Species, tissue and gender-related organochlorine bioaccumulation in white-sided dolphins, pilot whales and their common prey in the northwest Atlantic

Organochlorine concentrations were measured in white-sided dolphins, pilot whales, and their prey from the Gulf of Maine and used to identify species, tissue, and gender differences, and trophic transfer trends, in bioaccumulation. Polychlorinated biphenyl concentrations ([PCB]) in dolphin blubber (13 +/- 7.1 micrograms/g fresh wt.) were twice those in pilot whales, but pesticide concentrations (20 +/- 13 micrograms/g fresh) were similar between species. 4,4'-DDE, trans-non-achlor, Cl6(153) and Cl6(138) concentrations were highest. Skin tissues had more recalcitrant organochlorines than the internal organs. Male dolphins bioaccumulated higher concentrations of nonmetabolizable PCBs and hexachlorocyclohexane (HCH) isomers, whereas pilot whales had no gender-related differences in bioaccumulation. Pilot whales, mackerel, and herring had proportionately higher concentrations of DDTs, whereas [PCB] were higher in dolphins and squid. Although these odontocetes feed at the same trophic level and store a similar suite of contaminants, dolphins bioaccumulated higher and potentially hazardous 4,4'-DDE and PCB concentrations from food in their more geographically restricted range.     

Modeling basin-scale hydrology in support of physical climate and global biogeochemical studies: An example using the Zambezi River

Human activity is an important agent defining the contemporary hydrologic cycle. We have documented the potential impacts of impoundment, land use change and climate change on the Zambezi River system in southern Africa and found that they can be substantial. A full analysis requires construction and parameterization of a simulation for the entire catchment. This paper develops a strategy for implementing catchment-scale models of the major hydrologic processes operating within the basin. A coherent data set for calibrating the models has also been assembled. The algorithms consist of a Water Balance (WBM) and a Water Transport (WTM) operating at 1/2^o spatial scale and at monthly timesteps. These models transform complex patterns of regional climatology into estimates of soil water, evapotranspiration, runoff, and discharge through rivers of various size. The models are dependent on the characteristics of the terrestrial surface, principally soil texture and land cover. A simulated river network is also required. Additional tabular data sets are essential for model testing and calibration. These include subcatchment areas; observed river discharge at selected points; flooding, storage and loss characteristics of major wetlands; floodwave translation; and, volume, surface area, withdrawal and evaporative losses from impoundments. An important design consideration for the numerous impoundments in the Zambezi requires an understanding of the seasonal variation in discharge, in particular how it might respond to climate and land use change. The research strategy offered here lays a framework for addressing such issues. Although the primary focus of this work is hydrologic, we discuss how the model can be extended to consider constituent transport and biogeochemical cycling issues at the continental scale.     

Toxicity of No. 2 fuel oil to coon stripe shrimp

Bioassay of a No. 2 fuel oil dispersion with shrimp in a continuous flow system using measured waterborne oil as the indicator of oil concentrations reveals a treatment more definable than those previously described in terms of volume ratios and produces lower lethal concentrations. Shrimp 96-h LC₅₀ was 0.8 mg/l in this study as compared to values from 1.5 to 50 mg/l reported for other methods. Mean concentrations in tests do not give significant differences in concentration with respect to day of the test or spatial distribution in the exposure tanks.     

Frequency response corrections for eddy correlation systems

Simplified expressions describing the frequency response of eddy correlation systems due to sensor response, path-length averaging, sensor separation and signal processing are presented. A routine procedure for estimating and correcting for the frequency response loss in flux and variance measurements is discussed and illustrated by application to the Institute of Hydrology's Hydra eddy correlation system.The results show that flux loss from such a system is typically 5 to 10% for sensible and latent heat flux, but can be much larger for momentum flux and variance measurements in certain conditions.A microcomputer program is included which, with little modification, can be used for estimating flux loss from other eddy correlation systems with different or additional sensors.     

AN HISTORICAL APPROACH TO MOBILITY RESEARCH *

Most existing work on residential mobility has assumed that the household relocation decision is an intrinsically significant object of inquiry. In contrast, we argue that mobility derives its significance primarily from the particular historical and locational contexts within which it occurs. We suggest, therefore, that future mobility research should be directed away from the development of a theory of mobility per se and toward a more explicit articulation of mobility studies to existing theories of urbanization and social change.     

Simple analytical Green's functions for ray perturbations in layered media

The total Green's function for two-point boundary-value problems can be related to the propagator for initial-value problems. A very simple expression for the Green's function is obtained when the unperturbed medium may be described by material with a constant gradient in quadratic slowness. The derivation requires a correct understanding of assumptions made in the propagator solution. Expressions are also obtained for Green's function in multilayered media.     

The reserves of extracted resources: Historical data

The available data on known reserves of extracted resources have not previously been tabulated and graphed. In this article we compile the reserves data in one place for the first time. This serves to (1) show the trends in the reserves series, (2) make the series available to others, and (3) place the reserves data in the context of price data for which longer series have been available, and with which they can now be seen to be consistent in both showing increasing availability rather than increasing scarcity.     

Above‐stream microclimate and stream surface energy exchanges in a wildfire‐disturbed riparian zone

Stream temperature and riparian microclimate were characterized for a 1·5 km wildfire‐disturbed reach of Fishtrap Creek, located north of Kamloops, British Columbia. A deterministic net radiation model was developed using hemispherical canopy images coupled with on‐site microclimate measurements. Modelled net radiation agreed reasonably with measured net radiation. Air temperature and humidity measured at two locations above the stream, separated by 900 m, were generally similar, whereas wind speed was poorly correlated between the two sites. Modelled net radiation varied considerably along the reach, and measurements at a single location did not provide a reliable estimate of the modelled reach average. During summer, net radiation dominated the surface heat exchanges, particularly because the sensible and latent heat fluxes were normally of opposite sign and thus tended to cancel each other. All surface heat fluxes shifted to negative values in autumn and were of similar magnitude through winter. In March, net radiation became positive, but heat gains were cancelled by sensible and latent heat fluxes, which remained negative. A modelling exercise using three canopy cover scenarios (current, simulated pre‐wildfire and simulated complete vegetation removal) showed that net radiation under the standing dead trees was double that modelled for the pre‐fire canopy cover. However, post‐disturbance standing dead trees reduce daytime net radiation reaching the stream surface by one‐third compared with complete vegetation removal. The results of this study have highlighted the need to account for reach‐scale spatial variability of energy exchange processes, especially net radiation, when modelling stream energy budgets. Copyright © 2010 John Wiley & Sons, Ltd.