The influence of oxidation state on the electrical conductivity of olivine

The electrical conductivity of a single crystal of San Carlos olivine (Fo₉₂, 0.16 wt.% Fe₂O₃) has been measured as a function of temperature and oxygen fugacity (fO₂). After heating to 1338°C at fO₂ = 10^?12 atm., the conductivity at 950°C was 10^?5 (ohm-m)^?1, almost 3 orders of magnitude less than that measured in air. This decrease is due to the reduction of Fe³⁺ to Fe²⁺. Further heating to 1500°C at fO₂ = 10^?14 atm., decreased the electrical conductivity at 950°C to 10^?6 (ohm-m)^?1. When recovered at room temperature, the speciment had Fo₉₆ composition and contained small, opaque blebs distributed throughout the crystal. Derivations of temperature profiles for the earth's mantle from conductivity-depth models must take account of the important role played by iron oxidation state in the electrical conductivity of olivine.     

Geochemical Aspects of Hypogene Hydrothermal Alteration Zones in the Chol-qeshlaghi Area, NW Iran: Constrains on REEs

Chol-qeshlaghi altered area lies in the northwestern part of the post-collisional Urumieh-Dokhtar magmatic arc, NW Iran. Pervasive silicic, argillic, phyllic and propylitic altered zones appears to be intimately affiliated to the fluids derivative of upper Oligocene Khankandi granodiorite. This paper is dedicated to the identification of geochemical characteristics of hydrothermal alterations, focusing on the determination of the mass gains and losses of REEs, to gain significant insights regarding the chemical exchanges prevailed between the host rocks and hydrothermal fluids. The low pH and high activity of SO_4~(-2) ligands in silicic alteration fluids, resulting in depletion of entire REEs. Decreasing of LREEs appeared in argillic zone may attributed to reduce in adsorption ability of clay minerals in low pH; whereas HREEs enrichment in phyllic zone was inclined to put it down to the abundance of sericite(± Fe oxides). A significant reduction of Eu/Eu* ratio in silicic zone can be attributed to negligible sulfides and clay minerals as some effective agents in adsorption of released Eu~(+2). Factors such as changes in pH, the abundance of absorptive neomorph mineral phases, activity of ligands play an important role in controlling the distribution and concentration of REEs in Chol-qeshlaghi alteration system.     

The Dar al Gani meteorite field (Libyan Sahara): Geological setting,pairing of meteorites,and recovery density

Abstract— As of July 2001, 1238 Libyan meteorites have been reported. Most were found in two areas called Dar al Gani and Hamadah al Hamra. Dar al Gani is located on a plateau of marine carbonate rocks with marly components. Eight‐hundred and sixty‐nine meteorites between 6 g and 95 kg totalling 687 kg have been found here but the calculated mean recovery density is comparatively low with one meteorite on 6.5 km². Dar al Gani is a perfect site for the recognition and preservation of meteorites. The existence of meteorites is the result of a combination of specific geological and geomorphological conditions: there is a bright‐colored, old limestone plateau (<2 Ma), under arid weather conditions over long periods of time, with rapid elimination of surface water if present and low erosion rates. The preservation of meteorites is guaranteed through the absence of quartz sand on the plateau, strongly reducing wind erosion and a basic environment emerging from the carbonate ground retards rusting of metallic meteorite components. A supposed soil cover during pluvial times has probably protected older meteorites and led to a concentration of meteorites of different periods. An evaluation of Dar al Gani meteorites suggests the existence of at least 26 strewnfields and 26 meteorite pairs reducing the number of falls to, at most, 534. Shock and weathering grades as a tool for the recognition of pairings turned out to be problematic, as several strewnfields showed paired meteorites which had been classified to different shock and weathering grades.     

