Paleo-ocean chemistry records in marine opal: Implications for fluxes of trace elements, cosmogenic nuclides (Be and Al), and biological productivity

Here, we provide evidence suggesting that marine (diatom) opal contains not only a high fidelity record of dissolved oceanic concentrations of cosmic ray-produced radionuclides, ¹⁰Be and ²⁶Al, but also a record of temporal variations in a large number of trace elements such as Ti, Fe, Zn and Mn. This finding is derived from measurements in purified biogenic opal that can be separated from detrital materials using a newly developed technique based on surface charge characteristics. Initial results from a sediment core taken near the present-day position of the Antarctic Polar Front (ODP Site 1093) show dramatic changes in the intrinsic concentrations of, Be, Al, Ti, Fe, Mn and Zn in the opal assemblages during the past ∼140 kyr BP. The results imply appreciable climatically controlled fluctuations in the level of bioreactive trace elements. The time series of total Be, Al, Ti, Fe and ¹⁰Be in the sediment core are all well correlated with each other and with dust records in the polar ice cores. The observations suggest that a significant flux of these trace metals to oceans is contributed by the aeolian dust, in this case, presumably from the Patagonia. This observation also allows determination of fluxes of dust-contributed ¹⁰Be to the Antarctica ice sheets. However, our data show that the relationships among the various metals are not perfectly linear. During periods of higher dissolved concentrations of trace elements (indicated by Fe and Ti) the relative concentrations of bioreactive elements, Be, Al, Mn and Zn are decreased. By contrast, the Fe/Zn and Fe/Mn ratios decrease significantly during each transition from cold to warm periods. The relative behavior could be consistent with any of the following processes: (i) enhanced biological productivity due to greater supply of the bioreactive elements (e.g. Zn) during cold periods (ii) increased biological and inorganic scavenging of particle active elements (e.g. Be and Al) during early interglacial periods (iii) differential uptake/removal of the metals by the various diatom taxa whose relative productivity or growth rate changes with large scale climate. In any case, with one sedimentary phase and in single sedimentary sections, we now have the potential to compare directly a proxy for aeolian input of micronutrients (e.g. Fe or Ti), with a proxy for production (e.g. ²⁶Al/Al ratios). We expect that studies of the temporal records of trace elements and cosmogenic nuclides in contrasting regions of upwelling and productivity, which exhibit different sensitivities to global climate fluctuations and micronutrient inputs, would lead to a direct and comprehensive test of ideas such as the hypothesis of iron control of atmospheric carbon dioxide [Martin, J.H., 1990. Glacial-interglacial CO₂ change: the iron hypothesis. Paleoceanography5, 1-13]. Our present data from a single site do not show that increases in dissolved Fe concentrations, per se, were responsible for increased biological productivity. However, a much clearer picture of the effect of increased dust fluxes should emerge when we have data for trace elements and the cosmogenic nuclides, ¹⁰Be and ²⁶Al from various oceanic provinces.     

Zircon and sphene as fission track geochronometer and geothermometer: A reappraisal

The data published earlier on zircon and sphene fission track ages and annealing are discussed in the light of different etching conditions used for age determination and annealing experiments in order to explain the age discordances of some zircon and sphene pairs, as well as numerous closing temperatures obtained for individual minerals. Using the new set of simple etching conditions, zircon (KOH melt) and sphene (HF+HCl), the annealing experiments indicate that tracks in sphene are annealed more easily than in zircon. The closing temperature of zircon and sphene have been calculated at 300° and 250° C respectively. The study reveals that both the fission track age and the closing temperature of a mineral can vary considerably if different etchants are used. For different etching conditions the closing temperatures (T) of sphene have the following order: ^T NaOH> ^T HF+HCl+HNO₃+H₂O> ^THF+HCl>^THCl. An alternative method can be used to obtain thermal histories of rocks by selectively applying various etchants on the same mineral.     

