Evaluation of reservoir temperatures and local utilization of geothermal waters of the Konkan Coast, India

Geochemical studies on fifteen geothermal manifestations (38–70°C) from the Konkan coast geothermal province of India have been used to evaluate the reservoir temperatures. Activity studies of the minerals and the waters present in the reservoirs suggest that the thermal waters are in equilibrium with montmorillonite, kaolinite and quartz at about 100°C. Reservoir temperatures of these geothermal systems as estimated by geochemical thermometers, are 88 to 128°C, and thus too low for economic electricity production.     

An experimental study of dissolution kinetics of Calcite, Dolomite, Leucogranite and Gneiss in buffered solutions at temperature 25 and 5°C

Laboratory experiments were carried out continuously for 30–35 days at 25 and 5°C in three different buffer solutions of pH 4.0, 2.2 and 8.4 to calculate dissolution rates of two minerals, calcite (CC) and dolomite (DM) and two rocks, leucogranite (LG) and gneiss (GN) from the Himalayan range. Calculated rates in terms of release of targeted elements versus time (Ca for CC; Mg for DM; Si for LG and GN) demonstrate direct correlation with temperature. Dissolution rates are higher at 25°C compared to 5°C. CC and DM were experimented only at pH 8.4 and results show that both undergo congruent dissolution with CC dissolving ∼5 times faster than DM. Ca and Mg exhibit average apparent activation energies (E _a) of 13.98 and 9.98 kcal mol⁻¹ respectively at pH 8.4 which reflects greater sensitivity of CC dissolution than DM dissolution towards an increase in temperature. Scanning Electron Microscope attached with Energy Dispersive X-Ray Analyser (SEM-EDX) data indicates that dissolution is controlled primarily by surface-reaction processes, with dislocation sites contributing maximum to the dissolution. As compared to CC and DM dissolution, LG and GN undergo relatively slower incongruent dissolution with precipitation of some secondary minerals as revealed from X-ray diffractometer (XRD) results. Rates of dissolution of LG is maximum at pH 2.2, moderate at pH 8.4 and least at pH 4.0, whereas GN shows maximum dissolution at pH 2.2, moderate at pH 4.0 and least at pH 8.4. A comparison in dissolution behavior of LG and GN at experimental conditions reveals that increase in Si-release rate in the temperature range between 5 and 25°C is maximum at pH 8.4 (∼3.4–4.5 times), moderate at pH 4.0 (∼3–1.8 times) and least at pH 2.2 (∼1.0–1.5 times). Within the experimental temperature range, calculated values of E _a for Si release during LG and GN dissolution advocates positive correlation with pH. A substantial decrease in initial values of Brunauer–Emmett–Teller (BET) surface area of DM, LG, and GN has been encountered at the end of the experiment, except for CC for which an increase is observed. The study clearly demonstrates the dissolution behavior of pure minerals and rocks under controlled conditions. The dissolution rates assume enormous significance for the release of trace elements from rocks/minerals to the reacting water.     

Removal of metal from acid mine drainage (AMD) by using natural zeolite of Nizarneshwar Hills of Western India

The mining industry faces stringent effluent discharge regulations and has acknowledged that it is necessary to look into innovative technologies to recycle considerable amount of effluent rather than discharging into surface water. Effluents from mines give rise to aesthetic unpleasantness. The focus of the investigations was to cope with more stringent effluent discharge regulations and to protect the ecosystem from harmful pollutants in the mine effluents. Copper is one of the heavy metal in the mine systems, which are known to be a harmful element. The present study has been undertaken to investigate a process that might remove Cu(II) from mine waste water by using natural zeolite, such as stilbite, and compared with synthetic resins like CSA-9 and CSA-609D. In this study, natural zeolite was used as a low-cost adsorbent to evaluate its ability to remove heavy metals from acid mine drainage. The zeolite used in this study is the natural clay mineral from the Nizarneshwar Hills of Western India. Three resins tested are CSA-9, natural zeolite–stilbite, and CSA-609D. Batch testing has been conducted to select effective ion-exchange resins for copper removal and to determine effective regenerants for regeneration of exhausted resins. All tests were conducted at bench scale and in batch mode. Three strong acid cation exchangers were evaluated to compare their metal removal capacities. The metal concentration in the effluent was reduced with all resins tested. It was found that, among all the three types of natural zeolite, stilbite shows the highest removal efficiency of copper in every parameter that is considered for evaluating the performance of resins.     

Hurricanes and tropical storms: A necessary evil to ensure water supply?

