Diagenetic evolution vis-a-vis reservoir characteristics of Dhosa sandstones,Ler dome,Kachchh, western India

The detrital mineralogy as well as diagenetic characters of the Dhosa Sandstone Member of Chari Formation exposed at the Lerdome, south of Bhuj was studied. In order to assess the potential of the Dhosa Sandstone as a reservoir, it is substantial to understand the diagenetic processes that are controlled largely by post-depositional cementation and compaction in addition to framework composition and original depositional textures. The petrologic analysis of 33 thin sections was carried out to discern primary composition and diagenetic features including primary and secondary porosity patterns. Monocrystalline quartz dominates the detrital mineralogy followed by polycrystalline quartz. Among the polycrystalline variety recrystallized metamorphic quartz surpasses stretched metamorphic quartz in terms of abundance. Feldspars comprise microcline and plagioclase where the former is dominant over the latter. Orthoclase too comprises a very small percentage. Mica, chert, rock fragments, and heavies form the remaining detrital constituent in descending order of their constituent percentage. The diagenetic precipitates are mainly carbonate (8.30%) and iron (7.80%) followed by clay (0.66%) and silica (0.88%) that are minor constituent of the total cementing material. The main paragenetic events identified are early cementation, mechanical compaction, late cementation, dissolution, and authigenesis of clays. The overall reservoir quality seems to be controlled by compaction and authigenic carbonate cementation. The minus cement porosity average 29.4%. The porosity loss due to compaction is 21.92% and by cementation is 29.71%. The loss of original porosity was due to early cementation followed by moderate mechanical compaction during shallow burial. Preservation of available miniscule primary porosity was ascribed to dissolution of carbonates and quartz overgrowth which resisted chemical compaction during deep burial. The studied sandstones may have low reservoir quality owing to existing porosity of less than 9%. More carbonate dissolution and its transformation in dolomite in sub-surface condition and macro-fracture porosity may result in enhanced secondary porosity and good diagenetic traps.     

Microbiostratigraphy of Kazhdumi Formation in the Northwestern Shiraz (Southwest Iran) on the Basis of Foraminifera and Calcareous Algae

The middle Cretaceous Kazhdumi Formation,with a thickness of 222 m,belongs to the Bangestan Group and occurs in the Zagros folded zone in southwest Iran.The lower boundary with the Dariyan Formation is disconformable,which is recognized by iron oxides and glauconite.The recognized microfossils are Valvulammina sp.,Scandonea sp.,Daxia cenomana,Choffatela sp., Pseudolituonella reicheli and calcareous algae-Lithocodium aggregation(which belongs to the Sarvak Formation),representing the beginning of Cenomani...     

Geochemical Aspects of Hypogene Hydrothermal Alteration Zones in the Chol‐qeshlaghi Area,NW Iran: Constrains on REEs

Chol-qeshlaghi altered area lies in the northwestern part of the post-collisional Urumieh-Dokhtar magmatic arc, NW Iran. Pervasive silicic, argillic, phyllic and propylitic altered zones appears to be intimately affiliated to the fluids derivative of upper Oligocene Khankandi granodiorite. This paper is dedicated to the identification of geochemical characteristics of hydrothermal alterations, focusing on the determination of the mass gains and losses of REEs, to gain significant insights regard...     

Composition-related microstructures in zinc-bearing carbonate assemblages from Broken Hill,New South Wales

Summary Analytical transmission electron microscopy has been used to investigate two zincian dolomites occurring as overgrowths on calcite from the oxidized zone of the ore bodies at Broken Hill, New South Wales. Particular attention has been focussed on the nature of the microstructures, and any correlations between microstructure and local composition, especially zinc content. The possible occurrence of tiny amounts of the zinc dolomite, minrecordite, has also been explored.The most notable features in the zincian dolomite are fine-scale distributions of ribbonlike calcitic second phase, growth bands, and modulated microstructures (strong modulations in diffraction contrast). Their occurrence is correlated with calcium in excess of stoichiometric requirements, but is not directly influenced by zinc content. The associated calcites are low in zinc, but they also exhibit carbonate second phase, which is thought to be dolomitic although giving no detectable order (b-type) reflections. Long-exposure electron diffraction patterns, however, revealed the presence of diffuse c-type superstructure reflections, which are thought to arise from smaller volumes in which Ca and Mg cations are ordered, for which a model is proposed.

