动力学模型预测深海鲣鱼(Katsuwonus pelamis)调理食品常温下的货架期

为了预测鲣鱼(Katsuwonus pelamis)调理食品的货架期,将鲣鱼调理食品贮藏在25°C、30°C、35°C温度条件下,通过测定在贮藏期间菌落总数、挥发性盐基氮、过氧化值三个指标的变化,分别对这三个指标与贮藏时间、温度建立一级动力学模型,来预测鲣鱼调理食品的货架期。经计算得出,菌落总数预测模型中的活化能(Ea)及指前因子(k0)分别为30.96 k J/mol和2.06×103,挥发性盐基氮预测模型中的的活化能及指前因子分别为24.35 k J/mol和75.1,过氧化值预测模型中的活化能及指前因子分别为48.75 k J/mol和2.92×106。在32°C和37°C条件下验证动力学模型,结果表明相对误差分别为–5.52%和–6.45%,准确性较好。进一步推算得出,在18°C和23°C常温下贮藏鲣鱼调理食品,产品的货架期为209d和172d。     

Area usage estimation and spatiotemporal variability in distribution patterns of southern right whales,Eubalaena australis,of southern Brazil

Southern right whales—Eubalaena australis (Desmoulins, 1822)—migrate seasonally from high‐latitude feeding grounds to coastal breeding and calving grounds at lower latitudes such as the southern coast of Brazil. Understanding how these whales are distributed along the coast is important for monitoring their postwhaling recovery and defining management strategies. In this study, we applied Kernel density estimators to aerial survey data to determine main occurrence and concentration areas of right whales in southern Brazil and investigate inter‐ and intra‐annual distribution patterns between 2003 and 2012. Our results show considerable variation in area usage within and among years, and changes in the general distribution pattern of right whales in the last years of the study. Intra‐annually, higher concentration area tended to expand from July to September and decrease in November. Some areas stood out as high‐density areas for right whales: Ribanceira/Ibiraquera, Itapirubá Sul/Sol, and from Arroio to Gaivota. Some evidences also suggest preferential areas for mother–calf pairs. The higher concentration area of right whales in southern Brazil was estimated at 52,541 km² and the occurrence area was 682.69 km², which is the whole study area. As right whale distribution in the region is likely expanding due to this population's current recovery, our study provides essential information for management plan of the Right Whale Environmental Protection Area.     

Complex multiple cosmogenic nuclide concentration and histories in the arid Rio Lluta catchment,northern Chile

Terrestrial cosmogenic nuclide (TCN) concentrations measured in river sediments can be used to estimate catchment‐wide denudation rates. By investigating multiple TCN the steadiness of sediment generation, transport and depositional processes can be tested. Measurements of ¹⁰Be, ²¹Ne and ²⁶Al from the hyper‐ to semi‐arid Rio Lluta catchment, northern Chile, yield average single denudation rates ranging from 12 to 75 m Myr^–1 throughout the catchment. Paired nuclide analysis reveals complex exposure histories for most of the samples and thus the single nuclide estimates do not exclusively represent catchment‐wide denudation rates. The lower range of single nuclide denudation rates (12–17 m Myr^–1), established with the noble gas ²¹Ne, is in accordance with palaeodenudation rates derived from ²¹Ne/¹⁰Be and ²⁶Al/¹⁰Be ratio analysis. Since this denudation rate range is measured throughout the system, it is suggested that a headwater signal is transported downstream but modulated by a complex admixture of sediment that has been stored and buried at proximal hillslope or terrace deposits, which are released during high discharge events. That is best evidenced by the stable nuclide ²¹Ne, which preserves the nuclide concentration even during storage intervals. The catchment‐wide single ²¹Ne denudation rates and the palaeodenuation rates contrast with previous TCN‐derived erosion rates from bedrock exposures at hillslope interfluves by being at least one order of magnitude higher, especially in the lower river course. These results support earlier studies that identified a coupling of erosional processes in the Western Cordillera contrasting with decoupled processes in the Western Escarpment and in the Coastal Cordillera. Copyright © 2008 John Wiley & Sons, Ltd.     

