Acquisition de salinité et qualité des eaux d’une nappe profonde en Tunisie: approche statistique et géochimique

Abstract

The multi-layered Jeffara de Gabes aquifer system is greatly influenced by tectonics. This system is limited at the base and laterally by evaporite layers and has lateral contacts with the sebkhas (salt flats). The groundwater in this aquifer is characterized by high salinity (3–10 g L^-1). Multivariate statistical analysis and a geochemical approach were applied to determine the influence of the evaporite layers and sebkhas on the hydrochemical quality of the Jeffara de Gabes aquifer, and to understand the processes governing its salinity. According to these methods, and based in part on the Sr²⁺/Ca²⁺ ratio, it is demonstrated that the strong salinity of the groundwater is due to interactions between water and the evaporite layers that act as a substratum of this aquifer, as well as saltwater intrusion from the sebkhas. Moreover, the medium- to poor-quality groundwaters are characterized by geochemical interactions: cationic exchange and the precipitation/dissolution process of minerals in the aquifer formations.

Editeur Z.W. Kundzewicz

Citation Ben Alaya, M., Zemni, T., Mamou, A. et Zargouni, F., 2014. Acquisition de salinité et qualité des eaux d’une nappe profonde, Tunisie: approche statistique et géochimique. Hydrological Sciences Journal, 59 (2), 395–419.     

Preparation of Nano‐Lepidocrocite and an Investigation of Its Ability to Remove a Metal Complex Dye

Lepidocrocite (γ‐FeOOH) nanoparticles were synthesized from iron(II) sulfate solution and characterized using X‐ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform‐IR (FT‐IR), nitrogen adsorption, and point of zero charge pH (pH_PZC) analyses. TEM, XRD, and FT‐IR analyses proved the synthesis of nano‐lepidocrocite. Surface area and pH_PZC of the synthesized lepidocrocite were 68.1 m² g^?1 and 4.8, respectively. Utilization of the synthesized lepidocrocite in the adsorption of Lanacron brown S‐GL (LBS‐GL) from aqueous solutions was investigated, and the effect of lepidocrocite dosage, pH, temperature, and contact time on this process were optimized and modeled using response surface methodology approach. The lepidocrocite dosage of 0.015 g, pH 3.5, temperature of 38°C, and contact time of 100 min were determined as optimum adsorption conditions. Isotherm and kinetics of the adsorption process were analyzed at the optimum conditions. The equilibrium data were fitted well to the Langmuir isotherm model. The maximum monolayer adsorption capacity was 528.21 mg g^?1. The adsorption process was described by the pseudo‐second‐order kinetic model. Furthermore, the effect of pH on the desorption of LBS‐GL was investigated. High LBS‐GL desorption efficiency was achieved at a high pH value.     

Evaluation of Methods for Determining Crack Initiation in Compression Tests on Low-Porosity Rocks

Laboratory testing of rocks is traditionally carried out to determine the peak strength using the ISRM Suggested Methods or other suitable standards. However, it is well known that in low-porosity crystalline rocks there are at least three distinct stages of compressive loading that can be readily identified if the stress–strain response is monitored during the loading process: (1) crack initiation, (2) unstable crack growth, i.e., crack coalescence and (3) peak strength. Crack initiation is noted as the first stage of stress-induced damage in low-porosity rocks, yet the suggested guidelines of the ISRM for compression tests make no mention of crack initiation. In addition, recent research suggests that crack initiation can be used as an estimate for the in situ spalling strength, commonly observed around underground excavations in massive to moderately jointed brittle rocks. Various methods have been proposed for identifying crack initiation in laboratory tests. These methods are evaluated using ten samples of ?sp? Diorite and the results are compared with a simplified method, lateral strain response. Statistically, all methods give acceptable crack-initiation values. It is proposed that the ISRM Suggested Methods be revised to include procedures suitable for establishing the crack-initiation stress.     

A Neuro-Genetic Network for Predicting Uniaxial Compressive Strength of Rocks

Uniaxial Compressive Strength (UCS) is considered as one of the most important parameters in designing rock structures. Determination of this parameter requires preparation of rock samples which is costly and time consuming. Moreover discrepancy of laboratory test results is often observed. To overcome the drawbacks of traditional method of UCS measurement, in this paper, predictive models based on neuro-genetic approach and multivariable regression analysis have been developed for predicting compressive strength of different type of rocks. Coefficient of determinatoin (R2) and the Mean Square Error (MSE) were calculated for comparison of the models’ efficiency. It was observed that accuracy of the neuro-genetic model is significantly better than regression model. For the neuro-genetic and regression models, R2 and MSE were equal to 95.89 % and 0.0045 and 77.4 % and 1.61, respectively. According to sensitivity analysis for neuro-genetic model, Schmidt rebound number is the most effective parameter in predicting UCS.     

Hydrogeochemistry of Groundwater and Its Suitability for Drinking and Agricultural Use in Nahavand,Western Iran

Groundwater is the major source of drinking water in Nahavand city. However, the groundwater quality at the agricultural areas has been deteriorating in recent years. Ground water quality monitoring is a tool which provides important information for water management and sustainable development of the water resources in Nahavand. Hydrochemical investigations were carried out in an agricultural area in Nahavand, western Iran, to assess chemical composition of groundwater. In this study, 64 representative groundwater samples were collected from different irrigation wells and analyzed for pH, electrical conductivity, major ions, and nitrate. The results of the chemical analysis of the groundwater showed that concentrations of ions vary widely and the most prevalent water type is Ca–Mg–HCO₃, followed by other water types: Ca–HCO₃, Ca–Na–HCO₃, and Na–Cl, which is in relation with their interactions with the geological formations of the basin, dissolution of feldspars and chloride and bicarbonate minerals, and anthropogenic activities. Thirty-seven percent of the water samples showed nitrate (NO₃ ⁻) concentrations above the human affected value (13 mg L⁻¹). The phosphorous (P) concentration in groundwater was between 0.11 and 0.90 mg L⁻¹, with an average value of 0.30 mg L⁻¹, with all of the samples over 0.05 mg L⁻¹. The most dominant class C2-S1 (76.5%) was found in the studied area, indicating that sodicity is very low and salinity is medium, and that these waters are suitable for irrigation in almost all soils. Agronomic practices, such as cultivation, cropping, and irrigation water management may decrease the average NO₃ ⁻ concentration in water draining from the soil zone.     

