K–Ar ages of the Akan-Shiretoko volcanic chain lying oblique to the Kurile trench: Implications for tectonic control of volcanism

The Akan‐Shiretoko volcanic chain, situated in the Southwestern Kurile arc, consists mainly of nine subaerial andesitic stratovolcanoes and three calderas. The chain extends in a SW–NE direction for 200 km, situated oblique to the Kurile trench at an angle of 25 degrees. Thirty‐seven new K–Ar ages, plus previous data, suggest that volcanic activity along the Akan‐Shiretoko volcanic chain began at ca 4 Ma at Akan, at the southwestern end of the chain, and systematically progressed northeastward, resulting in the southwest‐northeast‐trending volcanic chain. This spatial and temporal distribution of volcanoes can be explained by anticline development advancing northeastward from the Akan area, accompanied by magma rising through northeast‐trending fractures that developed along the anticlinal axis. The northeastward development of the anticline caused uplifting of the Akan‐Shiretoko area and changed the area from submarine to subaerial conditions. Anticline formation was likely due to deformation of the southwestern Kurile arc, with southwestward migration of the Kurile forearc sliver caused by oblique subduction of the Pacific plate. The echelon topographic arrangement of the Shiretoko, Kunashiri, Etorofu and Urup was formed at ca 1 Ma.     

The ISO-SWS detectors: Performance trends and space radiation effects

We present a trend analysis of the ISO-SWS detector performance and a study of the space radiation effects on the SWS detectors. In particular, dark currents, dark current noise and detector responses have been checked as a function of time through the mission and as a function of time in arevolution. The results show that these parameters were stable during the mission in all bandsbut for band 3 (Si:As). Dark currents and responses were found to be higherin the first hours following the start of the science window,especially in band 2 (Si:Ga). We have studied the impacts of cosmic rays and radiation belt particles on the SWS detectors, as well as of the only large solar proton event on November 6, 1997,that occurred during the ISO mission (operated during solar minimum).The observed glitch rates in all SWS bands are found to be between 2 and4 times higher than the value predicted by the CREME96 model for the cosmic ray flux in the period considered. The bands that registered the highest glitch rates showed also a correlation with the electron fluxes measured on theGOES 9 spacecraft. From the distribution of glitchheights (voltage jumps in the detector signal), we have derived the deposited energy distributions of the particles hits. Our results lead to the conclusion that secondaryparticles produced in the shield and the detectors contributed at least as much as cosmic rays to the observed glitch rate. The effects on the detectors of the November 6, 1997 event, which caused that all observationsin a revolution were declared failed, are described in detail.     

Adaptive optics near-infrared imaging of NGC 2992 – unveiling core structures related to radio figure-of-8 loops

We present near-infrared adaptive optics, Very Large Array (VLA) radio and Hubble Space Telescope ( HST ) optical imaging of the nearby Seyfert galaxy NGC 2992. Spiral structure and an extension to the west are traced down to the core region at the limiting resolution of our near-infrared images. A faint, diffuse loop of near-infrared and radio emission is also observed to the north, embedded within the prominent 2-arcsec radio loop previously observed to the north-west. Near-infrared colour maps and CO narrow-band imaging are then used to identify which regions may not be purely reddened stellar populations. Our new data provide evidence that the VLA radio-loop morphology in the shape of a figure of 8 represents two components superimposed: (1) outflow bubbles out of the plane of the disc, coincident with the extended emission-line region (EELR); (2) star formation along the spiral arm within the galaxy disc and through the dust lane. The near-infrared continuum emission associated with the outflowing radio bubbles suggests that the radio loops are driven by the active nucleus.     

Mineralogy,petrology, chronology,and exposure history of the Chelyabinsk meteorite and parent body

Three masses of the Chelyabinsk meteorite have been studied with a wide range of analytical techniques to understand the mineralogical variation and thermal history of the Chelyabinsk parent body. The samples exhibit little to no postentry oxidation via Mössbauer and Raman spectroscopy indicating their fresh character, but despite the rapid collection and care of handling some low levels of terrestrial contamination did nonetheless result. Detailed studies show three distinct lithologies, indicative of a genomict breccia. A light‐colored lithology is LL5 material that has experienced thermal metamorphism and subsequent shock at levels near S4. The second lithology is a shock‐darkened LL5 material in which the darkening is caused by melt and metal‐troilite veins along grain boundaries. The third lithology is an impact melt breccia that formed at high temperatures (~1600 °C), and it experienced rapid cooling and degassing of S₂ gas. Portions of light and dark lithologies from Chel‐101, and the impact melt breccias (Chel‐102 and Chel‐103) were prepared and analyzed for Rb‐Sr, Sm‐Nd, and Ar‐Ar dating. When combined with results from other studies and chronometers, at least eight impact events (e.g., ~4.53 Ga, ~4.45 Ga, ~3.73 Ga, ~2.81 Ga, ~1.46 Ga, ~852 Ma, ~312 Ma, and ~27 Ma) are clearly identified for Chelyabinsk, indicating a complex history of impacts and heating events. Finally, noble gases yield young cosmic ray exposure ages, near 1 Ma. These young ages, together with the absence of measurable cosmogenic derived Sm and Cr, indicate that Chelyabinsk may have been derived from a recent breakup event on an NEO of LL chondrite composition.     

