Diverse Range of Mineralization Induced by Phase Separation of Hydrothermal Fluid: Case Study of the Yonaguni Knoll IV Hydrothermal Field in the Okinawa Trough Back-Arc Basin

The Yonaguni Knoll IV hydrothermal vent field (24°51′N, 122°42′E) is located at water depths of 1370–1385 m near the western edge of the southern Okinawa Trough. During the YK03–05 and YK04–05 expeditions using the submersible Shinkai 6500, both hydrothermal precipitates (sulfide/sulfate/carbonate) and high temperature fluids (Tmax = 328°C) presently venting from chimney‐mound structures were extensively sampled. The collected venting fluids had a wide range of chemistry (Cl concentration 376–635 mmol kg^?1), which is considered as evidence for sub‐seafloor phase separation. While the Cl‐enriched smoky black fluids were venting from two adjacent chimney‐mound structures in the hydrothermal center, the clear transparent fluids sometimes containing CO₂ droplet were found in the peripheral area of the field. This distribution pattern could be explained by migration of the vapor‐rich hydrothermal fluid within a porous sediment layer after the sub‐seafloor phase separation. The collected hydrothermal precipitates demonstrated a diverse range of mineralization, which can be classified into five groups: (i) anhydrite‐rich chimneys, immature precipitates including sulfide disseminations in anhydrite; (ii) massive Zn‐Pb‐Cu sulfides, consisting of sphalerite, wurtzite, galena, chalcopyrite, pyrite, and marcasite; (iii) Ba‐As chimneys, composed of barite with sulfide disseminations, sometimes associated with realgar and orpiment overgrowth; (iv) Mn‐rich chimneys, consisting of carbonates (calcite and magnesite) and sulfides (sphalerite, galena, chalcopyrite, alabandite, and minor amount of tennantite and enargite); and (v) pavement, silicified sediment including abundant native sulfur or barite. Sulfide/sulfate mineralization (groups i–iii) was found in the chimney–mound structure associated with vapor‐loss (Cl‐enriched) fluid venting. In contrast, the sulfide/carbonate mineralization (group iv) was specifically found in the chimneys where vapor‐rich (Cl‐depleted) fluid venting is expected, and the pavement (group v) was associated with diffusive venting from the seafloor sediment. This correspondence strongly suggests that the subseafloor phase separation plays an important role in the diverse range of mineralization in the Yonaguni IV field. The observed sulfide mineral assemblage was consistent with the sulfur fugacity calculated from the FeS content in sphalerite/wurtzite and the fluid temperature for each site, which suggests that the shift of the sulfur fugacity due to participation of volatile species during phase separation is an important factor to induce diverse mineralization. In contrast, carbonate mineralization is attributed to the significant mixing of vapor‐rich hydrothermal fluid and seawater. A submarine hydrothermal system within a back‐arc basin in the continental margin may be considered as developed in a geologic setting favorable to a diverse range of mineralization, where relatively shallow water depth induces sub‐seafloor phase separation of hydrothermal fluid, and sediment accumulation could enhance migration of the vapor‐rich hydrothermal fluid.     

Landfill development in the urban fringe of Metro Manila

In low-lying areas of urban and suburban regions in Asia, the use of landfill has allowed urban land use to encroach onto watery landforms, such as back marshes, which were formerly used as rice fields. To improve understanding of the associations between land-use patterns and landfill development, we carried out a case study in the urban fringe of Metro Manila in the Philippines. We examined landfill volume derived from land-use change using GIS, and field surveyed qualitative aspects of the landfill used. We calculated the rate of application of landfill in low-lying housing development areas to be 5.0 × 10³ m³ km^?2 year^?1, most of which consisted of offsite disposal of construction waste or crushed rock produced by urban development and renewal on the adjoining uplands. The flow of fill material from offsite sources to onsite landfill development areas was on the basis of individual agreements between suppliers and developers.     

