Thallium: A potential guide to mineral deposits

Several recent studies have suggested that rocks associated with mineral deposits of hydrothermal origin are generally enriched in Rb. TI is similar in its geochemical characteristics to Rb, but its use as a potential guide to ore deposits has not been suggested. Although TI has the same size and valency as Rb, it is concentrated more in residual melts than Rb and K because the TI-O bond is more covalent and weaker than either the Rb-O or K-O bonds.A new method which is rapid and precise has been developed by one of the authors for the determination of TI in geological materials at the ppb level. About 350 rocks from 4 mineralized areas in northeastern Washington and central Montana were analyzed for TI by this method. Most of these rocks were also analyzed for SiO₂, A1₂O₃,Fe₂O₃, MgO, CaO, Na₂O, K₂O, TiO₂, P₂O₅, MnO, Ag, As, Au, Ba, Co, Cu, F, Li, Mo, Ni, Pb, Sr, Sb, Sn, Sr, Te, U, W, and Zn. The ore deposits of the areas studied include the gold-silver deposits of the Republic district, the uranium deposit of the Midnite mine, the coppermolybdenum deposit of Mount Tolman, and the gold deposits of the North Moccasin mining district.In all the mineralized areas there is significantly more TI in hydrothermally altered rocks than in unaltered rocks. The very high abundance of TI in the altered rocks of the North Moccasin gold district, and the significant positive correlations of TI and K and TI and Rb in the mineralized rocks of the other three areas suggest that TI was concentrated in hydrothermal fluids. In altered rocks the average K/Rb and K/TI ratios are lower, and the Rb/Sr and TI/Sr ratios are higher.Often the abundance of TI and the K/TI and TI/Sr ratios are more useful in delineating mineralized areas than the abundance of Rb and the K/Rb and Rb/Sr ratios. The ternary relationships between TI and several other elements, especially Rb, K, Ba, and Sr, show mineralized rocks to fall near the TI apices or near the TI-Rb or TI-K boundaries.     

Full‐scale dynamic response of an RC building under weak seismic motions using earthquake recordings,ambient vibrations and modelling

In countries with a moderate seismic hazard, the classical methods developed for strong motion prone countries to estimate the seismic behaviour and subsequent vulnerability of existing buildings are often inadequate and not financially realistic. The main goals of this paper are to show how the modal analysis can contribute to the understanding of the seismic building response and the good relevancy of a modal model based on ambient vibrations for estimating the structural deformation under weak earthquakes. We describe the application of an enhanced modal analysis technique (frequency domain decomposition) to process ambient vibration recordings taken at the Grenoble City Hall building (France). The frequencies of ambient vibrations are compared with those of weak earthquakes recorded by the French permanent accelerometric network (RAP) that was installed to monitor the building. The frequency variations of the building under weak earthquakes are shown to be less (∼2%) and therefore ambient vibration frequencies are relevant over the elastic domain of the building. The modal parameters extracted from ambient vibrations are then used to determine the 1D lumped‐mass model in order to reproduce the inter‐storey drift under weak earthquakes and to fix a 3D numerical model that could be used for strong earthquakes. The correlation coefficients between data and synthetic motion are close to 80 and 90% in horizontal directions, for the 1D and 3D modelling, respectively. Copyright © 2009 John Wiley & Sons, Ltd.     

Mechanical behaviour and failure of cohesive granular materials

We investigate the stress–strain behaviour and failure of a cohesive granular material both by experiments and numerical simulations. The material is an assembly of aluminium rods glued together by means of an epoxy resin. The behaviour of cohesive bonds (force–displacement relationship, failure conditions) is characterized by performing simple loading tests (tension/compression, shear…) on a couple of rods. Then, this local behaviour is introduced in a numerical code based on a discrete element method in order to perform numerical compression tests on large samples. The validation of this approach was the main goal of the present investigation that is essentially achieved by a direct comparison between the numerical results and similar experimental tests. As a basic application, we derive the macroscopic cohesion and friction characteristics of random cohesive materials by systematic numerical simulations in a biaxial geometry. Copyright © 2004 John Wiley & Sons, Ltd.     

