P–T evolution of meta-peridotite in the Penjwin ophiolite, northeastern Iraq

The Penjwin meta-peridotite rock represents one of the five main metamorphosed ultramafic bodies in Kurdistan region, Northwest Zagros Thrust Zone. It underwent at least two successively low-retrograde metamorphic events with one progressive one which all modified the original mineralogy and texture of primary dunite and harzburgite. The primary upper mantle mineral assemblage olivine?+?orthopyroxene?+?chromian spinel is replaced by olivine?+?tremolite–actiolite?+?anthopylite?+?talc?+?ferichromite?+?Cr-chlorite assemblage of amphibolite facies. The further retrograde metamorphic amphibolite facies assemblage is replaced by lizardite–chrysotile?+?Cr-chlorite?+?syn-serpentinization Cr-magnetite of lower greenschist facies. Later at the main Zagros thrust fault, low greenschist facies underwent progressive metamorphism due to the local effect of shear stress as a result of the exhumation and obduction of Penjwin ophiolite suite over Merga Red bed series during Tertiary. Lizardite–chrysotile transformed to antigorite and producing antigorite?+?carbonate?+?syn-serpentinization Cr-magnetite?+?Cr-chlorite assemblage of upper greenschist facies. Chromian spinel is concentrically zoned as a result of multi-stages retrogressive metamorphic events, in which the Cr # (Cr/(Cr?+?Al)) increases from core to rim (0.5 to 1). Three zones can be identified from core to rim: The core is primary Al-rich and mantled by ferrichromite of amphibolite facies. The most outer zone of chromian spinel grains is represented by syn-serpentinization Cr-magnetite of greenschist facies.     

Scaling property of regional floods in New South Wales Australia

Regional flood frequency analysis (RFFA) is often used in hydrology to estimate flood quantiles when there is a limitation of at-site recorded flood data. One of the commonly used RFFA methods is the index flood method, which is based on the assumptions that a region satisfies criterion of simple scaling and it can be treated homogeneous. Another RFFA method is quantile regression technique where prediction equations are developed for flood quantiles of interest as function of catchment characteristics. In this paper, the scaling property of regional floods in New South Wales (NSW) State in Australia is investigated. The results indicate that the annual maximum floods in NSW satisfy a simple scaling assumption. The application of a heterogeneity test, however, reveals that NSW flood data set does not satisfy the criteria for a homogeneous region. Finally, a set of prediction equations are developed for NSW using quantile regression technique; an independent test shows that these equations can provide reasonably accurate design flood estimates with a median relative error of about 27%.     

Isolation and characterization of alkane degrading bacteria from petroleum reservoir waste water in Iran (Kerman and Tehran provenances)

Petroleum products spill and leakage have become two major environmental challenges in Iran. Sampling was performed in the petroleum reservoir waste water of Tehran and Kerman Provinces of Iran. Alkane degrading bacteria were isolated by enrichment in a Bushnel–Hass medium, with hexadecane as sole source of carbon and energy. The isolated strains were identified by amplification of 16S rDNA gene and sequencing. Specific primers were used for identification of alkane hydroxylase gene. Fifteen alkane degrading bacteria were isolated and 8 strains were selected as powerful degradative bacteria. These 8 strains relate to Rhodococcus jostii, Stenotrophomonas maltophilia, Achromobacter piechaudii, Tsukamurella tyrosinosolvens, Pseudomonas fluorescens, Rhodococcus erythropolis, Stenotrophomonas maltophilia, Pseudomonas aeruginosa genera. The optimum concentration of hexadecane that allowed high growth was 2.5%. Gas chromatography results show that all strains can degrade approximately half of hexadecane in one week of incubation. All of the strains have alkane hydroxylase gene which are important for biodegradation. As a result, this study indicates that there is a high diversity of degradative bacteria in petroleum reservoir waste water in Iran.     

Shallow and deep aquifer hydrochemistry and chemical variability of water quality at Shariatpur district, Bangladesh

Water quality and hydrochemistry of Shariatpur district were evaluated in terms of hydrochemical composition and some important physico-chemical parameters. The groundwater of the study area is good for drinking, domestic as well as for irrigation purposes. Among the major ions, shallow tube well waters give higher concentration of Ca²⁺ which ranges from 24 to 260 mg/L. The deep tubewell waters show higher concentration of Na⁺ which varies from 74 to 582 mg/L during dry season. Among the trace elements most of the shallow aquifer samples show higher concentration of Fe²⁺, Mn²⁺ and As. Concentration of Fe²⁺ varies from 0.655 to 18.8 mg/L, and Mn²⁺ from trace to 0.868 mg/L during dry period. Hydrochemical analyses reveal significant seasonal variation in water quality of shallow aquifer. Both the shallow aquifer and the surface water of the study area are predominantly of Ca–Mg–HCO₃ type, while the deep aquifer water is mainly of Na–K–Cl–SO₄ type with slight inclination to Ca–Mg–HCO₃ type. The study area is suitable for groundwater development if comprehensive and holistic approaches towards water resource management are taken into consideration.     