Tracing groundwater flow and sources of organic carbon in sandstone aquifers using fluorescence properties of dissolved organic matter (DOM)

The fluorescence properties of groundwaters from sites in two UK aquifers, the Penrith Sandstone of Cumbria and the Sherwood Sandstone of South Yorkshire, were investigated using excitation–emission matrix (EEM) fluorescence spectroscopy. Both aquifers are regionally important sources of public supply water and are locally impacted by pollution. The Penrith Sandstone site is in a rural setting while the Sherwood Sandstone site is in suburban Doncaster. Fluorescence analysis of samples from discrete sample depths in the Penrith Sandstone shows decreasing fulvic-like intensities with depth and also shows a good correlation with CFC-12, an anthropogenic groundwater tracer. Tryptophan-like fluorescence centres in the depth profile may also provide evidence of rapid routing of relatively recent applications of organic slurry along fractures. Fluorescence analysis of groundwater sampled from multi-level piezometers installed within the Sherwood Sandstone aquifer also shows regions of tryptophan-like and relatively higher fulvic-like signatures. The fluorescence intensity profile in the piezometers shows tryptophan-like peaks at depths in excess of 50 m and mirrors the pattern exhibited by microbial species and CFCs highlighting the deep and rapid penetration of modern recharge due to rapid fracture flow. Fluorescence analysis has allowed the rapid assessment of different types and relative abundances of dissolved organic matter (DOM), and the fingerprinting of different sources of organic C within the groundwater system. The tryptophan:fulvic ratios found in the Penrith Sandstone were found to be between 0.5 and 3.0 and are characteristic of ratios from sheep waste sources. The Sherwood Sandstone has the lowest ratios (0.2–0.4) indicating a different source of DOM, most likely a mixture of terrestrial and microbial sources, although there is little evidence of pollution from leaking urban sewage systems. Results from these two studies suggest that intrinsic fluorescence may be used as a proxy for, or complementary tool to, other groundwater investigation methods in helping provide a conceptual model of groundwater flow and identifying different sources of DOM within the groundwater system.     

Galaxy groups at 0.3 ≤z≤ 0.55 – II. Evolution to z∼ 0

We compare deep Magellan spectroscopy of 26 groups at  0.3 ≤ z ≤ 0.55  , selected from the Canadian Network for Observational Cosmology 2 field survey, with a large sample of nearby groups from the 2PIGG catalogue. We find that the fraction of group galaxies with significant [O  ii ]λ3727 emission (≥5 Å) increases strongly with redshift, from ∼29 per cent in 2dFGRS to ∼58 per cent in CNOC2, for all galaxies brighter than  ∼ M _*+ 1.75  . This trend is parallel to the evolution of field galaxies, where the equivalent fraction of emission-line galaxies increases from ∼53 to ∼75 per cent. The fraction of emission-line galaxies in groups is lower than in the field, across the full redshift range, indicating that the history of star formation in groups is influenced by their environment. We show that the evolution required to explain the data is inconsistent with a quiescent model of galaxy evolution; instead, discrete events in which galaxies cease forming stars (truncation events) are required. We constrain the probability of truncation ( P _trunc) and find that a high value is required in a simple evolutionary scenario neglecting galaxy mergers  ( P _trunc≳ 0.3 Gyr⁻¹)  . However, without assuming significant density evolution, P _trunc is not required to be larger in groups than in the field, suggesting that the environmental dependence of star formation was embedded at redshifts   z ≳ 0.45  .     

Comparison of the structures of humic acids from marine sediments and degraded field diatoms by 13C- and 1H-NMR spectroscopy

Humic acids isolated from marine sediments of the Peru continental shelf and from a degraded field diatom population dominated by the diatoms Skeletonema costatum, Nitzschia seviata and Thalassiosira sp. were characterized on the basis of infrared spectra and ¹³C- and proton-NMR spectra. Aliphatic structures were found to constitute the major fraction of humic acids and they appear to be highly branched. Carbohydrates and to a lesser extent aromatic materials, carbonyl-, ether-, alcohol- and amino groups are important contributors to the structure of marine humic acids. A close relationship was observed between the chemical structure of the sedimentary humic acid and the plankton humic acid.