Spectral classification criteria for some early type stars in the UV region/atl>

The aim of this paper is to get new critertia for spectral classification of some early type stars which depend on the flux in the UV region λ λ 1500–2500 by carrying out spectrophotometric analysis of observational ultraviolet data of stars obtained by the S2/68 Ultraviolet Sky Survey Telescope (UVSST) aboard the European Space Research Organization (ESRO) Satellite TD1. We have developed these new criteria based on the Intrinsic Ultraviolet Colour Index (IUI), and the Intrinsic Flux Ratio (IFR). Using these quantities we are going to represent the results of spectral classification of 323 early type stars mainly from spectral type B and A. The results of calculations of the Intrinsic Flux Ratios for the stars under investigation together with their Colour Temperatures (Tc) are given. Comparison between our suggested two new criteria with the MK classification system and Cucchairo (1980) classification system was carried out. This revised version was published online in July 2006 with corrections to the Cover Date.     

Dynamic Properties of Soft Clay and Loose Sand from Seismic Centrifuge Tests

Appropriate evaluation of shear modulus and damping characteristics of soils subjected to dynamic loading is key to accurate seismic response analysis and soil modeling programs. Dynamic centrifuge experiments were conducted at C-CORE (Memorial University of Newfoundland) centrifuge center to investigate the dynamic properties and seismic response of soft clay and dry loose sand strata. Soft clay with shear strength of about 30 kPa and well graded silica sand at about 35% relative density were employed in a rigid container to simulate local site effects. Several earthquake-like shaking events were applied to the model to evaluate variation of shear modulus and damping ratio with shear strain amplitude and confining pressure, and to assess their effects on site response. The estimated modulus reduction and damping ratio were compared to the predictions of empirical formulae and resonant column tests for both soft clay and loose sand. The evaluated shear modulus and damping ratio were found to be dependent on confining pressure in both soil types. Modulus variation in both soils agreed well with the empirical curves and resonant column test results. However, the sand modulus values were slightly higher than the empirical relations and resonant column tests. This discrepancy is attributed to higher stress and densification of sand during large amplitude shaking applied to the model. The damping ratio at shear strains lower than 0.5% was in reasonable agreement with the empirical curves and the resonant column tests in both clay and sand models, but was generally higher at shear strain larger than 0.5%.     

Study of the interaction between U(VI) and the anoxic corrosion products of carbon steel

The objective of this study was to investigate the removal mechanism of U(VI) from groundwater by magnetite as the main product of anoxic steel corrosion. For this purpose, a systematic sequence of batch experiments was conducted to focus the active role of magnetite in the reduction of U under different conditions. Results indicated that under anoxic conditions U(VI) was sorbed at the magnetite surface, whereas under reducing conditions at different H₂(g) pressures, U was present in tetravalent form as amorphous UO₂.     

Geochemical characteristics and spectrometric prospecting in the muscovite-bearing pegmatites and granites,southeastern Aswan,Egypt

