Hydrothermal alteration,fluid inclusions and stable isotope systematics of the Alvo 118 iron oxide–copper–gold deposit,Carajás Mineral Province (Brazil): Implications for ore genesis

The Alvo 118 iron oxide–copper–gold (IOCG) deposit (170 Mt at 1.0 wt.% Cu, 0.3 g/t Au) lies in the southern sector of the Itacaúnas Shear Belt, Carajás Mineral Province, along a WNW–ESE-striking, 60-km-long shear zone, close to the contact of the ~2.76-Ga metavolcano-sedimentary Itacaiúnas Supergroup and the basement (~3.0 Ga Xingu Complex). The Alvo 118 deposit is hosted by mafic and felsic metavolcanic rocks and crosscutting granitoid and gabbro intrusions that have been subjected to the following hydrothermal alteration sequence towards the ore zones: (1) poorly developed sodic alteration (albite and scapolite); (2) potassic alteration (biotite or K-feldspar) accompanied by magnetite formation and silicification; (3) widespread, pervasive chlorite alteration spatially associated with quartz–carbonate–sulphide infill ore breccia and vein stockworks; and (4) local post-ore quartz–sericite alteration. The ore assemblage is dominated by chalcopyrite (~60%), bornite (~10%), hematite (~20%), magnetite (10%) and subordinate chalcocite, native gold, Au–Ag tellurides, galena, cassiterite, F-rich apatite, xenotime, monazite, britholite-(Y) and a gadolinite-group mineral. Fluid inclusion studies in quartz point to a fluid regime composed of two distinct fluid types that may have probably coexisted within the timeframe of the Cu–Au mineralizing episode: a hot (>200°C) saline (32.8‰ to 40.6 wt.% NaCl eq.) solution, represented by salt-bearing aqueous inclusions, and a lower temperature (<200°C), low to intermediate salinity (<15 wt.% NaCl eq.) aqueous fluid defined by two-phase (L_H2O + V_H2O) fluid inclusions. This trend is very similar to those defined for other IOCG systems of the Carajás Mineral Province. δ ¹⁸O_H2O values in equilibrium with calcite (−1.0‰ to 7.5‰ at 277°C to 344°C) overlap the lower range for primary magmatic waters, but the more ¹⁸O-depleted values also point to the involvement of externally derived fluids, possibly of meteoric origin. Furthermore, sulphide δ ³⁴S values (5.1‰ to 6.3‰), together with available boron isotope and Cl/Br–Na/Cl data provide evidence for a significant component of residual evaporative fluids (e.g., bittern fluids generated by seawater evaporation) in this scenario that, together with magma-derived brines, would be the main sources of the highly saline fluids involved in the formation Alvo 118 IOCG deposit. The restricted high temperature sodic alteration, the pervasive overprinting of the potassic alteration minerals by chlorite proximal to the ore zones, ore breccias with open-space filling textures in brittle structures, microthermometric and stable isotope data indicate, collectively, that the Alvo 118 IOCG system developed at structurally high levels and may be considered the shallower representative of the IOCG systems of the CMP.     

Discrimination of water quality monitoring sites in River Vouga using a mixed-effect state space model

The surface water quality monitoring is an important concern of public organizations due to its relevance to the public health. Statistical methods are taken as consistent and essential tools in the monitoring procedures in order to prevent and identify environmental problems. This work presents the study case of the hydrological basin of the river Vouga, in Portugal. The main goal is discriminate the water monitoring sites using the monthly dissolved oxygen concentration dataset between January 2002 and May 2013. This is achieved through the extraction of trend and seasonal components in a linear mixed-effect state space model. The parameters estimation is performed with both maximum likelihood method and distribution-free estimators in a two-step procedure. The application of the Kalman smoother algorithm allows to obtain predictions of the structural components as trend and seasonality. The water monitoring sites are discriminated through the structural components by a hierarchical agglomerative clustering procedure. This procedure identified different homogenous groups relatively to the trend and seasonality components and some characteristics of the hydrological basin are presented in order to support the results.     

Porto Oscillation Code (posc)

The Porto Oscillation Code (posc) has been developed in 1995 and improved over the years, with the main goal of calculating linear adiabatic oscillations for models of solar-type stars. It has also been used to estimate the frequencies and eigenfunctions of stars from the pre-main sequence up to the sub-giant phase, having a mass between 0.8 and 4 solar masses. The code solves the linearised perturbation equations of adiabatic pulsations for an equilibrium model using a second order numerical integration method. The possibility of using Richardson extrapolation is implemented. Several options for the surface boundary condition can be used. In this work we briefly review the key ingredients of the calculations, namely the equations, the numerical scheme and the output.     

Epibiotic assemblages on the pen shell Pinna rudis (Bivalvia,Pinnidae) at Matiota Beach,São Vicente Island,Cabo Verde

The rough pen shell Pinna rudis Linnaeus, 1758 (family Pinnidae), a mollusc with an Atlantic–Mediterranean distribution, is able to live in coarse sandy substrates. Considering its shell structure and ecological characteristics, P. rudis can enhance biodiversity by providing a substrate for settlement on its shell. For this reason, we compared the diversity of benthic taxa around P. rudis shells with the species diversity on P. rudis shells, at Matiota Beach, São Vicente Island, Cabo Verde. We sampled an area of 900 m2 and recorded data in situ to estimate the population size of P. rudis and the epibiotic and benthic community diversity. The average density of P. rudis estimated in the sampled area was 6.6 ind. 100 m–2 and the highest density was found at between 2 and 3 m depth, mostly in biogenic and sandy substrates. The epibiotic species diversity on P. rudis shells was significantly higher than the species diversity in the microhabitat around the shells. The P. rudis shell seems to play an important role in increasing the biodiversity of the ecosystem, with some species found only as epibionts on P. rudis.     