Coexisting chloritoid-staurolite from the Sillimanite (fibrolite) zone,Sini, district Singhbhum,India

Microprobe analyses of the minerals from an unusual chloritoid-staurolite-garnet (+ muscovite + quartz + ilmenite) assemblage from the sillimanite (fibrolite) zone of Sini, India are presented and the petrological significance of the paragenesis is discussed. The X Mg in the different minerals from the chloritoid-staurolite-bearing rock varies in the order, muscovite > chlorite > chloritoid > staurolite > garnet > ilmenite, and from the associated sillimanite-bearing schists: muscovite > biotite > staurolite > garnet rim > garnet core > ilmenite. A graphical representation of the mineral compositions in an AFM projection displays a consistent topology if the effects of non-AFM components such as Zn in the staurolite and Mn in the garnet are taken into account. Petrographic and mineralogical data are consistent with a prograde formation of the chloritoid-staurolite-garnet assemblage. It is suggested that the paragenesis has been formed at similar PT conditions to the associated sillimanite (fibrolite)-staurolite-garnet-mica schists. These conditions are estimated to be 600–625°C/6±0.5 Kb.     

An evaluation of the universal soil loss equation and field techniques for assessing soil erosion on a tropical alfisol in western Nigeria

Four techniques for soil erosion assessment were compared over two consecutive seasons for bare-fallow plots and a maize-cowpea sequence in 1985 at IITA, Ibadan, Nigeria. The techniques used were: tracer (aluminium paint), nails (16 and 25), the rill method, and the Universal Soil Loss Equation (USLE). Soil loss estimated by these techniques was compared with that determined using the runoff plot technique. There was significantly more soil loss (P < 0·01) in bare-fallow than in plots under maize (Zea mays) or cowpea (Vigna unguiculata). In the first season, soil loss from plots sown to maize was 40·2 Mg ha^?1 compared with 153·3 Mg ha^?1 from bare-fallow plots. In the second season, bare-fallow plots lost 87·5 Mg ha^?1 against 39·4 Mg ha^?1 lost from plots growing cowpea. The techniques used for assessing erosion had no influence on the magnitude of soil erosion and did not interfere with the processes of erosion. There was no significant difference (P < 0·05) between soil erosion determined by the nails and the runoff plot technique. Soil loss determined on six plots (three under maize, three bare-fallow) by the rill technique, at the end of the season, was significantly lower (P < 0·05) than that determined by the runoff plot technique. The soil loss estimated by the rill method was 143·2, 108·8 and 121·9 Mg ha^?1 for 11, 11, and 8 per cent slopes respectively, in comparison with 201·5, 162·0, and 166·4 Mg ha^?1 measured by the runoff plot method. Soil loss measured on three bare-fallow plots on 10 different dates by the rill technique was also significantly lower (P < 0·01) than that measured by the runoff plot. In the first season the USLE significantly underestimated soil loss. On 11, 11, and 8 per cent slopes, respectively, soil loss determined by the USLE was 77, 92, and 63 per cent of that measured by the runoff plot. However, in the second season there was no significant difference between soil loss determined by the USLE and that determined by the conventional runoff plot technique.     

Holocene Sea Levels and Coastal Change,South-west Viti Levu Island,Fiji

For the first time, a sediment core spanning the entire Holocene has been analysed from Fiji. The 6 m core was obtained from the floor of an ancient coastal lagoon (palaeolagoon) adjacent to Bourewa, the site of the earliest known human settlement in this island group. The basal sediments, just above bedrock, date from 11 470 cal bp. A major transition occurs around 8000 cal bp where marine influences on palaeolagoon sedimentation increase sharply. Full shallow-water marine conditions are attained around 4630 cal bp and last until 3480 cal bp after which there is a regressive phase. The results agree with the area-specific predictions of sea level in the ICE-4G model, particularly in the timing of the highstand. In addition, the results support the ideas (a) that early human colonisation of Fiji occurred during the late Holocene regression, (b) that the first inhabitants of Bourewa utilised both nearshore marine (reefal) and brackish lagoon food sources, and (c) that the abrupt human abandonment of the area around 2500 cal bp could have been prompted by a reduction in these resources driven largely by sea-level fall.     