The development of Fe-nodules surrounding biological material mediated by microorganisms

Takashikozo is a phenomenon of Quaternary sediments in Japan. They are cylindrical Fe-oxyhydroxide nodules that form as plaques round plant roots, where Fe is preferentially concentrated to develop a solid wall. Structural features suggest that after the roots have decayed, the central space where the roots were situated acts as a flow path for oxidized water. Analysis of microbial 16S rDNA extracted from the nodules identified iron-oxidizing bacteria encrusted round the roots where they are the likely initiators of nodule formation. Direct microscopic observation revealed an accumulation of Fe-oxyhydroxides that fill the pore spaces and is also likely to be linked with the encrusting microbial colonies. Geological history and nanofossil evidence suggest that these Fe-nodules may have been buried at a depth of up to several tens of meters for at least 10⁵ years in reducing Quaternary sediments. Thus Fe-oxyhydroxide nodules that have formed in a geological environment at the interfaces between water and rock by microbial mediation can persist under reducing conditions. If this is the case, the phenomenon is significant as an analogue of post-closure conditions in radioactive waste repositories, since it could influence nuclide migration.     

Trans-boundary and in-country transport of air pollutants observed in Kobe,Japan by high frequent filter pack sampling method

The seasonal intensive sampling of gases and particulate matter in ambient air was conducted at the site established in urban area of Japan to study the seasonal difference of the temporal variation of gases and particulate matter concentrations in urban atmosphere as well as to illustrate the different transport regimes that impacts air pollutants. The sample was collected by the four-stage filter-pack method with 6-h interval for one week in four seasons (spring, summer, autumn and winter). The trans-boundary transport of air pollutants with high concentration was characteristically observed in the spring sampling. On the other hand, we could successfully detect the in-country transports of air pollutants in the summer sampling. Four-season’s intensive survey considered, we could show the characteristic transport of air pollutants to provide the episodic high concentration for ambient air in the urban area of Japan, and successfully illustrate the seasonal-dependent transport regimes to impact on air pollutants.     

High-temperature thermal expansion and elasticity of calcium-rich garnets

We present new high temperature elasticity data on two grossular garnet specimens. One specimen is single-crystal, of nearly endmember grossular, the other is polycrystalline with about 22% molar andradite. Our data extend the high temperature regime for which any garnet elasticity data are available from 1000 to 1350 K and the compositional range of temperature data to near endmember grossular. We also present new data on the thermal expansivity of calcium-rich garnet. We find virtually no discernable differences in the temperatureT derivatives at ambient conditions of the isotropic bulkK _S and shearμ moduli when comparing our results between these two specimens. These calcium-rich garnets have the lowest values of ¦(?K _S /?T) _P ¦ = (1.47,1.49) x 10^-2GPa/K, and among the highest values of ¦(?μ/?T) _P ¦ = 1.25 x 10^-2GPa/K, when compared with other garnets. Small, but measurable, nonlinear temperature dependences of most of the elastic moduli are observed. Several dimensionless parameters are computed with the new data and used to illustrate the effects of different assumptions on elastic equations of state extra-polated to high temperatures. We discuss how dimensionless parameters and other systematic considerations can be useful in estimating the temperature dependence of some properties of garnet phases for which temperature data are not yet available. While we believe it is premature to quantitatively predict the temperature variation ofK _S andμ for majorite garnets, our results have bearing on the amount of diopside required to explain the shear velocity gradients in Earth's transition zone.     

Back-arc rifting in the Izu-Bonin Island Arc: Structural evolution of Hachijo and Aoga Shima Rifts

