The accuracy of standard enthalpies and entropies for phases of petrological interest derived from density-functional calculations

The internal energies and entropies of 21 well-known minerals were calculated using the density functional theory (DFT), viz. kyanite, sillimanite, andalusite, albite, microcline, forsterite, fayalite, diopside, jadeite, hedenbergite, pyrope, grossular, talc, pyrophyllite, phlogopite, annite, muscovite, brucite, portlandite, tremolite, and CaTiO₃–perovskite. These thermodynamic quantities were then transformed into standard enthalpies of formation from the elements and standard entropies enabling a direct comparison with tabulated values. The deviations from reference enthalpy and entropy values are in the order of several kJ/mol and several J/mol/K, respectively, from which the former is more relevant. In the case of phase transitions, the DFT-computed thermodynamic data of involved phases turned out to be accurate and using them in phase diagram calculations yields reasonable results. This is shown for the Al₂SiO₅ polymorphs. The DFT-based phase boundaries are comparable to those derived from internally consistent thermodynamic data sets. They even suggest an improvement, because they agree with petrological observations concerning the coexistence of kyanite?+?quartz?+?corundum in high-grade metamorphic rocks, which are not reproduced correctly using internally consistent data sets. The DFT-derived thermodynamic data are also accurate enough for computing the P–T positions of reactions that are characterized by relatively large reaction enthalpies (>?100 kJ/mol), i.e., dehydration reactions. For reactions with small reaction enthalpies (a few kJ/mol), the DFT errors are too large. They, however, are still far better than enthalpy and entropy values obtained from estimation methods.     

Retrieving of Land Surface Temperature Using Thermal Remote Sensing and GIS Techniques in Kandaihimmat Watershed,Hoshangabad, Madhya Pradesh

Remotely sensed thermal infrared (TIR) data have been widely used to retrieve land surface temperature (LST). LST is an important parameter in the studies of urban thermal environment and dynamics. In the study, an attempt has been made using LANDSAT 8 thermal imagery to compute LST and the associated land cover parameters viz; land surface emissivity (LSE), normalized difference vegetation index (NDVI), normalized difference built-up index (NDBI) and normalized difference water index (NDWI). Landsat 8 TIRS band 10 & 11 (thermal bands) during 21 Oct. 2016, 22 Nov.2016, 24 Dec. 2016 and 09 Jan. 2017 were processed for LST analysis. However, band 5 & band 4 of the imagery was processed for NDVI, band 6 & band 5 for NDBI and band 2 & band 5 for NDWI analysis. LST has been derived from both the bands 10 &11 and validated by in-situ observations on the date and time of satellite overpass from the study area. Band 10 derived LST have shown much temperature difference while comparing with the in-situ observations. However, LST derived from band 11 found similar & close to the in-situ measurements. Relationship between band 11 results and in-situ observed measurements were developed, which has showing a strong correlation with (r² = 0.991). Land surface emissivity were also evaluated which shows variation in different land cover surfaces like vegetation, settlement, forest cover and water body. The study has proven that land surface temperature derived from satellite band 11 is the actual surface temperature of the study area.     

Petrogenesis and tectonic association of rift-related basic Panjal dykes from the northern Indian plate,North-Western Pakistan: evidence of high-Ti basalts analogous to dykes from Tibet

Mineralogy and Petrology - Rift related magmatism during Permian time in the northern margin of Indian plate is represented by basic dykes in several Himalayan terranes including north western...     

Satellite estimates and subpixel variability of rainfall in a semi-arid grassland

卫星估雨精度的不确定性受到当地降雨类型和像元内降雨非均匀性影响,而结合这两个关键因素开展半干旱草原卫星估雨的研究有限.2009年夏,我们在中国锡林郭勒半干旱草原用多部微雨雷达和雨量计构建了9 km卫星像元降雨观测网,观测了像元内降雨非均匀性(空间变异系数CV),并评估了卫星估雨精度.结果表明:(1)CV值受像元内平均降雨量,降雨类型,降雨云面积及移向等影响,如高Cv值的降雨过程大多为平均降雨量小,对流性降雨过程,降雨云边缘像元CV值较高;(2)TRMM 3B42V7卫星估雨产品适用性较好,CMORPH和PERSIANN次之,但TRMM 3B42V7易在半干旱草原湖泊处高估降雨.     

Carbon costs and benefits of France’s biomass energy production targets

Background

Concern about climate change has motivated France to reduce its reliance on fossil fuel by setting targets for increased biomass-based renewable energy production. This study quantifies the carbon costs and benefits for the French forestry sector in meeting these targets. A forest growth and harvest simulator was developed for French forests using recent forest inventory data, and the wood-use chain was reconstructed from national wood product statistics. We then projected wood production, bioenergy production, and carbon balance for three realistic intensification scenarios and a business-as-usual scenario. These intensification scenarios targeted either overstocked, harvest-delayed or currently actively managed stands.

Results

All three intensification strategies produced 11.6–12.4 million tonnes of oil equivalent per year of wood-based energy by 2026, which corresponds to the target assigned to French wood-energy to meet the EU 2020 renewable energy target. Sustaining this level past 2026 will be challenging, let alone further increasing it. Although energy production targets can be reached, the management intensification required will degrade the near-term carbon balance of the forestry sector, compared to continuing present-day management. Even for the best-performing intensification strategy, i.e., reducing the harvest diameter of actively managed stands, the carbon benefits would only become apparent after 2040. The carbon balance of a strategy putting abandoned forests back into production would only break even by 2055; the carbon balance from increasing thinning in managed but untended stands would not break even within the studied time periods, i.e. 2015–2045 and 2046–2100. Owing to the temporal dynamics in the components of the carbon balance, i.e., the biomass stock in the forest, the carbon stock in wood products, and substitution benefits, the merit order of the examined strategies varies over time.

Conclusions

No single solution was found to improve the carbon balance of the forestry sector by 2040 in a way that also met energy targets. We therefore searched for the intensification scenario that produces energy at the lowest carbon cost. Reducing rotation time of actively managed stands is slightly more efficient than targeting harvest-delayed stands, but in both cases, each unit of energy produced has a carbon cost that only turns into a benefit between 2060 and 2080.

     

Missing basics: a study on sanitation and women’s health in urban slums in Lucknow,India

GeoJournal - Sanitation is a multidimensional concept alluding primarily to provision of services for safe disposal of human excreta, provision of clean potable water as well as maintenance of...     

Indices based assessment of built-up density and urban expansion of fast growing Surat city using multi-temporal Landsat data sets

GeoJournal - The population growth in urban areas leads to the expansion of built-up area which leads to a number of serious problems like environmental pollution, destruction of urban ecology,...     

Evaluation of long term trends in apple cultivation and its productivity in Jammu and Kashmir from 1975 to 2015

GeoJournal - Horticulture plays a pivotal role in the economy of Jammu and Kashmir. Owing to favourable agro-climatic conditions, temperate horticulture is fast expanding in the state which is...     

Investigation of Failed Slopes Based on a New Method of Back Analysis in Rock Masses: A Case Study

Geotechnical and Geological Engineering - Small variation in shear strength parameters results in remarkable changes in the safety factor (SF) of a rock slope. In this regard, rock mass strength of...     

Causes and consequences of long-term groundwater overabstraction in Jordan

Hydrogeology Journal - In 2017, a comprehensive review of groundwater resources in Jordan was carried out for the first time since 1995. The change in groundwater levels between 1995 and 2017 was...