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921.
Interatomic potential parameters have been derived at simulated temperatures of 0 K and 300 K to model pyrite FeS2. The predicted pyrite structures are within 1% of those determined experimentally, while the calculated bulk modulus is within 7%. The model is also able to simulate the properties of marcasite, even though no data for this phase were included in the fitting procedure. There is almost no difference in results obtained for pyrite using the two potential sets; however, when used to model FeS2 marcasite, the potential fitted at 0 K performs better. The potentials have also been used to study the high-pressure behaviour of pyrite up to 44 GPa. The calculated equation of state gives good agreement with experiment and shows that the Fe–S bonds shorten more rapidly that the S–S dimer bonds. The behaviour of marcasite at high pressure is found to be similar to that of pyrite. 相似文献
922.
H. Sommer A. Kröner C. Hauzenberger S. Muhongo M. T. D. Wingate 《Journal of Metamorphic Geology》2003,21(9):915-934
New data on the metamorphic petrology and zircon geochronology of high‐grade rocks in the central Mozambique Belt (MB) of Tanzania show that this part of the orogen consists of Archean and Palaeoproterozoic material that was structurally reworked during the Pan‐African event. The metamorphic rocks are characterized by a clockwise P–T path, followed by strong decompression, and the time of peak granulite facies metamorphism is similar to other granulite terranes in Tanzania. The predominant rock types are mafic to intermediate granulites, migmatites, granitoid orthogneisses and kyanite/sillimanite‐bearing metapelites. The meta‐granitoid rocks are of calc‐alkaline composition, range in age from late Archean to Neoproterozoic, and their protoliths were probably derived from magmatic arcs during collisional processes. Mafic to intermediate granulites consist of the mineral assemblage garnet–clinopyroxene–plagioclase–quartz–biotite–amphibole ± K‐feldspar ± orthopyroxene ± oxides. Metapelites are composed of garnet‐biotite‐plagioclase ± K‐feldspar ± kyanite/sillimanite ± oxides. Estimated values for peak granulite facies metamorphism are 12–13 kbar and 750–800 °C. Pressures of 5–8 kbar and temperatures of 550–700 °C characterize subsequent retrogression to amphibolite facies conditions. Evidence for a clockwise P–T path is provided by late growth of sillimanite after kyanite in metapelites. Zircon ages indicate that most of the central part of the MB in Tanzania consists of reworked ancient crust as shown by Archean (c. 2970–2500 Ma) and Palaeoproterozoic (c. 2124–1837 Ma) protolith ages. Metamorphic zircon from metapelites and granitoid orthogneisses yielded ages of c. 640 Ma which are considered to date peak regional granulite facies metamorphism during the Pan‐African orogenic event. However, the available zircon ages for the entire MB in East Africa and Madagascar also document that peak metamorphic conditions were reached at different times in different places. Large parts of the MB in central Tanzania consist of Archean and Palaeoproterozoic material that was reworked during the Pan‐African event and that may have been part of the Tanzania Craton and Usagaran domain farther to the west. 相似文献
923.
ABSTRACT Maar craters often contain exceptionally preserved fossils and maar sediments may reflect detailed environmental changes. Volcanosedimentary processes in a Middle Eocene maar crater lake are illustrated by the deposits of Eckfeld Maar in the Tertiary Hocheifel Volcanic Field (Rhenish Massif, Germany). The maar origin of the basin is evident from a circular negative gravity anomaly which indicates a low-density funnel-shaped basin filling. From the facies analysis of an Eocene (Eckfeld) and a Pleistocene (Döttingen) maar we develop a lithozone classification for the interpretation of maar sediments: syn-/post-eruptive breccias are followed by a fining-upwards sequence of lacustrine mud with coarse layers and final swamp deposits. From the facies analysis and regional geological data we reconstruct the pre- to post-eruptive history of a maar crater prior to post-Eocene uplift. These observations can be used for the interpretation of Tertiary and Quaternary maar craters that are ideal fossil and sediment traps. 相似文献
924.
We analyze the strong motion accelerograms recorded for the large (MS=7.7, MW=7.3, mb=6.4) Rudbar earthquake of June 20, 1990. The earthquake had a complex source process. We have identified the imprints of rupture of three localized asperities on the major causative fault on the accelerograms. These asperities are interpreted to correspond to (i) the main shock that initiated the rupture process and was located in the domino block between the Kabateh and Zard Goli faults, (ii) a foreshock that occurred about 10 s earlier in the Kabateh fault and (iii) a later shock, on the western end of the Baklor fault, which terminated the bilateral rupture process at the western end. We estimate the strike, dip and slip of these causative sub-event rupture planes using the SH spectral amplitudes, based on a point source representation of sub-events and a non-linear least square formulation for inversion of the amplitude data. The results of our inversion of the near field data are comparable to other studies based on teleseismic data. 相似文献
925.
The relative significance of early (Finnmarkian) and late (Scandian) Caledonian deformation in N. Norway is uncertain. Early studies suggested pervasive Finnmarkian deformation whilst later results indicated a restricted Finnmarkian domain. The present work suggests it was more widespread than accepted and that inter Finnmarkian–Scandian deformation occurred. 40Ar/39Ar dating of 2–6 and 6–11 μm pelitic fractions from the lower to mid-greenschist facies Tanahorn Nappe (five samples; base Middle Allochthon) and the epizone Løkvikfjellet and Barents Sea Groups (three samples; North Varanger Region) in the north Scandinavian Caledonides show slightly discordant spectra. Most spectra from the Tanahorn Nappe preserve possible evidence of an early Caledonian event in the high temperature steps, with recoil/excess Ar effects in the low temperature steps; no pre-Caledonian relict component has been recorded. The results indicate Finnmarkian deformation continued to 460 Ma, with Scandian reactivation at 425–415 Ma. From the North Varanger Region, a strongly crenulated sample yielded plateau ages (444–442 Ma); means of combined young steps from weakly to uncrenulated samples gave 470–450 Ma, suggesting penetrative strike-slip deformation occurred in the late Finnmarkian to inter-Finnmarkian–Scandian period. No Scandian ages were recorded in the North Varanger Region. Reassessment of published data from the Laksefjord Nappe and Gaissa Thrust Belt suggests they were affected by Finnmarkian deformation. 相似文献
926.