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Zusammensetzungsabhängige Mikrogefüge in Zn-haltigen Karbonat-Vergesellschaftungen von Broken Hill, New South Wales

Zusammenfassung Analytische Transmissionselektronenmikroskopie wurde benutzt um zwei Zn-haltige Dolomite zu untersuchen, die als Überzüge von Calcit aus der Oxidationszone der Erzkörper von Broken Hill, New South Wales, auftraten. Besondere Aufmerksamkeit wurde der Art der Mikrogefüge und möglichen Korrelationen zwischen Mikrogefüge und der lokalen Zusammensetzung, vor allem dem Zn-Gehalt, gewidmet. Dem möglichen Auftreten von geringen Mengen des Zn-Dolomit, Minrecordit, wurde ebenfalls nachgegangen.Die bemerkenswertesten Erscheinungen im Zn-haltigen Dolomit sind feine bandartige Verteilung einer calcitischen Phase, Wachstumsbänder und modulierte Strukturen (starke Modulationen im Beugungskontrast sichtbar). Ihr Auftreten ist mit über das stöchiometrische Verhältnis hinaus vorhandenem Ca korreliert; es ist aber vom Zn-Gehalt nicht direkt beeinflußt. Die mitvergesellschafteten Calcite haben einen niedrigen Zn-Gehalt, zeigen aber eine weitere Karbonatphase. Diese wird für dolomitsch gehalten, obwohl keine entsprechenden Ordnungsreflexe (b-Reflexè) nachweisbar waren. Sehr lange belichtete Elektronenbeugungs-Aufnahmen zeigen jedoch diffuse c-Typ-Über-struktur-Reflexe. Diese sind wahrscheinlich auf kleine Bereiche beschränkt, in dener die Ca und Mg Kationen geordnet sind, wofür ein Modell vorgeschlagen wird.

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With 10 Figures     

Ghaleh-khargushi rhyodacite and Gorid andesite from Iran: characterization,uses, and durability

Durability of building stones is an important issue in sustainable development. Crystallization of soluble salts is recognized as one of the most destructive weathering agents of building stones. For this reason, durability of Ghaleh-khargushi rhyodacite and Gorid andesite from Iran was investigated against sodium sulfate crystallization aging test. Petrographic and physico-mechanical properties and pore size distribution of these stones were examined before and after the aging test. The characteristics of the microcracks were quantified with fluorescence-impregnated thin sections. Durability and physico-mechanical characteristics of Ghaleh-khargushi rhyodacite are mainly influenced by preferentially oriented preexisting microcracks. Stress induced by salt crystallization led to the widening of preexisting microcracks in Ghaleh-khargushi rhyodacite, as confirmed by the pore size distributions before and after the aging test. The preexisting microcracks of Gorid andesite were attributed to the mechanical stress induced by contraction of lava during cooling. The number of transcrystalline microcracks was significantly increased after the aging test. The degree of plagioclase microcracking was proportional to its size. Durability of the studied stones depends on initial physico-mechanical properties, pore size distribution, and orientation of microcracks. Initial effective porosity is found to be a good indicator of the stones’ durability. Salt crystallization resulted in an increase in the effective porosity with a parallel decrease in the wave velocities. Surface microroughness parameters increased with the development of salt crystallization-induced microcracking. Gorid andesite showed higher quality and durability than Ghaleh-khargushi rhyodacite.     

Uncertainty assessment of the multilayer perceptron (MLP) neural network model with implementation of the novel hybrid MLP-FFA method for prediction of biochemical oxygen demand and dissolved oxygen: a case study of Langat River

