Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.     

Provenance of the Bosnian Flysch

Sandwiched between the Adriatic Carbonate Platform and the Dinaride Ophiolite Zone, the Bosnian Flysch forms a c. 3000 m thick, intensely folded stack of Upper Jurassic to Cretaceous mixed carbonate and siliciclastic sediments in the Dinarides. New petrographic, heavy mineral, zircon U/Pb and fission-track data as well as biostratigraphic evidence allow us to reconstruct the palaeogeology of the source areas of the Bosnian Flysch basin in late Mesozoic times. Middle Jurassic intraoceanic subduction of the Neotethys was shortly followed by exhumation of the overriding oceanic plate. Trench sedimentation was controlled by a dual sediment supply from the sub-ophiolitic high-grade metamorphic soles and from the distal continental margin of the Adriatic plate. Following obduction onto Adria, from the Jurassic–Cretaceous transition onwards a vast clastic wedge (Vranduk Formation) was developed in front of the leading edge, fed by continental basement units of Adria that experienced Early Cretaceous synsedimentary cooling, by the overlying ophiolitic thrust sheets and by redeposited elements of coeval Urgonian facies reefs grown on the thrust wedge complex. Following mid-Cretaceous deformation and thermal overprint of the Vranduk Formation, the depozone migrated further towards SW and received increasing amounts of redeposited carbonate detritus released from the Adriatic Carbonate Platform margin (Ugar Formation). Subordinate siliciclastic source components indicate changing source rocks on the upper plate, with ophiolites becoming subordinate. The zone of the continental basement previously affected by the Late Jurassic–Early Cretaceous thermal imprint has been removed; instead, the basement mostly supplied detritus with a wide range of pre-Jurassic cooling ages. However, a c. 80 Ma, largely synsedimentary cooling event is also recorded by the Ugar Formation, that contrasts the predominantly Early Cretaceous cooling of the Adriatic basement and suggests, at least locally, a fast exhumation.     

Transition from eclogite to amphibolite-facies metamorphism in the Austroalpine Ulten Zone

Summary The Ulten Zone of the Austroalpine crystalline basement south-west of Meran (Italy) contains metapelitic schists and granoblastic paragneisses, leucocratic orthogneisses, migmatites (in both gneiss-lithologies), metabasites and ultramafic lenses. Metamorphic textures of the metapelitic schists and granoblastic paragneisses indicate two different metamorphic events, characterized by two mineral assemblages, which differ in mineral chemistry: (1) an eclogite facies mineral assemblage (M1) comprising Grt-Ky I-Bt. Ms-Kfs-PI-Qtz-Rt, and (2) an amphibolite facies mineral assemblage (M2) comprising Grt-KyII-Bt-Ms-PI-Qtz-Ilm±St. For the M1 event, pressures of at least 15kbar and temperatures of about 700°±50°C can be estimated. The later amphibolite facies overprint occurred at pressures of 6 to 8kbar and about 600°±50°C. The M1 and M2 assemblages belong to a continuous clockwise metamorphic evolution during the Variscan orogeny. Evidence for Alpine metamorphism can only be detected by sericite rims around kyanite and reset biotite ages. The migmatites, which contribute about 15–30vol.% of all rocks in the investigated area, were formed on the prograde path during the M1 event. Dissolution of H₂O in the melted part of the migmatites resulted in a CO₂dominated fluid, which was trapped in primary kyanite (M1) fluid inclusions. Secondary H₂O-rich fluid inclusions are found in quartz grains and may represent the fluid which enabled a pervasive equilibration during M2.