Transient analysis of wave propagation in non‐homogeneous elastic unbounded domains by using the scaled boundary finite‐element method

The scaled boundary finite‐element method has been developed for the dynamic analysis of unbounded domains. In this method only the boundary is discretized resulting in a reduction of the spatial dimension by one. Like the finite‐element method no fundamental solution is required. This paper extends the scaled boundary finite‐element method to simulate the transient response of non‐homogeneous unbounded domains with the elasticity modulus and mass density varying as power functions of spatial coordinates. To reduce the number of degrees of freedom and the computational cost, the technique of reduced set of base functions is applied. The scaled boundary finite‐element equation for an unbounded domain is reformulated in generalized coordinates. The resulting acceleration unit‐impulse response matrix is obtained and assembled with the equation of motion of standard finite elements. Numerical examples of non‐homogeneous isotropic and transversely isotropic unbounded domains demonstrate the accuracy of the scaled boundary finite‐element method. Copyright © 2006 John Wiley & Sons, Ltd.     

Ground viscosity and stiffness measurements for near surface seismic velocity

In land surveys, the weathering layer can often distort the seismic signal due to it passing through rapid velocity and density changes, dispersion, scattering and inelastic absorption. In a simple spring‐dashpot model for the earth response, an equivalent medium groups these complex phenomena into two parameters only; these are called ground viscosity and ground stiffness. The most recent controllers for vibrators can estimate both parameters. To validate these measurements, Saudi Aramco conducted an experiment measuring ground viscosity and stiffness from two different vibrator control systems over an area of varying terrain conditions, including unconsolidated sand and limestone outcrop. The two systems measured different values, but detected similar trends that correlated well with weathering conditions and surface geology, e.g. lower viscosity values on the outcrop than on the sand. The ratio of ground viscosity to ground stiffness can approximate the shallow S‐wave velocity, which we converted into P‐wave velocity through calibration with sparse uphole data. Static corrections incorporating this velocity information somewhat improved the focusing of seismic time sections. This new approach does not require additional acquisition efforts, and can model shallow complex formations in arid areas where classical static methods often fail.     

Plain strain soil–structure interaction model for a building supported by a circular foundation embedded in a poroelastic half-space

A simple theoretical model for soil–structure interaction in water saturated poroelastic soils is presented, developed to explore if the apparent building–foundation–soil system frequency changes due to water saturation. The model consists of a shear wall supported by a rigid circular foundation embedded in a homogenous, isotropic poroelastic half-space, fully saturated by a compressible and inviscid fluid, and excited by in-plane wave motion. The motion in the soil is governed by Biot's theory of wave propagation in fluid saturated porous media. Helmholtz decomposition and wave function expansion of the two P-wave and the S-wave potentials is used to represent the motion in the soil. The boundary conditions along the contact surface between the soil and the foundation are perfect bond (i.e. welded contact) for the skeleton, and either drained or undrained hydraulic condition for the fluid (i.e. pervious or impervious foundation). For the purpose of this exploratory analysis, the zero stress condition at the free surface is relaxed in the derivation of the foundation stiffness matrix, which enables a closed form solution. The implications of this assumption are discussed, based on published comparisons for the elastic case. Also, a closed form representation is derived for the foundation driving forces for incident plane (fast) P-wave or SV wave. Numerical results and comparison with the full-scale measurements are presented in the companion paper, published in this issue.     

Effects of rainfall on soil–structure system frequency: Examples based on poroelasticity and a comparison with full-scale measurements

In this paper, a simple two-dimensional soil–structure interaction model, based on Biot's theory of wave propagation in fluid saturated porous media, is used to explain the observed increase of the apparent frequencies of Millikan library in Pasadena, California, during heavy rainfall and recovery within days after the rain. These variations have been measured for small amplitude response (to microtremors and wind excitation), for which Biot's linear theory is valid. The postulated hypothesis is that the observed increases in frequency are due to the water saturation of the soil. The theoretical model used to explore this hypothesis consists of a shear wall supported by a circular foundation embedded in a poroelastic half-space. This rigid foundation model may be appropriate only for the NS response of Millikan library. This paper presents results for the foundation stiffness, and for the system response for model parameters similar to those for Millikan library (located on alluvium with shear wave velocity of about 300 m/s). The foundation impedance matrix, foundation input motion and system response are compared for dry and fully saturated half-space, with permeable and impermeable foundation. The results show that for embedded foundations, the effects of saturation on the horizontal foundation stiffness are as significant as for the vertical stiffness, contrary to what has been known for surface foundations investigated by other authors. Further, the results suggest a 1–2% increase in system frequency of the first two modes of vibration, depending on the drainage condition along the foundation–soil interface. Such increases agree qualitatively with the observations.     

