Speciation of Fe in the Eastern North Atlantic Ocean

In the Eastern North Atlantic Ocean iron (Fe) speciation was investigated in three size fractions: the dissolvable from unfiltered samples, the dissolved fraction (<0.2 μm) and the fraction smaller than 1000 kDa (<1000 kDa). Fe concentrations were measured by flow injection analysis and the organic Fe complexation by voltammetry. In the research area the water column consisted of North Atlantic Central Water (NACW), below which Mediterranean Overflow Water (MOW) was found with the core between 800 and 1000 m depth. Below 2000 m depth the North Atlantic Deep Water (NADW) proper was recognised. Dissolved Fe and Fe in the <1000 kDa fraction showed a nutrient like profile, depleted at the surface, increasing until 500–1000 m depth below which the concentration remained constant. Fe in unfiltered samples clearly showed the MOW with high concentrations (4 nM) compared to the overlying NACW and the underlying NADW, with 0.9 nM and 2 nM Fe, respectively. By using excess ligand (Excess L) concentrations as parameter we show a potential to bind Fe. The surface mixed layer had the highest excess ligand concentrations in all size fractions due to phytoplankton uptake and possible ligand production. The ratio of Excess L over Fe proved to be a complementary tool in revealing the relative saturation state of the ligands with Fe. In the whole water column, the organic ligands in the larger colloidal fraction (between 0.2 μm and 1000 kDa) were saturated with Fe, whereas those in the smallest fraction (<1000 kDa) were not saturated with Fe, confirming that this fraction was the most reactive one and regulates dissolution and colloid aggregation and scavenging processes. This regulation was remarkably stable with depth since the alpha factor (product of Excess L and K′), expressing the reactivity of the ligands, did not vary and was 10¹³. Whereas, in the NACW and the MOW, the ligands in the particulate (>0.2 μm) fraction were unsaturated with Fe with respect to the dissolved fraction, thus these waters had a scavenging potential.     

Petrographical, geochemical and geochronological constraints on igneous clasts and sediments hosted in the Oligo-Miocene Bakony Molasse, Hungary: evidence for a Paleo-Drava River system

The provenance of igneous clasts and arenitic sediment enclosed within the Bakony Molasse was studied using geochemical and geochronological methods. The majority of igneous clasts were eroded from the Oligocene Periadriatic magmatic belt. A part of the andesite material has Eocene formation age. Rhyolitic pebbles originated from Permian sequences of the Greywacke zone or the Gurktal Alps. Apatite fission track (FT) ages from the sandstone matrix (age clusters at ~75 and ~30 Ma) are typical for the Austroalpine nappe pile and for the cooling ages of Periadriatic magmatic belt. Variscan detrital zircon FT ages indicate source areas that had not suffered Alpine metamorphism, such as the Bakony Mountains, Drauzug and the Southern Alps. Another group of detrital zircon grains of Late Triassic-Jurassic FT age (mean: ~183 Ma) marks source zones with Mesozoic thermal overprint such as the Gurktal Alps and some Austroalpine regions. Zircon grains with Oligocene FT age (mean: ~34.7 Ma) were derived from the Periadriatic intrusives and their contact zones. On the basis of the new data, we propose that the ancestor of the recent Drava River had already existed in Oligo-Miocene time and distributed eroded material of the southern Eastern Alps to the east.     

Finite element modeling of the July 12, 1993 Hokkaido Nansei-Oki tsunami

A fault plane model and a finite element hydrodynamic model are applied to the simulation of the Hokkaido Nansei-Oki tsunami of July 12, 1993. The joint performance of the models is assessed based on the overall ability to reproduce observed tsunami waveforms and to preserve mass and energy during tsunami propagation. While a number of observed characteristics of the waveforms are satisfactorily reproduced (in particular, amplitudes and arrival times at tidal gauges relatively close to the source, and general patterns of energy concentration), others are only marginally so (notably, wave periods at the same gauges, and wave heights along Okushiri); differences between observations and simulations are traceable to both the fault plane and the hydrodynamic models. Nonnegligible losses of energy occur throughout the simulated tsunami propagation. These losses seem to be due to a combination of factors, including numerical damping and possible deficiencies of the shallow water equations in preserving energy.     

