. Temporal patterns of stream chemistry were markedly different between S14 and S15, however, because the water sources in the two catchments have different solute concentrations. During late summer/fall, the largest source of in S14 was till groundwater, whereas shallow soil was the largest source in S15. concentrations in surface water decreased in S14, whereas they increased in S15 because an increasing proportion of stream flow was derived from shallow soil sources. During snowmelt, the largest sources of were in the near‐surface soil in both catchments. Concentrations of increased as stream discharge increased and usually peaked before peak discharge, when shallow soil water sources made the largest contribution to stream discharge. The timing of peaks in stream concentrations was affected by antecedent moisture conditions. By elucidating the factors that affect sources and transport of N, including differences in the soil nutrient cycling and hydrological characteristics of S14 and S15, this study contributes to the overall conceptualization of release from temperate forested catchments. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   
36.
A method has been developed for computing the gravitational force field of an axially symmetric flat galaxy from its surface mass density. The method is simple to program, fast, and accurate. An inversion formula is derived that allows computation of surface density from rotation curves by use of any method that converts density to force. The method is compared with a method of Clutton-Brock that utilizes Hankel transforms of Laguerre functions.  相似文献   
37.
The deflection of the velocity vector of a massless test star in the field of 100 stars was determined by numerical integration. The deflection due to each field star independently (with the other field stars removed) was also determined. The square of the deflection caused by the combined action of the field stars agreed quantitatively with the sum of the sauares of the individual deflections and also with the theoretical estimate of Williamson and Chandrasekhar.  相似文献   
38.
We performed computer experiments on 13 different initial configurations of one-dimensional self-gravitating systems. The three most and the three least violently relaxed systems were compared with the predictions of Lynden-Bell's statistical mechanics. The agreement between the experimental results and the theoretical predictions became worse as the relaxation became more violent. While all six systems were theoretically nondegenerate, the violent systems invariably flung out a halo that took most of the energy, leaving behind a low-energy degenerate core.  相似文献   
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