Assessment of subsurface structural elements around greater Cairo by using integrated geophysical tools

Geophysical techniques such as gravity, magnetic and seismology are perfect tools for detecting subsurface structures of local, regional as well as of global scales. The study of the earthquake records can be used for differentiating the active and non-active fault elements. In the current study, more than 2,200 land magnetic stations have been measured using two proton magnetometers. The data are corrected for diurnal variations and then reduced by the International Geomagnetic Reference Field. The corrected data have been interpreted by different techniques after filtering the data to separate shallow sources (basaltic sheet) from the deep sources (basement complex). Both Euler deconvolution and 3-D magnetic modeling were carried out. The results of interpretation indicate that the depth to the upper surface of basaltic sheet ranges from <10 to 600 m, depth to the lower surface ranges from 60 to 750 m, while the thickness of the basaltic sheet varies from <10 to 450 m. Moreover, gravity measurements are conducted at 2,250 stations using a CG-3 gravimeter. The measured values are corrected to construct a Bouger anomaly map. The least squares technique is then applied for regional–residual separation. The third order of least squares is found to be the most suitable to separate the residual anomalies from the regional one. The resultant third-order residual gravity map is used to delineate the structural fault systems of different characteristic trends. The trends show an NW–SE trend parallel to that of Gulf of Suez, an NE–SW trend parallel to the Gulf of Aqaba and an E–W trend parallel to that of the Mediterranean Sea. Taking seismological records into consideration, it is found that most of the 24 earthquake events recorded in the study area are located on fault elements. This gives an indication that the delineated fault elements are active.     

A generalized rigid particle contact model for fracture analysis

Rigid particle models taking directly into consideration the physical mechanisms and the influence of the material meso‐structure have recently been developed for fracture studies of quasi‐brittle material such as concrete. The formulation of a generalized contact model for rigid particle simulations is presented in which the contact discretization is a model parameter. The contact model performance for different discretizations is evaluated for uniaxial tensile tests, for uniaxial compression tests and for a notched beam in mode I. Copyright © 2005 John Wiley & Sons, Ltd.     

Revisiting hydrocarbons source appraisal in sediments exposed to multiple inputs

The aim of this work was to test the efficiency of statistical methods as compared to the traditional diagnostic ratios to improve hydrocarbon source identification in sediments subjected to multiple inputs. Hydrocarbon determination in Guanabara Bay sediments pointed out high degradation and ubiquitous petrogenic pollution through the presence of high unresolved complex mixture. Polycyclic aromatic hydrocarbon (PAHs) ratios suggested pervasive contamination derived from combustion in all sediments and failed discriminating samples despite the specificity of sources in different sampling sites. Principal component analysis (PCA) effectively distinguished the petrogenic imprint superimposed to the ubiquitous combustion contamination, since this technique reduces the influence of PAHs distribution which is common to all samples. PCA associated to multivariate linear regression (MLR) allowed a quantitative assessment of sources confirming predominance of the pervasive contaminant component superimposed to a generalized petrogenic imprint. The pervasive component derives from combustion contributions as well as from differential PAHs degradation.     

Accuracy of grid precipitation data for Brazil: application in river discharge modelling of the Tocantins catchment

Here, we compared grid precipitation data — Climate Forecast System Reanalysis (CFSR) and WATCH Forcing Data methodology applied to ERA‐Interim (WFDEI) data — with Brazilian Weather Bureau (INMET) and Brazilian Water Agency (ANA) rain gauge data (n = 2027) for the period 1980–2010 in order to evaluate which grid data set better represents precipitation, and is thus more suitable for hydrological modelling of Brazilian water resources. We found that WFDEI outperformed CFSR according to three statistical indicators. We then applied and interpolated a simple bias correction to further improve WFDEI data before we used these data to model river discharge of the Tocantins catchment with the Soil and Water Assessment Tool (SWAT). Calibration (validation in parentheses; weighted averages of all gauges) had satisfactory statistical metrics: p‐factor = 0.52 (0.47); r‐factor = 0.84 (0.99); R² = 0.78 (0.71); bR² = 0.68 (0.47); NS = 0.70 (0.66); Pbias = ?4.5 (4.0). Finally, the calibrated SWAT model was used to assess the spatial distribution of the catchment's water resources. Annual green water flow (evapotranspiration) increased from the south‐east (640–840 mm yr^?1) to north‐west (1140–1440 mm) of the Tocantins catchment, while green water storage (soil water content) increased from south (330–1070 mm) to north (2180–3290 mm). Blue water (water yield) had a less clear pattern, with lower values in the south and the central borders of the catchment (20–560 mm) and higher values along the central axis and the north (920–1460 mm). Our analysis suggested that WFDEI was an accurate representation of Brazilian precipitation. For large catchments, we therefore recommend the use of WFDEI instead of sparse and often missing rain gauge data in modelling Brazilian water resources. Copyright © 2015 John Wiley & Sons, Ltd.