A comparative analysis of eutrophication patterns in a temperate coastal lagoon

The coastal bays and lagoons of Maryland extend the full length of the state's Atlantic coast and compose a substantial ecosystem at the land-sea margin that is characterized by shallow depth, a well-mixed water column, slow exchange with the coastal ocean, and minimal freshwater input from the land. For at least 25 years, various types of measurements have been made intermittently in these systems, but almost no effort has been made to determine if water quality or habitat conditions have changed over the years or if distinctive spatial gradients in these features have developed in response to changing land uses. The purpose of this work was to examine this fragmented database and determine if such patterns have emerged and how they may be related to land uses. Turbidity, dissolved inorganic phosphate, algal biomass, and primary production rates in most areas of the coastal bays followed a regular seasonal pattern, which was well correlated with water temperature. Nitrate concentrations were low (<5 μM), and only modestly higher in tributary creeks (<20 μM). Additionally, there was little indication of the spring bloom typical of river-dominated systems. There does appear to be a strong spatial gradient in water quality conditions (more eutrophic in the upper bays, especially in tributary creeks). Comparisons of water quality data collected between 1970 and 1991 indicate little temporal change in most areas and some small improvements in a few areas, probably related to decreases in point-source discharges. Seagrass communities were once extensive in these systems but at present are restricted to the eastern portion of the lower bays where water clarity is sufficient to support plant survival. Even in these areas, seagrass densities have recently decreased. Examination of diel dissolved oxygen data collected in the summer indicates progressively larger diel excursions from lower to upper bays and from open bays to tributary subsystems; however, hypoxic conditions (<2 mg 1^?1) were rarely observed in any location. Nitrogen input data (point, surface runoff, groundwater and atmospheric deposition to surface waters) were assembled for seven regions of the coastal bay system; annual loading rates ranged from 2.4 g N m^?2 yr^?1 to 39.7 g N m^?2 yr^?1. Compared with a sampling of loading rates to other coastal systems, those to the upper and lower bays were low while those to tributaries were moderate to high. Regression analysis indicated significant relationships between annual nitrogen loading rates and average annual total nitrogen and chlorophyll a concentrations in the water column. Similar analyses also indicated significant relationships between chlorophyll a and the magnitude of diel dissolved oxygen changes in the water column. It is concluded that these simple models, which could be improved with a well-designed monitoring program, could be used as quantitative management tools to relate habitat conditions to nutrient loading rates.     

High (ground) water levels and dune development in central Australia: TL dates from gypsum and quartz dunes around Lake Lewis (Napperby), Northern Territory

An episode of high lake levels prior to the last maximum glaciation has been identified at many localities in wastern Australia. Similar events have been recognized at playa lakes in central Australia, where gypsum dunes along playa margins formed during one or more episodes of high groundwater discharge, with a large influx of calcium sulphate.At Lake Lewis, exposures at two islands show similar sediment sequences: three pedogenic gypcrete layers interbedded with aeolian quartz and gypsum sand horizons form three units within gypsum dunes up to 7 m high. The lowest unit has cliffed edges buried by the upper units, indicating a significant time break. Four TL dates (coarse-grained quartz) show that this lowest unit was deposited at or before 70–80 ka. The middle unit of mixed gypsum and quartz sand capped by gypcrete represents the major phase of gypsum dune formation, and 6 TL dates range from 33 to 46 ka with overlapping error bars. These are slightly younger but statistically similar to TL dates (from 39 to 59 ka) of the shoreline gypsum dune at Lake Amadeus in the same region. The top unit of the two islands, up to 1 m thick, has not yet been well dated. One date is inconsistent with the well dated middle layer below, possibly because of incomplete bleaching, and has been rejected. The other date (17 ± 5 ka) is much younger which possibly indicates a minor and local reactivation of old gypsum sediments. At the lake margin, there are quartz dunes overlying the gypsum dunes, and a buried aeolian quartz sand layer occurs in a lake-margin terrace. These represent reactivation of the regional quartz dune field after the major gypsum dune formation. Two consistent TL dates (21 ± 4 ka and 23 ± 6 ka) indicate that regional dunes were active at about the time of the Last Glacial Maximum.     

Population movement studied at microscale: Experience and extrapolation

The context for this paper is the nature of generalization deriving from the study of particular cases of human behaviour. With specific reference to field research on population movement conducted amongst individuals, households, small groups, and village communities in third world societies, it challenges the convention that both generalization and extrapolation are based inevitably and exclusively on the number of cases or events subject to examination. An evaluation is made of the methodological aspects of four different studies of population mobility at microscale, undertaken between 1965 and 1977 in the Solomon Islands and northwest Thailand. On this basis, integrated field designs that incorporate a range of intersecting instruments are favoured for their technical flexibility and logical strength. With case studies of third world villages, market centres, and urban neighbourhoods, generalization and extrapolation is based on depth of understanding and the power of theoretical connections.     