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Übergang von eklogit-zu amphibolitfazieller Matamorphose in der austroalpinen Ultenzone

Zusammenfassung Die Ulten Zone, ein Teil des ostalpinen kristallinen basements, südwestlich von Meran, wird aus Metapeliten and granoblastischen Paragneisen, leukokraten Orthogneisen, Migmatiten (in beiden Lithologien), Metabasiten and ultramafischen Linsen aufgebaut. Metamorphe Texturen der Metapelite und granoblastischen Paragneise lassen auf zwei verschiedene metamorphe Ereignisse schließen, die durch unterschiedliche Mineral-chemismen und Paragenesen charakterisiert sind: (1) eine eklogitfazielle Paragenese (M1), bestehend aus Grt-KyI-Bt-Ms-Kfs-P1-Qtz-Rt und (2) eine amphibolitfazielle Paragenese (M2), bestehend aus Grt-KyII-Bt-Ms-P1-Qtz-Ilm±St. Für M1 konnten Minimaldrucke von 15kbar und Temperaturen von 700°±50°C abgeleitet werden. Die spätere amphibolitfazielle Überprägung fand bei 6 bis 8kbar und 600°±50°C statt. M1 und M2 gehören einer kontinuierlichen Metamorphoseentwicklung während der variszischen Orogenese an.Die Migmatite, ungefähr 15–30vol.% der Gesteine im untersuchten Gebiet, wurden am prograden Pfad während des M1 Ereignisses gebildet. Aufgrund der höheren Löslichkeit von H₂0 in der Schmelze, blieb ein CO₂, reiches Fluid zurück, das im primären Kyanit (M1) eingeschlossen wurde. Wässrige Flüssigkeitseinschlüsse können in Quarzkörnern gefunden werden. Dieses Fluid ist wahrscheinlich für die Reequilibrierung zu amphibolitfaziellen Bedingungen verantwortlich.

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With 5 Figures     

Exclusive rights to fish: Towards a rational fisheries policy

Discusses the tragedy of the commons with regard to fish resources in the North Atlantic, and points to the fact that the Atlantic cod has now been so heavily exploited that a strong regulation of fisheries is needed to preserve an exploitable stock. The author argues for exclusive economic zones dividing up the remaining loopholes among coastal nations and individually transferable quotas.     

Red dust rain within the Spanish Mediterranean area

Dust rain belongs to the climatological conditions of the Iberian Peninsula's Mediterranean seaboard. Traditionally known as muddy' or bloody rains, red dust rain has become a topical issue as a result of more frequent rainfall of this kind in recent years. In spite of the difficulties that studying this phenomenon involves, owing to the lack of systematically kept records at meteorological observatories, details are provided of the high frequency of such phenomena within the Spanish Mediterranean area, using records from other phenological sources. The study analyzes the chemical composition of red dust rain and the atmospheric factors giving rise to such phenomena. Whether there is a relationship betwen the higher frequency of dust rain and possible changes in global atmospheric circulation is as yet unclear.     

A nonlinear tensor field and the second metric tensor

In our preceding paper {see [L. Sh. Grigorian and S. Gottlöber, Astrofizika (in press)]} we investigated a self-gravitating system consisting of a scalar field and a linear tensor field _ik= _ki with minimal coupling and with allowance for the action of vacuum polarization effects. In the present paper we investigate the case of a nonlinear tensor field _ik. The action S ⁽⁾ of the field _ik is determined by the difference R_ik — _ik, where R_ik is the space-time Ricci tensor and Rik is the analogous quantity constructed using the metric _ik=g_ik+_ik induced by _ik ( is a free parameter). Here S ⁽⁾ coincides with the previously known expression for the action of a linear field _ik. Equations of motion are derived for _ik in curved space-time. The energy-momentum metric tensor, determining the contribution of _ik to the gravitational field equations, is calculated.Translated from Astrofizika, Vol. 39, No. 1, pp. 135–144, January-March, 1996.     

Effects of water on strength and failure mode of coarse-grained granites at 300°C