东南极格罗夫山变基性岩初步研究

东南极格罗夫山存在一套经历了峰期麻粒岩相变质作用的镁铁质麻粒岩和斜长角闪岩。对含石榴石的镁铁质麻粒岩的详细研究则显示了近等温降压 (ITD)的顺时针PT演化轨迹 ,与拉斯曼丘陵有相似的演化历史。岩石的主量元素组成和玄武岩一致 ,并且具有拉斑玄武岩演化趋势。进一步的地球化学研究表明 ,这套玄武岩为洋岛型玄武岩 (OIB)和洋中脊型玄武岩(MORB)的组合。OIB型具有大体类似的地球化学性质 ,它们均富集Ti(TiO2 =2 .68% )、REE( =2 0 2 μg/g)、LREE[(La/Yb) N=4.8]、Ti/Y( =343)、Zr/Y( =3.1 ) ,具洋岛玄武岩的特征 ,推测岩浆来源于富集地幔源区 (EM)。而MORB型以低Ti (TiO2 =1 .1 %— 1 .31 % ) ,明显低于OIB的P的含量 (P2 O5=0 .1 %— 0 .2 % ) ,低REE ( 4 7— 93μg/g)、LREE/HREE( 2 .2 7— 2 .5 4 )、(La/Yb) N( =1 .30— 1 .62 )为特征 ,具洋中脊玄武岩的特征。MORB和OIB组合的出现说明在泛非期该区可能存在过洋盆。     

Impact of subsurface rock fragments on runoff and interrill soil loss from cultivated soils

Field and laboratory studies have indicated that rock fragments in the topsoil may have a large impact on soil properties, soil quality, hydraulic, hydrological and erosion processes. In most studies, the rock fragments investigated still remain visible at the soil surface and only properties of these visible rock fragments are used for predicting runoff and soil loss. However, there are indications that rock fragments completely incorporated in the topsoil could also significantly influence the percolation and water distribution in stony soils and therefore, also infiltration, runoff and soil loss rates. Therefore, in this study interrill laboratory experiments with simulated rainfall for 60 min were conducted to assess the influence of subsurface rock fragments incorporated in a disturbed silt loam soil at different depths below the soil surface (i.e. 0.001, 0.01, 0.05 and 0.10 m), on infiltration, surface runoff and interrill erosion processes for small and large rock fragment sizes (i.e. mean diameter 0.04 and 0.20 m, respectively). Although only small differences in infiltration rate and runoff volume are observed between the soil without rock fragments (control) and the one with subsurface rock fragments, considerable differences in total interrill soil loss are observed between the control treatment and both contrasting rock fragments sizes. This is explained by a rapid increase in soil moisture in the areas above the rock fragments and therefore a decrease in topsoil cohesion compared with the control soil profile. The observed differences in runoff volume and interrill soil loss between the control plots and those with subsurface rock fragments is largest after a cumulative rainfall (P_cum) of 11 mm and progressively decreases with increasing P_cum. The results highlight the impacts and complexity of subsurface rock fragments on the production of runoff volume and soil loss and requires their inclusion in process‐based runoff and erosion models. Copyright © 2011 John Wiley & Sons, Ltd.     

Theory and experimental study for sliding isolators with variable curvature

Because a conventional isolation system with constant isolation frequency is usually a long‐period dynamic system, its seismic response is likely to be amplified in earthquakes with strong long‐period wave components, such as near‐fault ground motions. Seismic isolators with variable mechanical properties may provide a promising solution to alleviate this problem. To this end, in this work sliding isolators with variable curvature (SIVC) were studied experimentally. An SIVC isolator is similar to a friction pendulum system (FPS) isolator, except that its sliding surface has variable curvature rather being spherical. As a result, the SIVC's isolation stiffness that is proportional to the curvature becomes a function of the isolator displacement. By appropriately designing the geometry of the sliding surface, the SIVC is able to possess favorable hysteretic behavior. In order to prove the applicability of the SIVC concept, several prototype SIVC isolators, whose sliding surfaces are defined by a sixth‐order polynomial function, were fabricated and tested in this study. A cyclic element test on the prototype SIVC isolators and a shaking table test on an SIVC isolated steel frame were all conducted. The results of both tests have verified that the prototype SIVC isolators do indeed have the hysteretic property of variable stiffness as prescribed by the derived formulas in this study. Moreover, it is also demonstrated that the proposed SIVC is able to effectively reduce the isolator drift in a near‐fault earthquake with strong long‐period components, as compared with that of an FPS system with the same friction coefficient. Copyright © 2011 John Wiley & Sons, Ltd.     

