Major ion chemistry and metal distribution in coal mine pit lake contaminated with industrial effluents: constraints of weathering and anthropogenic inputs

Ion chemistry of mine pit lake water reveals dominance of alkaline earths (Ca²⁺ and Mg²⁺) over total cation strength, while SO₄ ^2? and Cl^? constitute the majority of total anion load. Higher value of Ca²⁺?+?Mg²⁺/Na⁺?+?K⁺ (pre-monsoon 5.986, monsoon 8.866, post-monsoon 7.09) and Ca²⁺?+?Mg²⁺/HCO₃ ^??+?SO ₄ ² (pre-monsoon 7.14, monsoon 9.57, post-monsoon 8.29) is explained by weathering of Ca?CMg silicates and dissolution of Ca²⁺-bearing minerals present in parent rocks and overburden materials. Silicate weathering supposed to be the major geological contributor, in contrast to bicarbonate weathering does a little. Distribution coefficient for dissolved metals and sorbed to surface sediments is in the order of Cd?>?Pb?>?Fe?>?Zn?>?Cu?>?Cr?>?Mn. Speciation study of monitored metals in surface sediments shows that Fe and Mn are dominantly fractionated in exchangeable-acid reducible form, whereas rest of the metals (Cr, Pb, Cd, Zn, and Cu) mostly in residual form. Cd, Pb, and Zn show relatively higher recalcitrant factor that indicates their higher retention in lake sediments. Factor loading of monitored physico-chemical parameters resembles contribution/influences from geological weathering, anthropogenic inputs as well as natural temporal factors. Ionic load/strength of lake water accounted for geochemical process and natural factors, while pollutant load (viz BOD, COD and metals, etc.) is associated with anthropogenic inputs through industrial discharge.     

Mass-size distribution of PM10 and its characterization of ionic species in fine (PM2.5) and coarse (PM10−2.5) mode, New Delhi, India

Size distribution of PM₁₀ mass aerosols and its ionic characteristics were studied for 2 years from January 2006 to December 2007 at central Delhi by employing an 8-stage Andersen Cascade Impactor sampler. The mass of fine (PM_2.5) and coarse (PM_10?2.5) mode particles were integrated from particle mass determined in different stages. Average concentrations of mass PM₁₀ and PM_2.5 were observed to be 306 ± 182 and 136 ± 84 μg m^?3, respectively, which are far in excess of annual averages stipulated by the Indian National Ambient Air Quality Standards (PM₁₀: 60 μg m^?3 and PM_2.5: 40 μg m^?3). The highest concentrations of PM_10?2.5 (coarse) and PM_2.5 (fine) were observed 505 ± 44 and 368 ± 61 μg m^?3, respectively, during summer (June 2006) period, whereas the lower concentrations of PM_10?2.5 (35 ± 9 μg m^?3) and PM_2.5 (29 ± 13 μg m^?3) were observed during monsoon (September 2007). In summer, because of frequent dust storms, coarse particles are more dominant than fine particles during study period. However, during winter, the PM_2.5 contribution became more pronounced as compared to summer probably due to enhanced emissions from anthropogenic activities, burning of biofuels/biomass and other human activities. A high ratio (0.58) of PM_2.5/PM₁₀ was observed during winter and low (0.24) during monsoon. A strong correlation between PM₁₀ and PM_2.5 (r ² = 0.93) was observed, indicating that variation in PM₁₀ mass is governed by the variation in PM_2.5. Major cations (NH₄ ⁺, Na⁺, K⁺, Ca²⁺ and Mg²⁺) and anions (F^?, Cl^?, SO₄ ^2? and NO₃ ^?) were analyzed along with pH. Average concentrations of SO₄ ^2? and NO₃ ^? were observed to be 12.93 ± 0.98 and 10.33 ± 1.10 μg m^?3, respectively. Significant correlation between SO₄ ^2? and NO₃ ^? in PM_1.0 was observed indicating the major sources of secondary aerosol which may be from thermal power plants located in the southeast and incomplete combustion by vehicular exhaust. A good correlation among secondary species (NH⁺, NO₃ ^? and SO₄ ^2?) suggests that most of NH₄ ⁺ is in the form of ammonium sulfate and ammonium nitrate in the atmosphere. During winter, the concentration of Ca²⁺ was also higher; it may be due to entrainment of roadside dust particles, traffic activities and low temperature. The molar ratio (1.39) between Cl^? and Na⁺ was observed to be close to that of seawater (1.16). The presence of higher Cl^? during winter is due to western disturbances and probably local emission of Cl^? due to fabric bleaching activity in a number of export garment factories in the proximity of the sampling site.     