Summary Deformation experiments have been performed in a triaxial compression cell at a temperature of 300°C and confining pressures up to 65 MPa using samples of homogeneous, fresh two-mica-granite (RM) and monzogranite (CM). The cylindrical specimens (d=70 mm, h=140 mm, V=540 cm³) were tested undrained under dry (105°C), as received, and water saturated conditions at deformation rates between and . The mechanical behaviour of the two types of coarse-grained, crystalloblastic granites is critically influenced by mineralogical composition, porosity, and the amount of intergranular water present in the samples. The failure stress of the CM granite is at about 65% of that of the RM granite; in both rocks strength decreases with increasing porosity and water content.The presence of interstitial water causes a failure mode of non-localized, homogeneously distributed microcracking in the central parts of the samples, whereas, in runs with dry granites, strain localization along a single shear fracture was observed. When aqueous fluids are present, the macroscopic style of deformation of granites appears to be ductile even at lowP andT conditions. Strength and angle of internal friction are reduced to very low values. The style of deformation, as well as the reduction of strength of the water-saturated rock samples, is due to mechanical and chemical effects of intergranular water at elevated temperatures.The maximum differential stresses measured for these coarse-grained granites are much lower than the strength commonly reported for other granites, e. g. Westerly and Charcoal granites. Our data suggest that the strength of the granitic crust under differential stress is lower than currently deduced from laboratory experiments.     

Early Cretaceous volcaniclastic and quartzose sandstones from north central Nepal: composition,sedimentology and geotectonic significance

Early Cretaceous sandstones and shales from the Thakkhola region (Chukh and Tangbe Formations) were deposited on the subsiding northern (Tethyan) margin of Gondwana; current directions indicate a source area to the south. Whereas the Berriasian Chukh Formation is dominated by quartz arenites, volcaniclastic sandstones and minor conglomerates dominate the Tangbe Formation of Valanginian to Aptian age. Upsection, the composition of the volcaniclastic components changes from mainly basaltic to dominantly dacitic/rhyolitic. Magmatism was preceded and accompanied by strong uplift in the source area of the Chukh and Tangbe clastics, resulting in the erosion of probably more than several hundred meters of pre-Cretaceous sedimentary, metamorphic and plutonic rocks. A geochemical whole rock analysis of basaltic pebble fragments shows their alkaline character and suggests a within-plate geotectonic setting for the volcanic source. This volcanotectonic event is probably related to rifting between Australia and Greater India, where seafloor spreading began in late Valanginian/Hauterivian times.     

Automatic equipment to monitor groundwater radon

Prototype instrumentation, able to automatically measure groundwater radon content variations, is presented. The equipment is made of stainless steel and has spherical valves with automatic and pneumatic control. The deemanation of the gases from the water is obtained by evacuating a suitable expansion chamber. The instrumentation can make discrete sampling ranging from 1 per hour to 1 per 99 hours. The equipment was tested in the laboratory: the efficiency was measured by means of a²⁶⁶Ra solution. A mean value of (0.65±0.07) count/s/Bq was obtained. A calibration test was carried out by comparing countings from the automatic equipment with those obtained by the standard laboratory cell. Results of an operational check over a period of approximately one year indicate that variations in radon at the calibration site are attributable more to meteorological than to tectonic causes.     

Fossil carotenoids and paleolimnology of meromictic Mahoney Lake,British Columbia,Canada

Vertical distribution of fossil carotenoids in a sediment core from meromictic Mahoney Lake was studied. Besides okenone and demethylated okenone, lutein and zeaxanthin and-carotene isomers were identified. No carotenoids typical for purple nonsulfur or green sulfur bacteria were detected. The ratio of zeaxanthin to lutein (above 1:1 in all samples) indicates a dominance of cyanobacteria over green algae in the phytoplankton assemblages of the past. Okenone, which is found exclusively in Chromatiaceae, was the dominating carotenoid in all sediment zones.The oldest sediment layers containing okenone were deposited 11 000 years ago. Between 9000 and 7000 and since 3000 years b.p., Chromatiaceae reached a considerable biomass in the lake. Vertical changes in okenone concentration were not related to changes of paleotemperatures. In contrast, okenone concentrations decreased during periods of volcanic ash input. During most of the lake history, however, mean okenone concentrations were positively correlated with sedimentation rates. This indicates that vertical changes of okenone concentration in the sediment reflect past changes of purple sulfur bacterial biomass in the lake.According to these results, the past limnology of Mahoney Lake resembled that of the present with a sulfide-containing monimolimnion and a well-developed population of okenone-bearing purple sulfur bacteria.