Three-dimensional nonlinear seismic analysis of concrete faced rockfill dams subjected to scattered P,SV, and SH waves considering the dam–foundation interaction effects

In this study, the nonlinear seismic analysis of a typical three-dimensional concrete faced rockfill dam is reported. Three components of the Loma Prieta (Gilroy 1 station) earthquake acceleration time history are used as input excitation. The dam under study is considered as if it were located in a prismatic canyon with a trapezoidal cross-section. A nonlinear model for the rockfill material is used, and contact elements with Coulomb friction law are utilized at the slab–rockfill interface. Vertical joints in the face slab are also considered in the finite element model. A substructure method, in which the unbounded soil is modelled by the scaled boundary finite element method (SBFEM), is used to obtain the scattered motion and interaction forces along the canyon. The dam is subjected to spatially variable P, SV, and SH waves, and the effect of dam–foundation interaction and the reservoir water effects are considered. The results are compared with the non-scattered input motion analysis. Results of the analyses indicate that due to applying the scattered motion to the canyon the response of the dam and concrete face slab significantly increases. The reservoir water pressure affects the tensile stresses induced in the face slab by reducing the uplift movement of the concrete panels.Large horizontal axial forces are induced in the face slab due to out-of-phase and out-of-plane motions of the abutments. Although the normal movements of vertical joints are reduced due to the reservoir water confinement, the opening movements are still significant, and the local failure of construction joints is inevitable.     

Application of inverse geochemical modelling for predicting surface water chemistry in Ekbatan watershed,Hamedan, western Iran

ABSTRACT

A study of surface water chemistry evolution was conducted by multivariate statistical analysis and inverse geochemical modelling using the PHREEQC computer program. Using hierarchical cluster analysis the 14 sampling sites were classified into three groups (recharge, transition and discharge areas). Water chemistry changed along a flow path so that waters with Ca–HCO₃ and Mg–Cl composition changed to Mg–Cl–HCO₃ waters. The order of abundance of the major cations was Mg > Ca > Na > K. Their average concentrations were 21, 19, 3.6 and 2.5 mg L^-1, respectively. Inverse geochemical modelling along flow paths indicated that the dissolution of sylvite and kaolinite, and precipitation of feldspars and andalusite, happened with Na entering the solution and Ca, Mg and K leaving the solution.

Editor D. Koutsoyiannis; Associate editor not assigned     

Enhancement of Carbon Dioxide Capture by Amine‐Functionalized Multi‐Walled Carbon Nanotube

In this study, crude multi‐walled carbon nanotubes (MWCNT) was functionalized by a two‐step process; first using strong mixed acids (H₂SO₄/HNO₃) and then treatment with 1,3‐phenylenediamine (mPDA). The equilibrium adsorption of CO₂ on pristine MWCNT and amine functionalized MWCNT (MWCNT‐NH₂) were investigated. Experiments were preformed via application of volumetric method in a dual sorption vessel at temperature range of 298–318 K and pressures up to 40 bars. The results obtained indicated that the equilibrium uptake of CO₂ increased after functionalizing of MWCNT. The increase in CO₂ capture by MWCNT‐NH₂ was attributed to the existence of great affinity between CO₂ molecules and amine sites on this adsorbent at low pressures. The experimental data were analyzed by means of Freundlich and Langmuir adsorption isotherm models. The data obtained revealed a fast kinetics for the adsorption of CO₂ in which most of adsorption occurred at initial period of adsorption experiments. This renders MWCNT as a suitable adsorbent for practical applications. Values of isosteric heat of adsorption were evaluated based on Clausius–Clapeyron equation. The results demonstrated that both chemisorption and physisorption played important role in CO₂ adsorption on MWCNT‐NH₂, whereas the physisorption process was dominant for CO₂ adsorption on MWCNT.     

Extent of diagenetic transformations in severely altered biogenic silica deposits from Tunisia: new insights from mineralogy and geochemistry

Sedimentary biogenic silica from Redeyef in Gafsa basin (southern Tunisia) was analysed for its ²⁹Si and ²⁷Al magic angle spinning nuclear magnetic resonance (MAS NMR) spectra and complemented by X-ray diffraction and SEM observations. The ²⁹Si MAS NMR spectrum is characterized by the abundance of hydroxylated silicon, displayed in resonance intensities and reflects a clear tendency towards dissolution of diatomaceous amorphous silica and the occurrence of the hydrated silica, which is the main component that ensures the diagenetic transition via the mechanism of dissolution–precipitation to other more crystalline silica phases, after the lost of its hydroxyls groups (water) by heating (burial). ²⁷Al MAS NMR reveals two coordinations of Al; the octahedrally coordinated Al suggests the presence of clay relics trapped during crystal growth or a microcrystalline zeolite (clinoptilolite detected by SEM observations), while the tetrahedrally coordinated Al suggests the presence of minor quantities of minerals with tetrahedral Al, such as an Al-rich fluid and/or minerals such as feldspars.     

Effect of climate change on sea water intrusion in coastal aquifers

There is increasing debate these days on climate change and its possible consequences. Much of this debate has focused in the context of surface water systems. In many arid areas of the world, rainfall is scarce and so is surface runoff. These areas rely heavily on groundwater. The consequences of climate change on groundwater are long term and can be far reaching. One of the more apparent consequences is the increased migration of salt water inland in coastal aquifers. Using two coastal aquifers, one in Egypt and the other in India, this study investigates the effect of likely climate change on sea water intrusion. Three realistic scenarios mimicking climate change are considered. Under these scenarios, the Nile Delta aquifer is found to be more vulnerable to climate change and sea level rise. Copyright © 1999 John Wiley & Sons, Ltd.