Everyday effects, practices and causal mechanisms of ‘cultural embeddedness’: Learning from Utah’s high tech regional economy

In recent years, economic geographers have drawn extensively upon notions of ‘cultural embeddedness’ to explore how spatially variable sets of cultural conventions, norms, values and beliefs shape firms’ innovative performance in dynamic regional economies. However, our understanding of these causal links remains partial, reinforced by an ‘over-territorialised’ conception of cultural embeddedness which sidelines the role of institutional actors operating outside and across the boundaries of ‘the local’. So motivated, this paper offers a theoretically-informed - and theoretically informing - empirical analysis of the high tech regional economy in Salt Lake City, Utah to explore the everyday causal mechanisms, practices and processes - both local and extra-local - through which firms’ cultural embedding within the region is manifested, performed and (un)intentionally (re)produced. In so doing, this paper aims to further our understanding of the constitutive entanglement and complex interweaving of cultural/economic practices, and to contribute to the development of an in-depth empirical corpus of work which compliments the exciting conceptual developments that have largely dominated cultural economic geography over the last decade.     

Using Remote Sensing Data to Delineate the Lineaments for Hydrothermal Mineral Prediction in Heqing Area, Northwest Yunnan Province, China

Lineament extraction and analysis is one of the routine work in mapping medium and large areas using remote sensing data, most of which are satellite images. Landsat Enhanced Thematic Mapper （ETM） of 945×1 232 pixels subscene acquired on 21 March 2000 covering the northwestern part of Yunnan Province has been digitally processed using ER Mapper software. This article aims to produce lineament density map that predicts favorable zones for hydrothermal mineral occurrences and quantify spatial associations between the known hydrothermal mineral deposits. In the process of lineament extraction a number of image processing techniques were applied. The extracted lineaments were imported into MapGIS software and a suitable grid of 100 m×100 m was chosen. The Kriging method was used to create the lineament density map of the area. The results show that remote sensing data could be useful to extract the lineaments in the area. These lineaments are closely correlated with the faults obtained through other geological investigation methods. On comparing with field data the lineament-density map identifies two important high prospective zones, where large-scale deposits are already existing. In addition the map highlights unrecognized target areas that require follow up investigation.     

Early Cretaceous sedimentary provenance and structural evolution of the central Sanandaj–Sirjan Zone,Iran: implications for palaeogeographic reconstructions of the northern Neo-Tethyan margin

ABSTRACT

The Early Cretaceous was an important epoch in the evolution of the Earth system in which major tectonic episodes occurred, especially along the Alpine–Himalayan belt. The paucity of reliable palaeogeographic data from the central segment of this geological puzzle, however, hampers the reconstruction of a panoramic view of its Early Cretaceous palaeogeography and geodynamic setting. Here we present multidisciplinary provenance data from Lower Cretaceous strata of the overriding plate of the Neo-Tethyan subduction zone (the Sanandaj–Sirjan Zone; SSZ, of central Iran), including structural, basin-fill evolution, petrographic and geochemical analyses. Sandstone provenance analysis of Lower Cretaceous red beds suggests the occurrence of sub-mature litho-quartzose sandstones attributed to an active continental arc margin in convergent setting predominantly derived from plutonic, quartzose sedimentary and metamorphic rocks exposed in the central SSZ. Weathering indices indicate moderate chemical weathering in the source area which may be related to close source-to-sink relationships or arid climate. Our palaeogeographic reconstructions and original geological mapping indicate that the erosion of uplifted basement rocks exposed in horst blocks provided the sediment sources for the syn-extensional deposition of uppermost Jurassic–lowermost Cretaceous conglomerates and Lower Cretaceous siliciclastic red beds within a continental retro-arc basin during initiation of the ‘Neo-Tethys 2?. The polyphase tectonic reactivation along the principal fault of the study area controlled the syn- and post-extensional tectonostratigraphic evolution that reflect the corresponding mechanical decoupling/coupling along the northern Neo-Tethyan plate margin.