Land use intensity dynamics in the Andhikhola watershed,middle hill of Nepal

Land use intensity is a valuable concept to understand integrated land use system, which is unlike the traditional approach of analysis that often examines one or a few aspects of land use disregarding multidimensionality of the intensification process in the complex land system. Land use intensity is based on an integrative conceptual framework focusing on both inputs to and outputs from the land. Geographers' non-stationary data-analysis technique is very suitable for most of the spatial data analysis. Our study was carried out in the northeast part of the Andhikhola watershed lying in the Middle Hills of Nepal, where over the last two decades, heavy loss of labor due to outmigration of rural farmers and increasing urbanization in the relatively easy accessible lowland areas has caused agricultural land abandonment. Our intention in this study was to ascertain factors of spatial pattern of intensity dynamism between human and nature relationships in the integrated traditional agricultural system. High resolution aerial photo and multispectral satellite image were used to derive data on land use and land cover. In addition, field verification, information collected from the field and census report were other data sources. Explanatory variables were derived from those digital and analogue data. Ordinary Least Square(OLS) technique was used for filtering of the variables. Geographically Weighted Regression(GWR) model was used to identify major determining factors of land use intensity dynamics. Moran's I technique was used for model validation. GWR model was executed to identify the strength of explanatory variables explaining change of land use intensity. Accordingly, 10 variables were identified having the greatest strength to explain land use intensity change in the study area, of which physical variables such as slope gradient, temperature and solar radiation revealed the highest strength followed by variables of accessibility and natural resource. Depopulation in recent decades has been a major driver of land use intensity change but spatial variability of land use intensity was highly controlled by physical suitability, accessibility and availability of natural resources.     

Equilibrium structure of differentially rotating polytropic models of the stars

In this paper we propose a method for computing the equilibrium structure of differentially rotating polytropic models of the stars. A general law of differential rotation of the type ²=b ₀+b ₁ s ²+b ₂ s ⁴, which can account for a reasonably large variety of possible differential rotations in the stars has been used. The distortional effects have been incorporated in the structure equations up to second order of smallness in distortion parametersb ₀,b ₁, andb ₂ using Kippenhahn and Thomas' averaging approach in conjunction with Kopal's results on Roche equipotentials in manner similar to the one earlier used by Mohan and Saxena for computing the equilibrium structure of polytropes having solid body rotation. Numerical results have been obtained for various types of differentially rotating polytropic models of stars of polytropic indices 1.5, 3, and 4. Certain differentially rotating models of the Sun which are possible with such a type of law of differential rotation, have also been computed.     

On the origin of transient effects in the solar neutrino experiment

Correlation studies of the pattern of time variation of the recorded solar neutrino flux monitored through the reaction Cl³⁷ → Ar³⁷ with various parameters of solar activity is suggestive of possible emission of a penetrating neutral particle from the sun influencing directly or indirectly the transformation Cl³⁷ → Ar³⁷ deep underground at the required rates. This possibility has to be invoked in view of the difficulties in generating the observed pattern of variations through a large modulatory mechanism involving the electron neutrino. The prediction that follows is the possible existence of a time varying component (diurnal) in the rate of some nuclear transmutations deep underground caused by an unknown neutral radiation having an interaction cross section with matter probably much larger than the canonical value of 10^-36 cm² per nucleon speculated upon by some authors in the WIMP scenario for the sun.     

Climatic forcing before,during, and after the 8.2 Kyr B.P. global cooling event

This paper attempts at full characterization of the unique global 8.2 Kyr B.P. cooling event. Significant atmospheric cooling started during 9.5–8.5 Kyr B.P. when the Sun was extremely quiet during three periods of ∼ 50–100 years. The flood of melt water in the N. Atlantic from glacial lakes during the demise of the Laurentide ice sheet, starting at ∼ 8.5 Kyr B.P., adds to the atmospheric cooling. Climatic forcing events occurred at 8.5 Kyr B.P., at 8.2 Kyr B.P. and finally at 8.06 Kyr B.P., leading to concurrent increases or decreases in the atmospheric Δ¹⁴C levels, completely consistent with the climatic forcing proposed here.