Several parts of the globe including Southeast North America, the Caribbean, Southeast Asia, Australia, and China are often hit by hurricanes and tropical storms (HTSs), which can deliver a large amount of rainfall within a period of a few days. Although HTSs are mostly studied as disaster agents, considering that they occur during the period when water supply systems are generally depleted, it is important to ascertain their potential contributions toward sustaining water supply. Using the Lake Michie–Little River reservoir system that supplies water to the city of Durham (North Carolina) as a representative test case, we implemented an integrated watershed and reservoir management model, supported by publicly available observations, to evaluate the extent to which HTSs impact water storages. Results indicate that HTSs can have a significant impact on reservoir water storage, with their effects being felt for more than a year for some storms. The impact on reservoir water storage is identified to be primarily controlled by 3 factors, namely, streamflow response size from HTSs, storage in the reservoir right before the event, and streamflow succeeding the event response to HTS (henceforth referred as postevent streamflow). Although the impact of streamflow response size on water storage is generally proportional to its magnitude, initial water storage in the reservoir and postevent streamflow have a nonmonotonic influence on water storage. As all the 3 identified controls are a function of antecedent hydrologic conditions and meteorological forcings, these 2 factors indirectly influence the impact of HTS on water storage in a reservoir. The identification of controlling factors and assessment of their influence on reservoir response will further facilitate implementation of more accurate estimation and prediction frameworks for within‐year reservoir operations.     

Density and temperature diagnostics of solar emission lines from Navii and Alix

Line intensity ratios of EUV emission lines from Navii and Alix have been considered for electron density and temperature determinations within the chromosphere-corona transition region and the corona. The electron pressure within the emission region has been assumed to be a constant parameter. Theoretical line intensities for these ions have been computed using a model solar atmosphere and compared with the values as observed by ATM ultraviolet spectrometer. The observed intensities correspond to the average quiet-Sun conditions near solar minimum.     

Time-Dependent Synchrotron and Compton Spectra from Microquasar Jets

Jet models for the high-energy emission of Galactic X-ray binary sources have regained significant interest with detailed spectral and timing studies of the X-ray emission from microquasars, the recent detection by the HESS collaboration of very-high-energy γ-rays from the microquasar LS 5039, and the earlier suggestion of jet models for ultraluminous X-ray sources observed in many nearby galaxies. Here we study the synchrotron and Compton signatures of time-dependent electron injection and acceleration, and adiabatic and radiative cooling in the jets of Galactic microquasars.     

Measurement of electron temperatures in the lower ionosphere by detecting the space potential on the langmuir probe characteristic

Electron temperatures have been determined at Thumba on Nike Apache flight 10.11 (12 March 1967, 1857 hr IST) by the usual retarding potential analysis and by using an a.c. modulation technique for detecting the space potential on the Langmuir probe characteristic. Simultaneous measurements with the two techniques show that the space potential technique gives temperatures which are related to the temperatures obtained from the retarding potential analysis in a manner remarkably similar to the relations obtained by Booker and Smith as well as by Carlson and Sayers between radar temperatures and d.c. probe temperatures. This result is interesting in view of the fact that radar temperatures have been found to be in good agreement with the temperatures obtained by a.c. modulation techniques on satellite borne probes. The space potential technique is simple, requires limited additional electronics, does not make stringent demands on telemetry and can be easily adopted for rocket borne Langmuir probes.     

On the nature of the ice cap on the Tibetan Plateau during the late Quaternary

Considerable debate persists among scientists interested in the nature of the ice cap on the Tibetan Plateau during the late Quaternary. We examine the implications, on this problem, of the high resolution data that has recently become available from the Dunde ice cap in north Tibet. The observed −2% change in the δ¹⁸O of the ice formed at the Dunde ice cap during the Last Glacial Stage (LGS) suggests a limit in the range of 5–7°C on the reduction in annual surface air temperature over Tibet during the LGS. This then translates to an Equilibrium Line Altitude (ELA) lowering of 700–1200 m. Due to this lowering, ELA could have reached below the level of the surface of the plateau resulting in an extensive ice sheet formation during LGS.     

Constraints on ice-sheet thickness over Tibet during the last 40 000 years

The Late Quaternary glaciation of Tibet has received considerable attention in the last few decades due to its influence on the regional climate, especially the Asian summer monsoon. Recently, however, it has been argued that the Tibetan ice sheet also might have played an important role in initiating global-scale palaeoclimatic changes. Controversy, however, exists on the nature of Late Quaternary ice cover over Tibet due largely to the subjectivity in the interpretation of the sparse and complex geomorphological evidence. We have examined this problem in the light of δ ¹⁸O data (a temperature proxy) of ice cores-from the Dunde ice cap on the northern flank of Tibet. Considering only the gross features in the Dunde ice-core isotopic data, we have interpreted a temperature decrease of 4°–6°C and consequent lowering of equilibrium line altitude (ELA) in the range 700–850 m during the last glacial stage (LGS). This could have caused depression of the snow line below the mean altitutde of the Tibetan plateau, resulting in an areally extensive but marginally thick ice cover. However, if one also considers the possibility that precipitation on the Tibetan plateau during LGS may have been significantly lower than at present, the ELA depression would be much less than that estimated by considering the temperature effect alone.     

A multi-layered backpropagation artificial neural network algorithm for UV spectral classification

In this paper we present an application of an artificial neural network model based on a multi-layered backpropagation algorithm for spectral classification of UV data from the International Ultraviolet Explorer (IUE) low dispersion spectra reference atlas. The model used is similar to that of von Hippel et al. (1994), and is found to reduce the classification error as compared to the recently reported results on the same data set (Gulati et al. 1994b). The improved version of the network is much simpler in structure and the training time is reduced by a factor of almost 20. Such networks will prove very useful in efficient classification of large databases Subject headings: neural networks, stellar spectra, classification