Reactions of nitriles in ices relevant to Titan, comets, and the interstellar medium: formation of cyanate ion, ketenimines, and isonitriles

Motivated by detections of nitriles in Titan's atmosphere, cometary comae, and the interstellar medium, we report laboratory investigations of the low-temperature chemistry of acetonitrile, propionitrile, acrylonitrile, cyanoacetylene, and cyanogen (CH₃CN, CH₃CH₂CN, CH₂CHCN, HCCCN, and NCCN, respectively). A few experiments were also done on isobutyronitrile and trimethylacetonitrile ((CH₃)₂CHCN and (CH₃)₃CCN, respectively). Trends were sought, and found, in the photo- and radiation chemical products of these molecules at 12-25 K. In the absence of water, all of these molecules isomerized to isonitriles, and CH₃CN, CH₃CH₂CN, and (CH₃)₂CHCN also formed ketenimines. In the presence of H₂O, no isonitriles were detected but rather the cyanate ion (OCN⁻) was seen in all cases. Although isonitriles, ketenimines, and OCN⁻ were the main focus of our work, we also describe cases of hydrogen loss, to make smaller nitriles, and hydrogen addition (reduction), to make larger nitriles. HCN formation also was seen in most experiments. The results are presented in terms of nitrile ice chemistry on Titan, in cometary ice, and in the interstellar medium. Possible connections to prebiotic chemistry are briefly discussed.     

First Observations of Coronal Hole Structure and Evolution Using Soho-Cds

We report on initial observations of coronal holestructure and evolution by the Coronal Diagnostic Spectrometer (CDS) instrument on board the Solar and Heliospheric Observatory (SOHO). The data show that there is coronal activity on time scales of tens of minutes, manifested as brightenings at chromospheric network cell junctions in extreme ultraviolet (EUV) wavelengths. There are also significant differences in structure seen in different wavelengths in coronal holes. Finally, we show coronal hole EUV spectra and compare them to quiet-Sun spectra, also taken by CDS.     

A GIS-based method for defining snow zones: application to the western United States

This study maps the geographic extent of intermittent and seasonal snow cover in the western United States using thresholds of 2000–2010 average snow persistence derived from moderate resolution imaging spectroradiometer snow cover area data from 1 January to 3 July. Results show seasonal snow covers 13% of the region, and intermittent snow covers 25%. The lower elevation boundaries of intermittent and seasonal snow zones increase from north-west to south-east. Intermittent snow is primarily found where average winter land surface temperatures are above freezing, whereas seasonal snow is primarily where winter temperatures are below freezing. However, temperatures at the boundary between intermittent and seasonal snow exhibit high regional variability, with average winter seasonal snow zone temperatures above freezing in west coast mountain ranges. Snow cover extent at peak accumulation is most variable at the upper elevations of the intermittent snow zone, highlighting the sensitivity of this snow zone boundary to climate conditions.     

Thermal equilibrium in Europa's ice shell

Models of tidal-convective equilibrium for Europa's ice shell are computed using a laboratory-derived composite flow law for ice. Volume diffusion creep is found to dominate the flow law at equilibrium, and thus the thickness of the shell is strongly dependent on the poorly known grain size of the ice. This grain size is, however, constrained to be less than a few millimeters if equilibrium is achieved at the current eccentricity. Europa's ice shell cannot be thinner than about 16 km in equilibrium at present, since tidal dissipation cannot generate enough heat in such a thin shell to balance the heat transport. No conductive equilibria are found; this is likely due to the fact that most of a conductive shell must be cold if temperature gradients are to be large enough to carry the heat. A minimum eccentricity of about 0.0025 (about 1/4 the present value) below which there are no equilibria is also found.     

Large impact features on middle-sized icy satellites

All of the large impact features of the middle-sized icy satellites of Saturn and Uranus that were clearly observed by the Voyager spacecraft are described. New image mosaics and stereo-and-photoclinometrically-derived digital elevation models are presented. Landforms related to large impact features, such as secondary craters and possible antipodal effects are examined and evaluated. Of the large impacts, Odysseus on Tethys appears to have had the most profound effect on its “target” satellite of any of the impact features we examined. Our modeling suggests that the Odysseus impact may have caused the prompt formation of Ithaca Chasma, a belt of tectonic troughs that roughly follow a great circle normal to the center of Odysseus, although other hypotheses remain viable. We identify probable secondary cratering from Tirawa on Rhea. We attribute a number of converging coalescing crater chains on Rhea to a putative, possibly relatively fresh, ∼350 km-diameter impact feature. We examine the antipodes of Odysseus, the putative ∼350 km-diameter Rhean impact feature, and Tirawa, and conclude that evidence from Voyager data for damage from seismic focusing is equivocal, although our modeling results indicate that such damage may have occurred. We propose a number of observations and tests for Cassini that offer the opportunity to differentiate among the various explanations and speculations reviewed and evaluated in this study.