Opportunities for pollen stratigraphic analysis of shallow lake sediments: the example of Lake Balaton

Relying on several decades of research experience, ever more new methods and methodological approaches, the opportunities of the application of palynological analysis for shallow lake sediments are summarised. New findings — not yet appeared in international publications — are also mentioned and illustrated. Further tasks of research are outlined.     

Analysis of mobility data – A focus on Mobile Mapping Systems

ABSTRACT

The increasing availability of devices to capture the position of moving objects (and other environmental information) leads to a very large amount and variety of mobility data. In order to obtain important information about the objects, their behavior or the environment of the objects, an automatic analysis is required. This article highlights current research questions in the context of the analysis of mobility data and presents them on the basis of work carried out at the Institute of Cartography and Geoinformatics (ikg) at Leibniz University of Hannover, Germany. A focus is put on the analysis and exploitation of information from Mobile Mapping vehicles.     

Probabilistic assessment of travel times in groundwater modeling

A Monte Carlo approach is described for the quantification of uncertainty on travel time estimates. A real (non synthetic) and exhaustive data set of natural genesis is used for reference. Using an approach based on binary indicators, constraint interval data are easily accommodated in the modeling process. It is shown how the incorporation of imprecise data can reduce drastically the uncertainty in the estimates. It is also shown that unrealistic results are obtained when a deterministic modeling is carried out using a kriging estimate of the transmissivity field. Problems related with using sequential indicator simulation for the generation of fields incorporating constraint interval data are discussed. The final results consists of 95% probability intervals of arrival times at selected control planes reflecting the original uncertainty on the transmissivity maps.     

Quaternary reactivation of flexural-slip folds by diapiric activity: example from the western Ebro Basin (Spain)

In the western sector of the Ebro Basin two types of structures deform the Quaternary terraces and pediments developed by the Ebro River and its tributaries: (1) folds up to 10 km long in the lower levels of fluvial terraces and (2) normal listric faults that produce tilting and rollover anticlines of the Quaternary deposits. Both types of structures are linked to the geometrical and lithological features of the Tertiary beds that underlie the Quaternary deposits. Quaternary folds, whose axes are parallel to the strike of the Tertiary beds, are the result of reactivation of Tertiary large-scale (60 km long) folds due to diapirism of their gypsum cores, where the gypsum units reach a maximum thickness of 3 000 m. This reactivation produced flexural-slip in some beds on the limbs of the folds, bringing about the folding of the overlying Quaternary terraces. The mechanism of Quaternary folding involves layer-parallel shear in alternating Tertiary units and folding linked to detachments and reverse layer-parallel faults. Normal listric faults are widespread throughout the studied area. They are partly parallel to low dipping Tertiary beds and are the result of a NNE-SSW tectonic extension, compatible with minor structures and focal mechanisms of recent earthquakes. The relationship between the two kinds of Quaternary structures indicates that diapirism of the gypsum cores of the anticlines was activated by extensional tectonics.     

Contribution of nitrogen and phosphorus by precipitation in the drainage basin of the Santillana Reservoir (Madrid)

The contribution of nitrogen and phosphorus due to precipitation constitutes the second most important route after superficial runoff. The sampling carried out during a two-year period by means of a precipitation collector allows us to determine the contribution of this route both qualitatively and quantitatively. Nitrogen is mainly supplied in an inorganic form, while phosphorus is principally supplied as orthophosphate. During the period of this study (March 1986–February 1988) it was found that in the Santillana Reservoir Watershed the level of nitrogen supplied by precipitation constitutes an average of 4.87% and the level of phosphorus constitutes 8.01%. The contribution of nitrogen varies in inverse ratio to precipitation and the contribution of phosphorus varies in direct ratio.