Application of diffracted wave analysis to time‐lapse seismic data for CO2 leakage detection

Time‐lapse seismic analysis is utilized in CO₂ geosequestration to verify the CO₂ containment within a reservoir. A major risk associated with geosequestration is a possible leakage of CO₂ from the storage formation into overlaying formations. To mitigate this risk, the deployment of carbon capture and storage projects requires fast and reliable detection of relatively small volumes of CO₂ outside the storage formation. To do this, it is necessary to predict typical seepage scenarios and improve subsurface seepage detection methods. In this work we present a technique for CO₂ monitoring based on the detection of diffracted waves in time‐lapse seismic data. In the case of CO₂ seepage, the migrating plume might form small secondary accumulations that would produce diffracted, rather than reflected waves. From time‐lapse data analysis, we are able to separate the diffracted waves from the predominant reflections in order to image the small CO₂ plumes. To explore possibilities to detect relatively small amounts of CO₂, we performed synthetic time‐lapse seismic modelling based on the Cooperative Research Centre for Greenhouse Gas Technologies (CO2CRC) Otway project data. The detection method is based on defining the CO₂ location by measuring the coherency of the signal along diffraction offset‐traveltime curves. The technique is applied to a time‐lapse stacked section using a stacking velocity to construct offset‐traveltime curves. Given the amount of noise found in the surface seismic data, the predicted minimum detectable amount of CO₂ is 1000–2000 tonnes. This method was also applied to real data obtained from a time‐lapse seismic physical model. The use of diffractions rather than reflections for monitoring small amounts of CO₂ can enhance the capability of subsurface monitoring in CO₂ geosequestration projects.     

Surficial deposits on salt diapirs (Zagros Mountains and Persian Gulf Platform, Iran): Characterization, evolution, erosion and the influence on landscape morphology

The surfaces of salt diapirs in the Zagros Mountains are mostly covered by surficial deposits, which significantly affect erosion rates, salt karst evolution, land use and the density of the vegetation cover. Eleven salt diapirs were selected for the study of surficial deposits in order to cover variability in the geology, morphology and climate in a majority of the diapirs in the Zagros Mountains and Persian Gulf Platform. The chemical and mineralogical compositions of 80 selected samples were studied mainly by X-ray powder diffraction and X-ray fluorescence. Changes in salinity along selected vertical profiles were studied together with the halite and gypsum distribution. The subaerial residuum formed from minerals and rock detritus released from the dissolved rock salt is by far the most abundant material on the diapirs. Fluvial sediments derived from this type of residuum are the second most common deposits found, while submarine residuum and marine sediments have only local importance. The mineralogical/chemical composition of surficial deposits varies amongst the three end members: evaporite minerals (gypsum/anhydrite and minor halite), carbonates (dolomite and calcite) and silicates-oxides (mainly quartz, phyllosilicates, and hematite). Based on infiltration tests on different types of surficial deposits, most of the rainwater will infiltrate, while overland flow predominates on rock salt exposures. Recharge concentration and thick accumulations of fine sediment support relatively rich vegetation cover in some places and even enable local agricultural activity. The source material, diapir relief, climatic conditions and vegetation cover were found to be the main factors affecting the development and erosion of surficial deposits. A difference was found in residuum type and landscape morphology between the relatively humid NW part of the studied area and the arid Persian Gulf coast: In the NW, the medium and thick residuum seems to be stable under current climatic conditions. Large sinkholes and blind valleys with sinking streams are common. On other diapirs, the original thick residuum is undergoing erosion and the new morphology is currently represented by salt exposures and badland-like landscapes or by fields of small sinkholes developed in the thin residuum. Models for evolution of the subaerial residuum and the diapir landscape/morphology are described in this paper. While the thick residuum with vegetation has very low erosion rates, the salt exposures and thin residuum are eroded rapidly. During wet periods (e.g. early Holocene), the diapirs rose and salt glaciers expanded as the influx of salt mass was much faster compared to erosion. After the onset of an arid climate, c. 6 ka BP, the rising of the some diapir surfaces decreased or even reversed due to acceleration of erosion thanks to vegetation degradation and changes in the residuum type and thickness.     

Regional and urban population size weights in Saudi Arabia, 1962–1974

The aim of this paper 3s to study the development of population weights for regions and urban centres in Saudi Arabia through the period 1962–1974. In order to achieve this aim some non-parametric statistical rules have been used such as rank-size rule and the four-city index. The results show non-balanced distribution of population on both regional and urban scales. The concentration of people in urban centres is more pronounced than the concentration in regions. This is due to internal and external movement of population towards largesized urban centres. The paper recommends that the official authorities should give more consideration to economic and service development in rural and urban areas that are retreating in ranking and decreasing in population.     

