Ray parameters of diffracted long period P and S waves and the velocities at the base of the mantle

The derivation of P and S velocities at the core-mantle boundary (CMB) from long-period diffracted waves by the use of the simple ray-theoretical formulav _CMB=r _c /p (v _CMB=velocity at the CMB;r _c =core radius;p=ray parameter) yields apparent velocity values which differ from the true velocities. Using a dominant period of about 20 sec for calculating theoretical seismograms, we found a linear relation between the apparent velocity and the average velocity in a transition zone at the base of the mantle with fixed velocity on top.The ray parameters determined from long-period earthquake data are found to be 4.540±0.035 and 8.427±0.072 sec/deg for P_diff and S_diff, respectively. These values yield apparent velocities of 13.378±0.103 for P and 7.207±0.062 km/sec for S waves. By means of the theoretical relation between apparent and average velocity and under the assumption of linear variation of velocity with depth, one can invert the apparent velocities into true CMB velocities of 13.736±0.170 and 7.320±0.124 km/sec. These results imply positive velocity gradients at the base of the mantle and hence no significant departures from adiabaticity and homogeneity.Contribution No. 211 of the Geophysical Institute, University of Karlsruhe.     

A comprehensive study on the surface chemistry of particulate matter collected from Jeddah,Saudi Arabia

In this work, the X-ray Photoelectron Spectroscopy (XPS) technique is utilized to analyze the surface chemical composition of particulate matter (PM) which was collected from various locations at Jeddah, Saudi Arabia. The main elements found on the surface of PM are carbon (C), oxygen (O) and silicon (Si) with combined percentage of 89.4–94.9 while traces of nitrogen (N), calcium (Ca), aluminum (Al), sodium (Na), chlorine (Cl), manganese (Mg), and sulfur (S) were also present. The analyzed XPS chemical state of C, O and Si was further used to determine their bonding with other elements occurring over the surface of PM. Carbon was found in the form of carbides (18.86%), fluorides (2.39%) and carbonates (78.75%); oxygen was observed as oxides (21.05%) and hydroxides (73.42%) of other metals; and silicon was detected as silicones (12.16%), nitrides (82.53%) and silicates (5.25%). The particle size of a PM is also of great concern for health issues, and thus has been investigated by the Field Emission Scanning Electron Microscope (FESEM). The Energy Dispersive X-ray Spectroscopy (EDS) was employed for cross verification of detected elements by XPS.     

Groundwater and surface-water utilisation using a bank infiltration technique in Malaysia

Bank infiltration (BI) is one of the solutions to providing raw water for public supply in tropical countries. This study in Malaysia explores the use of BI to supplement a polluted surface-water resource with groundwater. Three major factors were investigated: (1) contribution of surface water through BI to the resulting abstraction, (2) input of local groundwater, and (3) water-quality characteristics of the resulting water supply. A geophysical method was employed to define the subsurface geology and hydrogeology, and isotope techniques were performed to identify the source of groundwater recharge and the interaction between surface water and groundwater. The physicochemical and microbiological parameters of the local surface-water bodies and groundwater were analyzed before and during water abstraction. Extracted water revealed a 5–98 % decrease in turbidity, as well as reductions in HCO₃ ^?, Cl^?, SO₄ ^2?, NO₃ ^?, Ca²⁺, Al³⁺ and As concentrations compared with those of Langat River water. In addition, amounts of E. coli, total coliform and Giardia were significantly reduced (99.9 %). However, water samples from test wells during pumping showed high concentrations of Fe²⁺ and Mn²⁺. Pumping test results indicate that the two wells used in the study were able to sustain yields.     

Evaluation of heavy metal contamination in groundwater samples from Kapas Island,Terengganu, Malaysia

An attempt has been made to delineate the hydrochemistry for a small island based on the major ions and heavy metal concentrations. In this investigation, six sampling campaigns were conducted to measure the concentrations of major ions (Ca, Mg, Na, K, HCO₃, Cl, and SO₄) and heavy metals (Zn, Cr, Pb, Mn, As, and Cu) in groundwater samples collected from seven sampling stations (boreholes) located on Kapas Island, Terengganu, Malaysia. The distribution of major ions is illustrated by a piper plot where Ca–HCO₃ is the dominant type. In addition, the concentrations of heavy metals demonstrate that Mn shows as being the highest concentrated heavy metal in the groundwater sampled in the sampling campaigns; the average Mn content in groundwater sampled was 54.05 μg/L. However, a comparison of the heavy metal (Mn, Cr, Zn, As, Pb, and Cu) concentrations in groundwater samples with the Drinking Water Quality Standard prescribed by World Health Organization reveals that none of these heavy metals exceeded the recommended threshold limits. The principal component analyses (PCA) extracted four components that control the groundwater chemistry. Components 1 and 2 from the PCA analyses extracted approximately 52.11 % of the total variance, which represent the heavy metals (As and Mn) and physical parameters (pH, redox potential, electrical conductivity, temperature, and total dissolved solids). Based on the output of the PHREEQC hydrogeochemical software, several species of heavy metals exist, in which the dominant species found are Mn²⁺, PbCO₃, Cu(OH)₂, and Zn⁺.     

Analytic network process for criteria selection in sustainable coastal land use planning

The coastal lands are very important boundaries in the natural system. But these areas are under pressure that has threatened their health by short-sighted planning policies. The management options have focused on economic production and human benefits rather than the natural systems that guaranty sustainability of them. Evaluation of sustainability in coastal lands needs some critical criteria and indicators. The purpose of this paper is to demonstrate an innovative reliable method for identification of the most important criteria and indicators using multi criteria techniques, especially the Analytic Network Process (ANP). Analytic Network Process as a new approach has potential to be applied into the field of coastal land use development. This is the first time ANP has been used for criteria selection to ensure sustainability in coastal land use planning. The integration of social, economic and environmental criteria within the planning framework in this paper has provided a holistic approach for integrated coastal land use development.     

