Adsorption of Pb(II) Ions from Aqueous Solutions by Date Bead Carbon Activated with ZnCl2

This study reports on the adsorption characteristics of Pb(II) ions from aqueous solutions using ZnCl₂‐activated date (Phoenix dactylifera) bead (ADB) carbon with respect to change in adsorbent dosage, initial pH, contact time, initial concentration, and temperature of the solution. Kinetic studies of the data showed that the adsorption follows the pseudo‐second‐order kinetic model. Thermodynamic parameters, enthalpy change (ΔH° = 55.11 kJ/mol), entropy change (ΔS° = ? 0.193 kJ/mol/K), and Gibbs free energy change (ΔG°) were also calculated for the uptake of Pb(II) ions. These parameters show that adsorption on the surface of ADB was feasible, spontaneous in nature, and endothermic between temperatures of 298.2 and 318.2 K. The equilibrium data better fitted the Langmuir and Freundlich isotherm models than the D–R adsorption isotherm model for studying the adsorption behavior of Pb(II) onto the ADB carbon. It could be observed that the maximum adsorption capacity of ADB was 76.92 mg/g at 318.2 K and pH 6.5.     

Assessing flood inundation mapping through estimated discharge using GIS and HEC-RAS model

Water discharge is the main parameter in hydraulic modeling for flood hazard assessment. However, the unavailability of data on discharge and observed river morphologies resulted in erroneous calculations and irregularities in flood inundation mapping. The objectives of this study are (i) to investigate uncertainties of hydraulic parameters (width, cross-sectional depth, and channel slope) used in discharge equation and (ii) to examine the influence of estimate discharge on water extent and flood depth with different boundary conditions on interferometric synthetic aperture radar (IFSAR) and modified IFSAR DEMs. Sensitivity analysis was conducted with the Monte Carlo simulation method to generate random data combinations. Bjerklie’s equation was used to calculate discharge based on the three variables, and Manning’s n was substituted into the Hydrologic Engineering Center River Analysis System (HEC-RAS) model. TerraSAR-X was used to distinguish existing flood water bodies and normal water extent. The uncertainty of the combined variables was assessed with the likelihood measures such as F-statistic, mean absolute error, root mean square error, and Nash–Sutcliffe efficiency which compares observed and predicted inundated area as well as flood water depth simulated using the HEC-RAS model.     

Predictive environmental impact assessment of total petroleum hydrocarbons in petrochemical wastewater effluent and surface sediment

The contamination level of total petroleum hydrocarbons (TPH) in wastewater and surface sediment samples from the Petrochemical Special Economic Zone (PETZONE) and adjacent coastal area in Musa Bay (in Northwest of Persian Gulf) was examined. Concentrations of TPH in the Musa Bay sediments ranged from 16.48 to 97.15 µg/g dry weight (dw) with average value of 48.98 ± 30.36 µg/g dw. The highest concentrations were estimated in stations close to the coastline, locations affected by intensive petrochemical discharges and shipping activities. The average TPH concentration in the PETZONE wastewater effluent samples was 5.22 mg/L, with a range of 0.06–35.33 mg/L. Regarding environmental impact assessment, the concentration of TPH was lower than the wastewater effluent discharge standard at most of the monitoring stations inside PETZONE companies, with the exception of stations 15, 16 (Imam Khomeini petrochemical company 1, 2) and 17 (Razi petrochemical company). These stations were considered as moderate environmental aspects, suggesting that concentration of TPH in the wastewater effluents of these petrochemical companies could be considered as contaminants of concern in the PETZONE area.     

PITCHER PLANTS RECORDED FROM BRIS FOREST IN JAMBU BONGKOK, KUALA TRENGGANU, MALAYSIA

1INTRODUCTION NepentheswhichareknownlocallyinPeninsular Malaysiaasperiukkerabelongtoamonogenericfami lyNepenthaceae.Atpresent,atotalofninespecies(excludingnaturalhybrids)arerecordedfromPenin sularMalaysia.Ofthese,fourspeciesareendemic,whilsttheotherfivespeciesarefoundoutsidethepen insula.Thespeciescanarbitrarilybeclassifiedinto thelowlandspeciesandthehighlandspecies(Clarke,2002;Shivas,1984;Kurata,1976).Threespeciesarefoundinthehighlandhabitatscom monlyatanelevationofabove1000mforaboves…     

Effect of soil hydraulic properties model on slope stability analysis based on strength reduction method

Soil hydraulic properties models which have been proposed were derived based on the empirical fitting curve such as Brooks-Corey model (BC) and Van Genuchten model (VG), or based on soil pore radius distribution such as Lognormal model (LN). Each model has different accuracy for predicting soil moisture distribution. In the analysis of rainfall-induced slope failure, the soil hydraulic properties model was needed to describe the physical phenomena of behavior characteristic of water in unsaturated soil. As moisture content has an effect on soil strength, it is vital to select the suitable soil hydraulic properties model for predicting Factor of Safety (FOS) especially in forecasting landslide hazard. In this study, a numerical model of seepage finite element analysis using BC, VG, and LN model were used and compared in order to analyze the soil moisture distribution, water movement phenomenon, and slope stability characteristic in unsaturated soil slope based on the strength reduction method (SRM). The results showed that the variations of the parameters predicting the moisture content of soil leads to differences of FOS in some cases. The parametric study showed that for the unsaturated soil condition, BC model has the greatest FOS value than the other model, while VG model has the lowest. On the other hand, the FOS of all models have the same result for the saturated condition. Other than that, it was found that the increasing of ESP value in the surface layer has significant effect in the sub-surface layer.     

Tracer-based estimation of temporal variation of water sources: an insight from supra- and subglacial environments

ABSTRACT

The temporal variations in electrical conductivity and the stable isotopes of water, δD and δ¹⁸O, were examined at Chhota Shigri Glacier, India, to understand water sources and flow paths to discharge. Discharge is highly influenced by supraglacially derived meltwater during peak ablation, and subglacial meltwaters are more prominent at the end of the melt season. The slope of the best fit linear regression line for δD versus δ¹⁸O, for both supraglacial and runoff water, is lower than that for precipitation (snow and rain) and surface ice, indicating strong isotopic fractionation associated with the melting processes. The slope of the local meteoric water line (LMWL) is close to that of the global meteoric water line (GMWL), reflecting that the moisture source is predominantly oceanic. The d-excess variation in rainwater confirms that the southwest monsoon is the main contributor during summer while the remainder including winter is mostly influenced by westerlies.     

Detection of multiple potentially pathogenic bacteria in Matang mangrove estuaries,Malaysia

The deltaic estuarine system of the Matang Mangrove Forest Reserve of Malaysia is a site where several human settlements and brackish water aquaculture have been established. Here, we evaluated the level of fecal indicator bacteria (FIB) and the presence of potentially pathogenic bacteria in the surface water and sediments. Higher levels of FIB were detected at downstream sampling sites from the fishing village, indicating it as a possible source of anthropogenic pollution to the estuary. Enterococci levels in the estuarine sediments were higher than in the surface water, while total coliforms and E. coli in the estuarine sediments were not detected in all samples. Also, various types of potentially pathogenic bacteria, including Klebsiella pneumoniae, Serratia marcescens and Enterobacter cloacae were isolated. The results indicate that the Matang estuarine system is contaminated with various types of potential human bacterial pathogens which might pose a health risk to the public.