Surfactant Enhance DLLME/FO‐LADS: Assay of Malachite Green Level in Aquatic Environment of Trout Fish

Malachite green (MG), a traditional agent used in aquaculture although is not approved; its low cost and high efficacy make illicit use likely. We developed a small‐scale, simple, and sensitive dispersive liquid–liquid microextraction procedure for the assay of trace amounts of MG in aquatic environment of Trout fish. Fiber optic‐linear array detection spectrophotometry with charge‐coupled device detector benefiting from a microcell was used for this purpose. The method is based on enhancement effect of an anionic surfactant on the extraction of MG in to very fine multidroplets of microextraction solvent which made assisted by disperser solvent. Under the optimum conditions, the enrichment factor 77.5 was obtained from a 5‐mL water sample. The calibration graph was linear up to 5 × 10^?7 mol L^?1 with detection limit of 1 × 10^?8 mol L^?1. The relative standard deviation for seven replicate measurements of 4 × 10^?7 and 5 × 10^?8 mol L^?1 of MG were 3.3 and 4.5%, respectively.     

Revised age of proximal deposits in the Zagros foreland basin and implications for Cenozoic evolution of the High Zagros

The regionally extensive, coarse-grained Bakhtiyari Formation represents the youngest synorogenic fill in the Zagros foreland basin of Iran. The Bakhtiyari is present throughout the Zagros fold-thrust belt and consists of conglomerate with subordinate sandstone and marl. The formation is up to 3000 m thick and was deposited in foredeep and wedge-top depocenters flanked by fold-thrust structures. Although the Bakhtiyari concordantly overlies Miocene deposits in foreland regions, an angular unconformity above tilted Paleozoic to Miocene rocks is expressed in the hinterland (High Zagros).

The Bakhtiyari Formation has been widely considered to be a regional sheet of Pliocene–Pleistocene conglomerate deposited during and after major late Miocene–Pliocene shortening. It is further believed that rapid fold growth and Bakhtiyari deposition commenced simultaneously across the fold-thrust belt, with limited migration from hinterland (NE) to foreland (SW). Thus, the Bakhtiyari is generally interpreted as an unmistakable time indicator for shortening and surface uplift across the Zagros. However, new structural and stratigraphic data show that the most-proximal Bakhtiyari exposures, in the High Zagros south of Shahr-kord, were deposited during the early Miocene and probably Oligocene. In this locality, a coarse-grained Bakhtiyari succession several hundred meters thick contains gray marl, limestone, and sandstone with diagnostic marine pelecypod, gastropod, coral, and coralline algae fossils. Foraminiferal and palynological species indicate deposition during early Miocene time. However, the lower Miocene marine interval lies in angular unconformity above ~ 150 m of Bakhtiyari conglomerate that, in turn, unconformably caps an Oligocene marine sequence. These relationships attest to syndepositional deformation and suggest that the oldest Bakhtiyari conglomerate could be Oligocene in age.

The new age information constrains the timing of initial foreland-basin development and proximal Bakhtiyari deposition in the Zagros hinterland. These findings reveal that structural evolution of the High Zagros was underway by early Miocene and probably Oligocene time, earlier than commonly envisioned. The age of the Bakhtiyari Formation in the High Zagros contrasts significantly with the Pliocene–Quaternary Bakhtiyari deposits near the modern deformation front, suggesting a long-term (> 20 Myr) advance of deformation toward the foreland.     

Subduction-related mafic to felsic magmatism in the Malayer–Boroujerd plutonic complex,western Iran

The Malayer–Boroujerd plutonic complex (MBPC) in western Iran, consists of a portion of a magmatic arc built by the northeast verging subduction of the Neo-Tethys plate beneath the Central Iranian Microcontinent (CIMC). Middle Jurassic-aged felsic magmatic activity in MBPC is manifested by I-type and S-type granites. The mafic rocks include gabbroic intrusions and dykes and intermediate rocks are dioritic dykes and minor intrusions, as well as mafic microgranular enclaves (MMEs). MBPC Jurassic-aged rocks exhibit arc-like geochemical signatures, as they are LILE- and LREE-enriched and HFSE- and HREE-depleted and display negative Nb–Ta anomalies. The gabbro dykes and intrusions originated from metasomatically enriched garnet-spinel lherzolite [Degree of melting (f_mel) ~ 15%] and exhibit negative Nd and positive to slightly negative ε_Hf(T) (+ 3.0 to ? 1.6). The data reveal that evolution of Middle Jurassic magmatism occurred in two stages: (1) deep mantle-crust interplay zone and (2) the shallow level upper crustal magma chamber. The geochemical and isotopic data, as well as trace element modeling, indicate the parent magma for the MBPC S-type granites are products of upper crustal greywacke (f_mel: 0.2), while I-type granites formed by partial melting of amphibolitic lower crust (f_mel: 0.25) and mixing with upper crustal greywacke melt in a shallow level magma chamber [Degree of mixing (f_mix): 0.3]. Mixing between andesitic melt leaving behind a refractory dense cumulates during partial crystallization of mantle-derived magma and lower crustal partial melt most likely produced MMEs (f_mix: 0.2). However, enriched and moderately variable ε_Nd(T) (? 3.21 to ? 4.33) and high (⁸⁷Sr/⁸⁶Sr)_i (0.7085–0.7092) in dioritic intrusions indicate that these magmas are likely experienced assimilation of upper crustal materials. The interpretations of magmatic activity in the MBPC is consistent with the role considered for mantle-derived magma as heat and mass supplier for initiation and evolution of magmatism in continental arc setting, elsewhere.