The oxidation state of manganese in marine sediments and ferromanganese nodules

Marine sediments and ferromanganese nodules from the Pacific Ocean have been analyzed for the $\text{O}\text{Mn}$ ratio of solid manganese. We tested six chemical methods and concluded that the iodometric and oxalate methods were equivalent and were the best choice in terms of accuracy and precision on natural samples. We choose the iodometric method for most of our analyses because the oxalate procedure is a method of differences.The ferromanganese nodules that we analyzed were all from MANOP site H and had $\text{Mn}\text{Fe}$ ratios that ranged from 5.6 to 70. These nodules were invariably highly oxidized with $\text{O}\text{Mn}$ values ranging from 1.90 to 2.00. Our most precise analyses suggest that less than 1% of the total manganese is present as Mn(II).We also analyzed red clay and hemipelagic sediments from the eastern tropical Pacific (Baja borderland and MANOP site H) and carbonate ooze samples from the equatorial Pacific. These sediments are also highly oxidized ($\text{O}\text{Mn}\text{= 1.90 to 2.00}$) except when Mn(II) appears in the interstitial water. As dissolved Mn(II) increases the value of the $\text{O}\text{Mn}$ ratio in the solid phase decreases. The $\text{O}\text{Mn}$ ratio decreases to values as low as 1.40. This decrease appears to be due to a decrease in oxidized manganese by reduction, however, an increase in reduced manganese in the solid sediments by adsorption or MnCO₃ formation can not be ruled out in all cases.     

Modelling the effect of vegetation on channel pattern in bedload rivers

We modify a simple numerical stream‐pattern model to examine the effect of sediment stabilization by roots on the channel pattern of bedload rivers. In the model, vegetation enhances bank resistance to erosion, causing the development of a single channel instead of a rapidly changing, multiple channel (braided) pattern. Net aggradation resulting from a high sediment supply, however, causes frequent avulsions that destroy vegetation locally, leading to the development of a multiple‐channel pattern. A stability diagram representing multiple model runs predicts whether a river will exhibit single or multiple channels, based on plant‐enhanced bank strength, and on the time scale of plant development relative to a time scale for change in unvegetated channels. A second stability diagram predicts the way in which the amplitude and period of a fluctuating imposed sediment load influence whether a single or multiple‐channel pattern develops. Copyright © 2003 John Wiley & Sons, Ltd.     

Assessing representation error in point-based coverage modeling

 Accurately representing geographic space in a digital environment continues to confound and challenge researchers. Carrying out spatial analysis in a setting where geographic representation is subject to change poses problems to be addressed. In this paper we examine spatial representation in the context of coverage-based location modeling. A geographic region can be represented in a variety of ways. We present an evaluation of spatial representation in the location of facilities that provide coverage oriented services. The analysis shows that the modeling results are sensitive to how spatial demand for service is represented in a digital environment. We develop an approach for evaluating representational appropriateness. This research contributes to spatial analysis integrated in geographic information system environment. Received: 10 January 2001 / Accepted: 8 April 2002     

Electrons in feldspar I: on the wavefunction of electrons trapped at simple lattice defects

 The purpose of this article is to make an initial consideration of the physical properties of electrons trapped at classic hydrogenic lattice defects in feldspar. We are particularly interested to determine the radial extent of the electron wavefunctions in the ground and excited states. It is shown that for NaAlSi₃O₈, the ground-state wavefunction is expected to be confined well within a single lattice unit cell, but the first excited state is far more extensive, being spread over several unit cells. This aspect is of direct relevance to understanding the nature of various luminescence processes in the materials. Under low-energy optical stimulation (hν∼ 1.4 eV), luminescence can be a competitive process between direct electron-hole tunnelling recombination (with the charge still trapped at the defect sites), and free-to-bound recombination (after the excited state electron accesses the conduction band). We show that analysis of the thermal behaviour of the luminescence can be used to separate the two processes. Received: 6 March 2001 / Accepted: 6 September 2001     

Evaluation and development of sustainable urban land use plans through spatial optimization

Along with rapid global urbanization, cities are challenged by environmental risks and resource scarcity. Sustainable urban planning is central to address the dilemma of economic growth and ecosystem protection, where the use of land is critical. Sustainable land use patterns are spatially explicit in nature, and can be structured and addressed using spatial optimization integrating GIS and mathematical models. This research discusses prominent sustainability concerns in land use planning and suggests a generalized multi‐objective spatial optimization model to facilitate conventional planning. The model is structured to meet land use demand while satisfying the requirements of the physical environment, society and economy. Unlike existing work relying on raster data, due to its simple data structure and ease of spatial relationship evaluation, this research develops an approach for identifying land use solutions based on vector data that better reflects the actual shape and spatial layout of land parcels as well as the ways land use information is managed in practice. An evolutionary algorithm is developed to find the set of efficient (Pareto) solutions given the complexity of vector‐based representations of space. The proposed approach is applied in an empirical study of Dafeng, China in order to support local urban growth and development. The results demonstrate that spatial optimization can be a powerful tool for deriving effective and efficient land use planning strategies. A comparison to results using a raster data approach supports the superiority of land use optimization using vector data as part of planning practice.