Chemical and Isotopic Characteristics of the Kuroko‐Forming Volcanism

The Miocene northeast Honshu magmatic arc, Japan, formed at a terrestrial continental margin via a stage of spreading in a back‐arc basin (23–17 Ma) followed by multiple stages of submarine rifting (19–13 Ma). The Kuroko deposits formed during this period, with most forming during the youngest rifting stage. The mode of magma eruption changed from submarine basalt lava flows during back‐arc basin spreading to submarine bimodal basalt lava flows and abundant rhyolitic effusive rocks during the rifting stage. The basalts produced during the stage of back‐arc basin spreading are geochemically similar to mid‐ocean ridge basalt, with a depleted Sr–Nd mantle source, whereas those produced during the rifting stage possess arc signatures with an enriched mantle source. The Nb/Zr ratios of the volcanic rocks show an increase over time, indicating a temporal increase in the fertility of the source. The Nb/Zr ratios are similar in basalts and rhyolites from a given rift zone, whereas the Nd isotopic compositions of the rhyolites are less radiogenic than those of the basalts. These data suggest that the rhyolites were derived from a basaltic magma via crystal fractionation and crustal assimilation. The rhyolites associated with the Kuroko deposits are aphyric and have higher concentrations of incompatible elements than do post‐Kuroko quartz‐phyric rhyolites. These observations suggest that the aphyric rhyolite magma was derived from a relatively deep magma chamber with strong fractional crystallization. Almost all of the Kuroko deposits formed in close temporal relation to the aphyric rhyolite indicating a genetic link between the Kuroko deposits and highly differentiated rhyolitic magma.     

Piping dynamics in mid‐altitude mountains under a temperate climate: Bieszczady Mountains,eastern Carpathians

Piping has been recognized as an important geomorphic, soil erosion and hydrologic process. It seems that it is far more widespread than it has often been supposed. However, our knowledge about piping dynamics and its quantification currently relies on a limited number of data for mainly loess‐derived areas and marl badlands. Therefore, this research aimed to recognize piping dynamics in mid‐altitude mountains under a temperate climate, where piping occurs in Cambisols, not previously considered as piping‐prone soils. It has been expressed by the estimation of erosion rates due to piping and elongation of pipes in the Bere?nica Wy?na catchment in the Bieszczady Mountains, eastern Carpathians (305 ha, 188 collapsed pipes). The research was based on the monitoring of selected piping systems (1971–1974, 2013–2016). Changes in soil loss vary significantly between different years (up to 27.36 t ha^?1 yr^?1), as well as between the mean short‐term erosion rate (up to 13.10 t ha^?1 yr^?1), and the long‐term (45 years) mean of 1.34 t ha^?1 yr^?1. The elongation of pipes also differs, from no changes to 36 m during one year. The mean total soil loss is 48.8 t ha^?1 in plots, whereas in the whole studied catchment it is 2.0 t ha^?1. Hence, piping is both spatially and temporally dependent. The magnitude of piping in the study area is at least three orders of magnitude higher than surface erosion rates (i.e. sheet and rill erosion) under similar land use (grasslands), and it is comparable to the magnitude of surface soil erosion on arable lands. It means that piping constitutes a significant environmental problem and, wherever it occurs, it is an important, or even the main, sediment source. Copyright © 2017 John Wiley & Sons, Ltd.     

Deep massive sulphide exploration using 2D and 3D geoelectrical and induced polarization data in Skellefte mining district,northern Sweden

Geoelectrical and induced polarization data from measurements along three profiles and from one 3D survey are acquired and processed in the central Skellefte District, northern Sweden. The data were collected during two field campaigns in 2009 and 2010 in order to delineate the structures related to volcanogenic massive sulphide deposits and to model lithological contacts down to a maximum depth of 1.5 km. The 2009 data were inverted previously, and their joint interpretation with potential field data indicated several anomalous zones. The 2010 data not only provide additional information from greater depths compared with the 2009 data but also cover a larger surface area. Several high‐chargeability low‐resistivity zones, interpreted as possible massive sulphide mineralization and associated hydrothermal alteration, are revealed. The 3D survey data provide a detailed high‐resolution image of the top ～450 m of the upper crust around the Maurliden East, North, and Central deposits. Several anomalies are interpreted as new potential prospects in the Maurliden area, which are mainly concentrated in the central conductive zone. In addition, the contact relationship between the major geological units, e.g., the contact between the Skellefte Group and the Jörn Intrusive Complex, is better understood with the help of 2010 deep‐resistivity/chargeability data. The bottommost part of the Vargfors basin is imaged using the 2010 geoelectrical and induced polarization data down to ～1‐km depth.