NMR Measurements in Carbonate Rocks: Problems and an Approach to a Solution

Carbonate rocks are well known for their complex petrophysical behavior where, in contrast to siliciclastic rocks, different parameters, including porosity and permeability, usually are not directly related. This behavior is the result of thorough reorganization of porosity during diagenesis, and it turns prediction of reservoir quality of carbonate rocks into a challenge. The study presented here deals with the problem of utilizing NMR techniques in prediction of petrophysical properties in carbonates.We employ a visual porosity classification as a priori knowledge for better interpreting NMR data for prediction purposes. This allows for choice of suitable T₂ cutoff values to differentiate movable from bound fluids adapted for the specific carbonate rock, thus resulting in better interpretation of NMR data. The approach of using a genetic pore type classification for adapting the conventional method for T₂ cutoff determination, which originally was developed for siliciclastic rocks, is promising. Similarly, for permeability determination on the basis of NMR measurements, the classification of carbonate rocks based on porosity types also shows potential. The approach implemented here has the promise to provide a basis of standardized interpretation of NMR data from carbonate rocks.Acknowledgment We are grateful to Baker Hughes INTEQ, Celle, for permission to publish the results of this work. This study was part of I.S.s Masters Thesis at Hannover University that was carried out in collaboration with Baker Hughes INTEQ, Celle, Germany. We appreciate comments of an anonymous referee and PAGEOPH editor Brian J. Mitchell.     

Effects of 12 years' operation of a sewage treatment plant on trace metal occurrence within a Mediterranean commercial sponge (Spongia officinalis, Demospongiae)

The present field study uses Spongia officinalis for assessing trace metals occurrence in time and space within Mediterranean rocky communities. Nine sites were selected in the Marseille area for studying spatial trends in 12 metal concentrations. Long term changes in 8 metal concentrations were assessed at sites that had been sampled before and 12 years after the opening of a treatment plant. Spongia officinalis highly concentrated all the trace metal surveyed excepted Hg and Cd. The overall contamination level registered provided a classification of the study sites which is congruent with that given by other studies on pollutant accumulation in neighbouring sandy-bottoms or benthic assemblages. Among the metals studied, Fe, Pb, Cr are those that best highlighted a pollution gradient. In the present study, only Cd concentration did not vary in space. Except for Ni, all pollutant concentrations clearly decreased between 1984 and 1999. This very impressive decrease in heavy metal concentrations within the Marseille area represents an indisputable evidence of the improvement of the seawater quality resulting from 12 years' operation of the Marseille sewage plant. Moreover, the significant decrease also recorded in the reference population at Port-Cros might reflect an overall improvement in the seawater quality of the NW Mediterranean.     

MAG Waves in Sunspots Umbrae: Slow Waves Leaking to the Corona

The linear oscillations of a stratified atmosphere embedded in a uniform vertical magnetic field are studied here. We use a simple theoretical model, formed by the superposition of two isothermal layers, representing, respectively, i) the photosphere and the chromosphere, and ii) the corona. The bottom layer behaves, for some modes, as a resonant cavity where MAG waves are semi-trapped. We find the existence of two types of modes: 1) Fast modes which are trapped below the transition layer, 2) Mixed modes which are resonant modes in the first layer and leak part of the energy to the corona. These mixed modes have been found to be damped in the horizontal direction and can explain the observed slow modes in the corona.     

Freshwater Ostracodes in Quaternary Permafrost Deposits in the Siberian Arctic

Ostracode analysis was carried out on samples from ice-rich permafrost deposits obtained on the Bykovsky Peninsula (Laptev Sea). A composite profile was investigated that covers most of a 38-m thick permafrost sequence and corresponds to the last ca. 60 kyr of the Late Quaternary. The ostracode assemblages are similar to those known from European Quaternary lake deposits during cold stages. The ostracode habitats were small, shallow, cold, oligotrophic pools located in low centred ice wedge polygons or in small thermokarst depressions. In total, 15 taxa, representing 7 genera, were identified from 65 samples. The studied section is subdivided into six ostracode zones that correspond to Late Quaternary climatic and environmental stadial-interstadial variations established by other paleoenvironmental proxies: (1) cold and dry Zyrianian stadial (58–53 kyr BP); (2) warm and dry Karginian interstadial (48–34 kyr BP); (3) transition from the Karginian interstadial to the cold and dry Sartanian stadial (34–21 kyr BP); (4) transition from the Sartanian stadial to the warm and dry Late Pleistocene period, the Allerød (21–14 kyr BP); (5) transition from the Allerød to the warm and wet Middle Holocene (14–7 kyr BP); and (6) cool and wet Late Holocene (ca. 3 kyr BP). The abundance and diversity of the ostracodes will be used as an additional bioindicator for paleoenvironmental reconstructions of the Siberian Arctic.     

3D seismic study of a ductile shear zone from laboratory and petrofabric data (Saint Barthélémy Massif, Northern Pyrenees, France)

In order to constrain interpretations of seismic reflection records more effectively, the seismic properties of a middle crustal section exposed in the Saint Barthélémy Massif have been determined. The massif, transected by a 200 m thick shear zone has been systematically sampled for density measurements and modal analysis has been performed in order to define the spatial variations of physical properties. Seismic velocities ( V _p, V _S, shear wave birefringence), have been measured on five representative samples to 600 MPa and 600°C simultaneously in the three structural directions (X, Y and Z). For two samples, the experimental data have been compared with calculated values, based on petrofabric analyses. The Lattice Preferred Orientation (LPO) is determined using universal stage, electron channelling microscopy and neutron diffraction goniometry. Using the experimental and calculated velocity data, we establish a lateral homogeneous anisotropic model.     

Planetary theories with the aid of the expansions of elliptic functions

For coplanar circular orbits, the mutual perturbations between two bodies can be expressed in term of the argument of Jacobian elliptic functions instead of the difference of the mean longitudes. For a given pair of planets, such a change of time variable improves the convergence of the developments. At the first order of planetary masses an integration of Lagrange's equations for the osculating elements is performed. When compared to classical developments the results are reduced by an important factor. The method is then extended to the mutual perturbations of Jupiter and Saturn, at any order of planetary masses, either with Fourier series with two arguments, or with one argument solely, taking advantage of the close commensurability of the mean motions.     

Alternate schemes in synthetic aperture sonar processing

Suboptimal processing schemes, the application of which is not widespread in synthetic aperture sonar processing, are described with reference to seafloor imaging. It is shown that their application can result in a significant increase of the azimuth resolution of the sonar system with respect to the resolution due to its physical beamwidth, without imposing unreasonable constraints on the sonar platform trajectory.