Nitrate pollution of groundwater in Toyserkan,western Iran

A total of 95 groundwater samples were collected from Toyserkan, western Iran to assess the chemical composition and nitrate (NO₃ ⁻) status of groundwater. The most prevalent water type is Ca–HCO₃ followed by water types Ca–Mg–HCO₃. In comparison with the World Health Organization (WHO) drinking water guideline of 50 mg l⁻¹ for NO₃ ⁻, a total of nine wells (9.5%) showed higher concentrations. In 36% of samples (34) NO₃ ⁻ concentration was low (<20 mg l⁻¹), and in 53.7% of samples (51), in the range of 20–50 mg l⁻¹. The samples were classified into four groups based on NO₃ ⁻ and chloride (Cl⁻) concentrations. Of the samples, 40% were classified as group 4 and were relatively high in Cl⁻ and NO₃ ⁻ (Cl⁻ > 47 mg l⁻¹, NO₃ ⁻ > 27 mg l⁻¹). The high correlation between NO₃ ⁻ and Cl⁻ (r = 0.86, p < 0.01) is consistent with a manure source, resulting from the practice of adding salt to animal feed. Pollution of groundwaters appeared to be affected by the application of inorganic fertilizer at greater than agronomic rates, Cl-salt inputs, and irrigation practice.     

The origin of mafic rocks in the Naqadeh intrusive complex, Sanandaj-Sirjan Zone, NW Iran

The Naqadeh mafic plutonic rocks are located on a plutonic assemblage and include different granitoid rocks related to ～40 Ma. U-Pb SHRIMP data shows different ages of 96?±?2.3 Ma for mafic rocks. Naqadeh mafic plutonic rocks consist of diorite to diorite-gabbros with relatively high contents of incompatible elements, low Na2O, and $ {\hbox{Mg\# }} = \left[ {{\hbox{molar}}\;{100} \times {\hbox{MgO/}}\left( {{\hbox{MgO}} + {\hbox{FeO}}} \right)} \right] > 44.0 $ . These features suggest that the Naqadeh mafic rocks originate from enriched lithospheric mantle above subducted slab during Neotethys subduction under Iranian plate.     

Geodynamic setting and emplacement of mylonitic granitoids within the North Golpayegan shear zone,Iran

The metamorphic complex of the North Golpayegan is part of the Sanandaj-Sirjan Zone. There are at least three distinct stages of deformation in this complex. Throughout the first stage, Paleozoic and Mesozoic sedimentary rocks have experienced regional metamorphism during Late Jurassic tectonic events related to the subduction of the Neo-Tethys oceanic lithosphere under the Iranian microcontinent. During the second deformation stage in the Late Cretaceous-Paleocene, the rocks have been mylonitized. The third stage of deformation in the region has led to folding and faulting superimposed on previous structures, and to exhumation of the metamorphic complex. This stage has determined the current morphology and N70E strike of the complex. The mylonitic zones of the second stage of deformation have been formed along the dextral transpressional faults. During the third stage of deformation and exhumation of the metamorphic complex, the mylonitic zones have been uplifted to the surface. The granitoids in the metamorphic complex have been injected along the extensional shear fractures related to the dextral transpressional displacements. The granitoids have been transformed into mylonites within the synthetic or antithetic shear zones. These granitoids are recognized as syncollision type (CCG) and have been formed at the end of orogenic events synchronous to the collision between the Arabian and the Iranian plates at the Late Cretaceous-Paleocene.     

Biosorption of Cd(II), Ni(II) and Pb(II) from Aqueous Solution by Dried Biomass of Aspergillus niger: Application of Response Surface Methodology to the Optimization of Process Parameters

In this study, the biosorption of Cd(II), Ni(II) and Pb(II) on Aspergillus niger in a batch system was investigated, and optimal condition determined by means of central composite design (CCD) under response surface methodology (RSM). Biomass inactivated by heat and pretreated by alkali solution was used in the determination of optimal conditions. The effect of initial solution pH, biomass dose and initial ion concentration on the removal efficiency of metal ions by A. niger was optimized using a design of experiment (DOE) method. Experimental results indicated that the optimal conditions for biosorption were 5.22 g/L, 89.93 mg/L and 6.01 for biomass dose, initial ion concentration and solution pH, respectively. Enhancement of metal biosorption capacity of the dried biomass by pretreatment with sodium hydroxide was observed. Maximal removal efficiencies for Cd(II), Ni(III) and Pb(II) ions of 98, 80 and 99% were achieved, respectively. The biosorption capacity of A. niger biomass obtained for Cd(II), Ni(II) and Pb(II) ions was 2.2, 1.6 and 4.7 mg/g, respectively. According to these observations the fungal biomass of A. niger is a suitable biosorbent for the removal of heavy metals from aqueous solutions. Multiple response optimization was applied to the experimental data to discover the optimal conditions for a set of responses, simultaneously, by using a desirability function.