U–Pb sensitive high resolution ion microprobe (SHRIMP) dating of zircons from charnockitic and garnet–biotite gneisses from the central portion of the Mozambique belt, central Tanzania indicate that the protolith granitoids were emplaced in a late Archaean, ca. 2.7 Ga, magmatic event. These ages are similar to other U–Pb and Pb–Pb ages obtained for other gneisses in this part of the belt. Zircon xenocrysts dated between 2.8 and 3.0 Ga indicate the presence of an older basement. Major and trace element geochemistry of these high-grade gneisses suggests that the granitoid protoliths may have formed in an active continental margin environment. Metamorphic zircon rims and multifaceted metamorphic zircons are dated at ca. 2.6 Ga indicating that these rocks were metamorphosed some 50–100 my after their emplacement. Pressure and temperature estimates on the charnockitic and garnet–biotite gneisses were obscured by post-peak metamorphic compositional homogenisation; however, these estimates combined with mineral textures suggest that these rocks underwent isobaric cooling to 800–850 °C at 12–14 kbar. It is considered likely that the granulite facies mineral assemblage developed during the ca. 2.6 Ga event, but it must be considered that it might instead represent a pervasive Neoproterozoic, Pan African, granulite facies overprint, similar to the ubiquitous eastern granulites further to the east. 相似文献
927.
S. K. Deb M. H. Manghnani K. Ross R. A. Livingston P. J. M. Monteiro 《Physics and Chemistry of Minerals》2003,30(1):31-38
A Raman scattering and X-ray diffraction study of the thermal decomposition of a naturally occurring, ettringite-group crystal
is presented. Raman spectra, recorded with increasing temperature, indicate that the thermal decomposition begins at ≈55 °C,
accompanied by dehydration of water molecules from the mineral. This is in contrast to previous studies that reported higher
temperature breakdown of ettringite. The dehydration is completed by 175 °C and this results in total collapse of the crystalline
structure and the material becomes amorphous. The Raman scattering results are supported by X-ray diffraction results obtained
at increasing temperatures.
Received: 9 July 2001 / Accepted: 14 August 2002 相似文献
928.
Relative sea level (RSL) data derived from isolation basins at Innaarsuit, a site on the south shores of the large marine embayment of Disko Bugt, West Greenland, record rapid RSL fall from the marine limit (ca. 108 m) at 10,300-9900 cal yr B.P. to reach the present sea level at 3500 cal yr B.P. Since 2000 cal yr B.P., RSL rose ca. 3 m to the present. When compared with data from elsewhere in Disko Bugt, our results suggest that the embayment was deglaciated later and more quickly than previously thought, at or slightly before 10,300 cal yr B.P. The northern part of Disko Bugt experienced less rebound (ca. 10 m at 6000 cal yr B.P.) compared with areas to the south. Submergence during the late Holocene supports a model of crustal down-warping as a result of renewed ice-sheet growth during the neoglacial. There is little evidence for west to east differences in crustal rebound across the southern shores of Disko Bugt. 相似文献
929.
A new method is presented for the computation of the gravitational attraction of topographic masses when their height information is given on a regular grid. It is shown that the representation of the terrain relief by means of a bilinear surface not only offers a serious alternative to the polyhedra modeling, but also approaches even more smoothly the continuous reality. Inserting a bilinear approximation into the known scheme of deriving closed analytical expressions for the potential and its first-order derivatives for an arbitrarily shaped polyhedron leads to a one-dimensional integration with – apparently – no analytical solution. However, due to the high degree of smoothness of the integrand function, the numerical computation of this integral is very efficient. Numerical tests using synthetic data and a densely sampled digital terrain model in the Bavarian Alps prove that the new method is comparable to or even faster than a terrain modeling using polyhedra. 相似文献
930.
Geoid determination using adapted reference field, seismic Moho depths and variable density contrast 总被引:4,自引:0,他引:4
The traditional remove-restore technique for geoid computation suffers from two main drawbacks. The first is the assumption
of an isostatic hypothesis to compute the compensation masses. The second is the double consideration of the effect of the
topographic–isostatic masses within the data window through removing the reference field and the terrain reduction process.
To overcome the first disadvantage, the seismic Moho depths, representing, more or less, the actual compensating masses, have
been used with variable density anomalies computed by employing the topographic–isostatic mass balance principle. In order
to avoid the double consideration of the effect of the topographic–isostatic masses within the data window, the effect of
these masses for the used fixed data window, in terms of potential coefficients, has been subtracted from the reference field,
yielding an adapted reference field. This adapted reference field has been used for the remove–restore technique. The necessary
harmonic analysis of the topographic–isostatic potential using seismic Moho depths with variable density anomalies is given.
A wide comparison among geoids computed by the adapted reference field with both the Airy–Heiskanen isostatic model and seismic
Moho depths with variable density anomaly and a geoid computed by the traditional remove–restore technique is made. The results
show that using seismic Moho depths with variable density anomaly along with the adapted reference field gives the best relative
geoid accuracy compared to the GPS/levelling geoid.
Received: 3 October 2001 / Accepted: 20 September 2002
Correspondence to: H.A. Abd-Elmotaal 相似文献