The 14 April 2012 Koyna Earthquake of M<Subscript>w</Subscript> 4.8: insights into active tectonics of the Koyna region

The 14 April 2012 earthquake of M_w 4.8 is the best monitored event in the Koyna region, a globally significant site of reservoir triggered seismicity in western India. Hence, investigation of this event assumes great importance, also considering its epicentral location close to that of the 1967 Koyna earthquake of M 6.3, the world’s largest reservoir triggered earthquake. Inversion of P-wave amplitude data along with the first motion polarities at 30 digital seismic stations provides a well-constrained strike-slip type focal mechanism solution, similar to that of the 1967 earthquake. The mechanism is further confirmed by moment tensor inversion of 3-component waveform data recorded at the three nearest broadband stations. The depth distribution of the aftershocks clearly delineates a NNE-SSW trending fault plane dipping about 78° to the WNW and coinciding with the trend of the Donachiwada fault, as well as the left-lateral fault plane of the focal mechanism solution obtained. The precise location, focal mechanism and the seismicity distribution from our dense network indicate that the activity in the Koyna region is mainly controlled by the NNE-SSW trending Donachiwada (D) fault zone rather than the Koyna River Fault Zone (KRFZ) on the west as suggested previously.     

A CCD photometric study of the late type contact binary EK Comae Berenices

We present CCD photometric observations of the W UMa type contact binary EK Comae Berenices using the 2 m telescope of IUCAA Girawali Observatory, India. The star was classified as a W UMa type binary of subtype-W by Samec et al. (1996). The new V band photometric observations of the star reveal that shape of the light curve has changed significantly from the one observed by Samec et al. (1996). A detailed analysis of the light curve obtained from the high-precision CCD photometric observations of the star indicates that EK Comae Berenices is not a W-type but an A-type totally eclipsing W UMa contact binary. The photometric mass ratio is determined to be 0.349 ± 0.005. A temperature difference of ΔT = 141 ± 10 K between the components and an orbital inclination of i[°] = 89.800 ± 0.075 were obtained for the binary system. Absolute values of masses, radii and luminosities are estimated by means of the standard mass-luminosity relation for zero age main-sequence stars. The star shows O’Connell effect, asymmetries in the light curve shape around the primary and secondary maximum. The observed O’Connell effect is explained by the presence of a hot spot on the primary component.     

Impact of gully incision on hillslope hydrology

The Southern U.S. Piedmont ranging from Virginia to Georgia underwent severe gully erosion over a century of farming mainly for cotton (1800s–1930s). Although tree succession blanketed much of this region by the middle 20th century, gully erosion still occurs, especially during wet seasons. While many studies on gully erosion have focused on soil loss, soil carbon exchange, and stormwater response, the impacts on soil moisture, groundwater, and transpiration remain under-studied. Using a newly developed 2D hydrologic model, this study analyzes the impacts of gully erosion on hillslope hydrologic states and fluxes. Results indicate that increases in gully incision lead to reduction in groundwater table, root zone soil moisture, and transpiration. These reductions show seasonal variations, but the season when the reduction is maximum differs among the hydrologic variables. Spatially, the impacts are generally the greatest near the toe of the hillslope and reduce further away from it, although the reductions are sometimes non-monotonic. Overall, the impacts are larger for shallow gully depths and diminish as the incision goes deeper. Lastly, the extent of impacts on a heterogeneous hillslope is found to be very different with respect to a homogeneous surrogate made of dominant soil properties. These results show that through gully erosion, the landscape not only loses soil but also a large amount of water from the subsurface. The magnitude of water loss is, however, dependent on hydrogeologic and topographic configuration of the hillslope. The results will facilitate (a) mapping of relative susceptibility of landscapes to gullying, (b) understanding of the impacts of stream manipulations such as due to dredging on hillslope eco-hydrology, (c) prioritization of mitigation measures to prevent gullying, and (d) design of observation campaigns to assess the impacts of gullying on hydrologic response.     

Fluctuation of groundwater in an urban coastal city of India: a GIS‐based approach

Groundwater is the most important and valuable natural resources especially in coastal urban environment where surface water is insufficient to satisfy the water requirement. Puri city is located on the east coast of India where groundwater is the only source available to meet city water supply. As the city is situated on the sandy aquifer, quality of groundwater is deteriorating because of anthropogenic activities, lack of sewerage system, etc. The objective of the study was to assess the groundwater fluctuation during post‐monsoon and summer with respect to hydrogeological conditions, topography, and groundwater consumption pattern of the city. For this assessment and analysis, Geographic Information System (GIS) was used to visualize topography of the area through digital elevation model (DEM) and distribution of groundwater contours spatially and temporally. The probable areas prone to contamination were identified based on aquifer property and depths to water table below ground. Copyright © 2010 John Wiley & Sons, Ltd.