Abstract Multi- and single-channel seismic profiles are used to investigate the structural evolution of back-arc rifting in the intra-oceanic Izu-Bonin Arc. Hachijo and Aoga Shima Rifts, located west of the Izu-Bonin frontal arc, are bounded along-strike by structural and volcanic highs west of Kurose Hole, North Aoga Shima Caldera and Myojin Sho arc volcanoes. Zig-zag and curvilinear faults subdivide the rifts longitudinally into an arc margin (AM), inner rift, outer rift and proto-remnant arc margin (PRA). Hachijo Rift is 65 km long and 20–40 km wide. Aoga Shima Rift is 70 km long and up to 45 km wide. Large-offset border fault zones, with convex and concave dip slopes and uplifted rift flanks, occur along the east (AM) side of the Hachijo Rift and along the west (PRA) side of the Aoga Shima Rift. No cross-rift structures are observed at the transfer zone between these two regions; differential strain may be accommodated by interdigitating rift-parallel faults rather than by strike- or oblique-slip faults. In the Aoga Shima Rift, a 12 km long flank uplift, facing the flank uplift of the PRA, extends northeast from beneath the Myojin Knoll Caldera. Fore-arc sedimentary sequences onlap this uplift creating an unconformity that constrains rift onset to ～1-2Ma. Estimates of extension (～3km) and inferred age suggest that these rifts are in the early syn-rift stage of back-arc formation. A two-stage evolution of early back-arc structural evolution is proposed: initially, half-graben form with synthetically faulted, structural rollovers (ramping side of the half-graben) dipping towards zig-zagging large-offset border fault zones. The half-graben asymmetry alternates sides along-strike. The present ‘full-graben’ stage is dominated by rift-parallel hanging wall collapse and by antithetic faulting that concentrates subsidence in an inner rift. Structurally controlled back-arc magmatism occurs within the rift and PRA during both stages. Significant complications to this simple model occur in the Aoga Shima Rift where the east-dipping half-graben dips away from the flank uplift along the PRA. A linear zone of weakness caused by the greater temperatures and crustal thickness along the arc volcanic line controls the initial locus of rifting. Rifts are better developed between the arc edifices; intrusions may be accommodating extensional strain adjacent to the arc volcanoes. Pre-existing structures have little influence on rift evolution; the rifts cut across large structural and volcanic highs west of the North Aoga Shima Caldera and Aoga Shima. Large, rift-elongate volcanic ridges, usually extruded within the most extended inner rift between arc volcanoes, may be the precursors of sea floor spreading. As extension continues, the fissure ridges may become spreading cells and propagate toward the ends of the rifts (adjacent to the arc volcanoes), eventually coalescing with those in adjacent rift basins to form a continuous spreading centre. Analysis of the rift fault patterns suggests an extension direction of N80°E ± 10° that is orthogonal to the trend of the active volcanic arc (N10°W). The zig-zag pattern of border faults may indicate orthorhombic fault formation in response to this extension. Elongation of arc volcanic constructs may also be developed along one set of the possible orthorhombic orientations. Border fault formation may modify the regional stress field locally within the rift basin resulting in the formation of rift-parallel faults and emplacement of rift-parallel volcanic ridges. The border faults dip 45–55° near the surface and the majority of the basin subsidence is accommodated by only a few of these faults. Distinct border fault reflections decreases dips to only 30° at 2.5 km below the sea floor (possibly flattening to near horizontal at 2.8 km although the overlying rollover geometry shows a deeper detachment) suggesting that these rifting structures may be detached at extremely shallow crustal levels.     

The Trobriand Subduction System in the Western Solomon Sea

A south-dipping Subduction system which underlies the Trobriand Trough and 149° Embayment, on the southern margin of the Solomon Sea, is active or was recently active. Oceanic basement is overlain by 2.5 s, two-way travel time (TWTT), of sediment that shows at least two stages of deformation: early thrusts (inner wall) and normal faults (outer wall), and later normal faults that have elevated the outer trench margin. Thrust anticlines and slope basins are developed on the inner wall. The floor of the Solomon Sea Basin arches upward between the Trobriand Trough and the New Britain Trench to form isolated peaks and ridges in the east (152° Peaks) and an east-west Central Ridge in the west. Structures in the subduction system, and in the Solomon Sea Basin, plunge westward towards the point of collision with the New Britain Trench.     

Acetylene reducing activity at a tropical seagrass bed in Papua New Guinea

Acetylene reduction activity at a tropical seagrass bed in Papua New Guinea was studied. Blades of every species of seagrass studied (Enhalus acoroides, Thalassia hemprichii, Halodule uninervis, Syringodium isoetifolium) at the bed showed active acetylene reduction in the rage of 0.025–0.050 mol cm^–2d^–1. It is suggested that epiphytic blue-green algae would be responsible for active acetylene reduction. Acetylene reducing activity was observed also at rhizosphere of seagrasses, microbial communities on the detritus and periphyton on snail shells. It is estimated that total nitrogen fixed at the seagrass bed will be equivalent to 6.7% of that required for the growth of seagrasses.