Deciphering factors controlling trace element distribution in the soils of Karaduvar industrial-agricultural area (Mersin,SE Turkey)

In this study, 30 topsoil samples were collected from Karaduvar area (Mersin, SE Turkey) where at present various industrial and agricultural activities are occurring. Using a five-step ultrasound-assisted sequential extraction (UASE) procedure, trace elements in soil samples were partitioned into the following: (1) soluble-exchangeable; (2) bound to carbonates; (3) bound to Fe- and Mn-oxides; (4) bound to organic matter and sulfide compounds, and (5) residual fraction. Concentrations of 11 trace elements in the extracts were determined using ICP-MS. Total concentrations ranged between (in mg kg⁻¹) 3.35 and 7.26 for As; 1.18 and 3.96 for Cd; 10.76 and 20.26 for Co; 37.99 and 63.48 for Cr; 18.55 and 243.1 for Cu; 338.7 and 565.6 for Mn; 4.42 and 6.44 for Mo; 148 and 279.3 for Ni; 10.12 and 73.71 for Pb; 17.93 and 36.55 for V, and 25.46 and 331.7 for Zn. Factor analysis was applied to dataset in order to discriminate between natural and anthropogenic pollution sources and factors controlling the spatial distribution of trace elements in the area. Results suggest that distributions of Co, Cr, Mn, and Ni are mainly controlled by lithological factors, whereas, distributions of Cu, Pb, and Zn can be attributed to agricultural activities such as pesticide/herbicide use and fertilizer application, as well as irrigation with petroleum hydrocarbon-contaminated groundwater. Highest concentrations of Cd and Mo are generally observed around the diesel-fired thermal power plant and ATAŞ refinery. Highest concentrations of As and V are generally observed at the NW sector of the area; however, no definitive source can be designated for both of these elements.     

The Effects of Groundwater Depth on the Soil Evaporation in Horqin Sandy Land,China

The interactions between groundwater depth and soil hydrological processes, play an important role in both arid and semi-arid ecosystems. The effect of groundwater depth on soil water variations were neglected or not explicitly treated. In this paper, we combine a simulation experiment and a water flow module of HYDRUS-1D model to study the variation in soil evaporation under different groundwater depth conditions and the relationship between groundwater depth and evaporation efficiency in Horqin Sandy Land, China.The results showed that with an increase in groundwater depth, the evaporation of soil and the recharge of groundwater decrease. In this study, the groundwater recharge did not account for more than 21% of the soil evaporation for the depths of groundwater examined. The soil water content at 60 cm was less affected by the evaporation efficiency when the mean groundwater depth was 61 cm during the experimental period. In addition, the evaporation efficiency(the ratio of actual evaporation to potential evaporation) decreases with the increase in groundwater depth during the experiment. Furthermore, the soil evaporation was not affected by groundwater when the groundwater depth was deeper than 239 cm.     

Multidecadal trend analysis of hydrological drought along River Niger using the Streamflow Drought Index

Droughts affect human well-being and the economy of countries across the world. Understanding the long-term evolution of droughts within a particular region will help in drought mitigation and adaptation plans, thereby reducing drought impact on the environment. This study examined the multidecadal trends in hydrological droughts at two stations along River Niger using 3-month, 6-month, and annual time scales. Hydrological drought events were identified using the streamflow drought index (SDI) between 1915 and 1990 based on the Theil-Sen slope and Mann-Kendall approaches. Across the timescales, extreme and severe droughts occurred in 1982/84 and 1983/84 with -2 ≤ S_d < -1.5. On an annual scale, the results from the annual SDI further showed that the 7th and 8th decades (1971−1990) recorded more drought events of varying degrees ranging from mild to extreme drought in both stations than in other decades. The last two decades (7th and 8th) further revealed the most extended hydrological drought duration from 1974/75 to 1988/89 for Baro and from 1979/80 to 1988/89 for Lokoja. The highest severity recorded at Baro was -15.56 and -14.26 at Lokoja. The prolonged duration of drought events across the stations and their associated yearly intensities suggests that more proactive measures are needed to ameliorate the hydrological drought impact in the study area.