Rare metal mineralization of Sn, Nb-Ta and W is encountered in the Gebel Dihmit area （GDA）, southeastern Aswan, Egypt. The mineralization is related to muscovite granites and their pegmatite derivatives. The pegmatites are divided into three types according to their main mineral assemblages： K-feldspar-muscovite-tourmaline, K-feldspar-albite-muscovite and albite-K-feldspar-lepidolite veins. Petrogenetic studies indicate that Sn and Nb-Ta mineralization extends from the late-magmatic stage to the pegmatite and hydrothermal stages of the （GDA） suite. The albite-K-feldspar-lepidolite granite is composed dominantly of albite, lepidolote, and quartz, with topaz, K-feldspar and amblygonite. The accessory minerals are zircon, monazite, pollucite, columbite-tantalite, microlite and Ta-rich cassiterite. Phenocrysts of quartz, topaz and K-feldspar contain abundant inclusions of albite laths and occasional lepidolite crystals along growth zones （snowball texture）, indicating simultaneous crystallization from a subsolvus, residual magma. The origin of the pegmatites is attributed to extreme differentiation by fractional crystallization of a granitic magma. The economic potential for rare metals was evaluated in the geochemical discrimination diagrams. Accordingly, some of the pegmatites are not only highly differentiated in terms of alkalis, but also the promising targets for small-scale Ta and, to a less extent, Sn. The pegmatites also provide the first example of Fe-Mn and Nb-Ta fractionation in successive generations of granites to cassiterite-bearing pegmatites, which perfectly ex- hibit similar fractionation trends established for primary columbite-tantalite in the corresponding categories of pegmatites. Uranium and Th of magmatic origin are indicated by the presence of thorite and allanite, whereas evidence of hydrothermal mineralization is the alteration of rock- foring minerals such as feldspar and the formation of secondary minerals such as uranophane..     

Utilization of low quality water of mountain reservoirs: a case study from Al Jabal Al Akhdar,Oman

Al Jabal al Akhdar (Green Mountain) in arid northern Oman has freshwater resources that had supported small communities for hundreds of years. Jabal Akhdar receives more rainfall (300-400 mm) when compared to the desert plains. In the last few years, this region had undergone enormous changes due to rapid development. The resident and transient populations have increased and their activities exert severe stress on the water resources. There are 24 retention reservoirs in the area, but most are eutrophic and the nutrient loading is due to input of animal fecal matter via surface run-off. As expected, these waters contaminated with coliform bacteria and some have pathogenic Escherichia coli. Drinking water needs of all the villages met by groundwater extraction. Because of poor quality, the surface water in the reservoirs is under-utilized. A low-cost low-maintenance treatment system designed, constructed and operated in one village to clean the reservoir water for non-drinking human use. The treatment unit improved the water quality parameters. A survey among the adult male population of the village showed their eagerness to adopt this system and use the treated reservoir water for uses other than agriculture. Establishment of these treatment units in other villages should reduce the pressures on groundwater extraction.     

Integration of LiDAR data for the assessment of activity in diachronic landslides: a case study in the Betic Cordillera (Spain)

In the procedures to minimize diachronic landslides, data on their temporal evolution and destructive capacities are necessary. For that purpose, remote-detection techniques proved to be highly useful for quantifying the ongoing change in the relief, as well as in comparisons between digital terrain models achieved by Light Detection and Ranging. The methodology presented in this paper includes the supervised merging and comparison of sequential scans, acquired within nearly annual intervals from an irregular terrain, which improves the quality of the results highlighting ground changes. This approach is based on the processing of digital terrain models from point clouds acquired by Terrestrial Laser Scanning to quantify and interpret the landslide displacements. In parallel, it is supported by Global Navigation Satellite Systems, the use of artificial targets and a refined data processing to minimize the uncertainty and improve the precision of the results. This is applied to a large translational slide affecting phyllite rocks in a IV-V degree of weathering settled on the southern slope of Sierra Nevada (south-eastern Spain). During the monitoring period (2008–2010), the slide remained inactive until 2009, followed by a reactivation with displacements in the range ?1.80 to 1.20 m along the period 2009–2010, where negative values are downwards from the reference model (2009). The accumulated relative standard deviation between data sets was on the order of 7.5 cm, whereas the threshold to determine a terrain displacement (also avoiding changes due to erosion-accumulation processes) was of 10 cm. When applying this methodology to Airborne Laser Scanning datasets for the years 2008 and 2010, covering zones hidden to the line of sight of the terrestrial technique, a reactivation with similar deformation pattern was found useful to validate the findings, although the detail of changes and quantitative results did not match exactly due to the different accuracy and resolution of both techniques. The reactivation of the slide coincided with a period of intense rains, pointing to this as the triggering factor, with a precipitation threshold of roughly 1000 mm in a period of 4 months, only reached on one occasion throughout in the historical record.