Accurate prediction of the chemical constituents in major river systems is a necessary task for water quality management, aquatic life well-being and the overall healthcare planning of river systems. In this study, the capability of a newly proposed hybrid forecasting model based on the firefly algorithm (FFA) as a metaheuristic optimizer, integrated with the multilayer perceptron (MLP-FFA), is investigated for the prediction of monthly water quality in Langat River basin, Malaysia. The predictive ability of the MLP-FFA model is assessed against the MLP-based model. To validate the proposed MLP-FFA model, monthly water quality data over a 10-year duration (2001–2010) for two different hydrological stations (1L04 and 1L05) provided by the Irrigation and Drainage Ministry of Malaysia are used to predict the biochemical oxygen demand (BOD) and dissolved oxygen (DO). The input variables are the chemical oxygen demand (COD), total phosphate (PO₄), total solids, potassium (K), sodium (Na), chloride (Cl), electrical conductivity (EC), pH and ammonia nitrogen (NH₄-N). The proposed hybrid model is then evaluated in accordance with statistical metrics such as the correlation coefficient (r), root-mean-square error, % root-mean-square error and Willmott’s index of agreement. Analysis of the results shows that MLP-FFA outperforms the equivalent MLP model. Also, in this research, the uncertainty of a MLP neural network model is analyzed in relation to the predictive ability of the MLP model. To assess the uncertainties within the MLP model, the percentage of observed data bracketed by 95 percent predicted uncertainties (95PPU) and the band width of 95 percent confidence intervals (d-factors) are selected. The effect of input variables on BOD and DO prediction is also investigated through sensitivity analysis. The obtained values bracketed by 95PPU show about 77.7%, 72.2% of data for BOD and 72.2%, 91.6% of data for DO related to the 1L04 and 1L05 stations, respectively. The d-factors have a value of 1.648, 2.269 for BOD and 1.892, 3.480 for DO related to the 1L04 and 1L05 stations, respectively. Based on the values in both stations for the 95PPU and d-factor, it is concluded that the neural network model has an acceptably low degree of uncertainty applied for BOD and DO simulations. The findings of this study can have important implications for error assessment in artificial intelligence-based predictive models applied for water resources management and the assessment of the overall health in major river systems.     

Hydraulic Conductivity of Fly Ash-Amended Mine Tailings

The objective of this study was to evaluate the effect of fly ash addition on hydraulic conductivity (k) of mine tailings. Mine tailings used in this study were categorized as synthetic tailings and natural tailings; two synthetic tailings were developed via blending commercially-available soils and natural tailings were collected from a garnet mine located in the U.S. Two fly ashes were used that had sufficient calcium oxide (CaO) content (17 and 18.9 %) to generate pozzolanic activity. Hydraulic conductivity was measured on pure tailings and fly ash-amended tailings in flexible-wall permeameters. Fly ash was added to mine tailings to constitute 10 % dry mass of the mixture, and specimens were cured for 7 and 28 days. The influence of fly ash-amendment on k of mine tailings was attributed to (1) molding water content and (2) plasticity of the mine tailings. Tailings that classified as low-plasticity silts with clay contents less than 15 % exhibited a decrease in k when amended with fly ash and prepared wet of optimum water content (w _opt ). Tailings that classified as low-plasticity clay exhibited a one-order magnitude increase in k with addition of fly ash for materials prepared dry or near w _opt . The decrease in k for silty tailings was attributed to formation of cementitious bonds that obstructed flow paths, whereas the increase in k for clayey tailings was attributed to agglomeration of clay particles and an overall increase in average pore size. The results also indicated that the effect of curing time on k is more pronounced during the early stages of curing (≤7 days), as there was negligible difference between k for 7 and 28-days cured specimens.     

A probabilistic tsunami hazard assessment for the Makran subduction zone at the northwestern Indian Ocean

A probabilistic tsunami hazard assessment is performed for the Makran subduction zone (MSZ) at the northwestern Indian Ocean employing a combination of probability evaluation of offshore earthquake occurrence and numerical modeling of resulting tsunamis. In our method, we extend the Kijko and Sellevoll’s (1992) probabilistic analysis from earthquakes to tsunamis. The results suggest that the southern coasts of Iran and Pakistan, as well as Muscat, Oman are the most vulnerable areas among those studied. The probability of having tsunami waves exceeding 5 m over a 50-year period in these coasts is estimated as 17.5%. For moderate tsunamis, this probability is estimated as high as 45%. We recommend the application of this method as a fresh approach for doing probabilistic hazard assessment for tsunamis. Finally, we emphasize that given the lack of sufficient information on the mechanism of large earthquake generation in the MSZ, and inadequate data on Makran’s paleo and historical earthquakes, this study can be regarded as the first generation of PTHA for this region and more studies should be done in the future.