Middle Permian cephalopods from central Peninsular Malaysia: implications for faunal migration through the southern Tethys

A Wordian (Middle Permian) cephalopod fauna consisting of four ammonoid species, Tauroceras aff. scrobiculatum (Gemmellaro), Agathiceras sp., Bamyaniceras orientale n. sp. and Pronoritidae gen. and sp. indet., and two nautiloid species, Tainoceras sp. and Orthocerida fam. indet., were recovered from the Bera South area, southern Pahang, Peninsular Malaysia. The outcrop represents the southernmost extent of the Bera Formation. Bamyaniceras and Tainoceras are recorded in Malaysia for the first time. The presence of T. aff. scrobiculatum suggests a regional correlation with an ammonoid-bearing bed of Sungai Cheroh, western Pahang, and permits global correlations with strata of northeastern Iraq, northern Oman and Sicily (Italy). A possible eastwards faunal migration through the southern Tethys is suggested.     

Permian felsic magmatism in the Neoproterozoic Nagar Parkar Igneous Complex of the Malani Igneous Suite: Evidence from zircon U–Pb age

We report Permian (ca. 272 Ma ±5.4 Ma) felsic dykes that intrude into the Neoproterozoic (ca. 750 Ma) magmatic suite of the Nagar Parkar Igneous Complex (NPIC), the western extension of the Malani Igneous Suite (MIS). The NPIC consists of Neoproterozoic basement amphibolites and granites (riebeckite–aegirine gray granites and the biotite–hornblende pink granites), all of which are intruded by several generations of mafic and felsic dykes. Granitic magmatism occurred in the Late Neoproterozoic (ca. 750 Ma) due to the subduction‐, followed by the rift‐related tectonic regime during the breakup of the Rodinia supercontinent. U–Th–Pb zircon and monazite CHIME age data of 700–800 Ma from the earlier generation porphyritic felsic dykes suggest the dyke intrusion was coeval or soon after the emplacement of the host granites. Our findings of Permian age orthophyric felsic dykes provide new insights for the prevalence of active tectonics in the MIS during late Paleozoic. Textural features and geochemistry also make the orthophyric dykes distinct from the early‐formed porphyritic dykes and the host granites. Our newly obtained age data combined with geochemistry, suggest the existence of magmatism along the western margin of India (peri‐Gondwana margin) during Permian. Like elsewhere in the region, the Permian magmatism in the NPIC could be associated with the rifting of the Cimmerian micro‐continents from the Gondwana.     

Regional analysis of annual maximum rainfall using TL-moments method

Information related to distributions of rainfall amounts are of great importance for designs of water-related structures. One of the concerns of hydrologists and engineers is the probability distribution for modeling of regional data. In this study, a novel approach to regional frequency analysis using L-moments is revisited. Subsequently, an alternative regional frequency analysis using the TL-moments method is employed. The results from both methods were then compared. The analysis was based on daily annual maximum rainfall data from 40 stations in Selangor Malaysia. TL-moments for the generalized extreme value (GEV) and generalized logistic (GLO) distributions were derived and used to develop the regional frequency analysis procedure. TL-moment ratio diagram and Z-test were employed in determining the best-fit distribution. Comparison between the two approaches showed that the L-moments and TL-moments produced equivalent results. GLO and GEV distributions were identified as the most suitable distributions for representing the statistical properties of extreme rainfall in Selangor. Monte Carlo simulation was used for performance evaluation, and it showed that the method of TL-moments was more efficient for lower quantile estimation compared with the L-moments.     

Temperature variability caused by internal tides in the coastal waters of east coast of Peninsular Malaysia

The effects of tidal currents (i.e., barotropic and internal tides) are important in the biogeochemistry of a coastal shelf sea. The high-frequency of currents and near-bottom temperatures collected in three consecutive southwest monsoon seasons (May, June, July and August of 2013 until 2015) is presented to reveal the role of the tidal currents to the temperature variability in the coastal shelf sea of the east coast of Peninsular Malaysia (ECPM), south of the South China Sea (SCS). The results of a spectral density and harmonic analysis demonstrate that the near-bottom temperature variability and the tidal currents are influenced by diurnal (O₁ and K₁) and semidiurnal (M₂) tidal currents. The spectral density of residual currents (detided data) at 5, 10 and 16 m depth also shows significant peaks at the diurnal tidal frequency (K₁) and small peaks at the semidiurnal tidal frequency (M₂) indicating the existence of internal tides. The result of the horizontal kinetic energy (HKE) shows a strong intermittent energy of internal tides in the ECPM with the strongest energy is found at 16 m depth during a sporadic cooling event in June and July. A high horizontal cross-shore heat flux (16 m) also indicates strong intrusions of cooler water into the ECPM in June and July. During the short duration of cold pulse water observed in June and July, a cross-wavelet analysis also reveals the strong relationship between the near-bottom temperatures and the internal tidal currents at the diurnal tidal frequency. The intrusion of this cooler water is probably related to the monsoon-induced upwelling in June. It is loosely interpreted that the interaction between the strong barotropic tides and the steep slope in the central basin of the SCS under the stratified condition in southwest monsoon has generated these internal tides. The dissipation of internal tides from the slope area probably has driven the cold-upwelled water into the ECPM coastal shelf sea when the upwelling intensity is the highest in June and July.