Authigenic dolomite cementation in the Upper Cretaceous Phosphate Formation, Western Desert, Egypt

The Upper Cretaceous Phosphate Formation in the Western Desert of Egypt displays a characteristic facies association that includes marine phosphorites interbedded with black shales and glauconitic sandstones. The upper part of the formation is characterized by the presence of thin phosphatic beds, which are filled-extensively-with disordered and non stoichiometric (mean MgCO₃ = 41.4 ± 0.34 mol%) authigenic dolomite cement. SEM and the back scattered images of these coarse crystalline dolomite cements reveal that they display planar euhedral crystal boundaries, polymodal crystal size distribution and variable inclusion pattern. The relatively low and wide ranged δ¹⁸O (− 0.87 to − 4.15‰ VPDB) values of the dolomite cements coupled with their depleted Sr (mean = 187 ± 26 ppm) and high iron and manganese values (mean = 6851 ± 554 ppm and 11599 ± 229 ppm respectively) invoke that they were formed from mixed hypo-saline fluids within a mixing marine-meteoric zone probably during a low stand period at the vicinity of the Maastrichtian/Early Tertiary unconformity. Meanwhile, their negative δ¹³C (− 1.31 to − 3.56‰ VPDB) values argue for a possible involvement of isotopically light carbon, derived from degradation of organic matter, during their precipitation.     

Identifying spatial heterogeneity of coal resource quality in a multilayer coal deposit by multivariate geostatistics

This study presents a new geostatistical approach to characterization of the geometry and quality of a multilayer coal deposit using the data of seam thickness as a geometric property and the contents of ash, sodium, total sulphur, and the heating value as quality properties. A coal deposit in East Kalimantan (Borneo), Indonesia, which has a synclinal geological structure, was chosen as the study site. Semivariogram analysis clarified the strong dependence of heating value on ash content in the top and bottom parts of each seam and the existence of a strong correlation with sodium content over the sub-seams in the same location. The correlations between the geometry and quality of the seams were generally weak. A linear coregionalization model was used to derive the spatial correlation coefficients of two variables at each scale component from the single- and cross-semivariogram matrices. Because the data were correlated spatially in the same seam or over different seams, multivariate techniques (ordinary cokriging and factorial cokriging) were mainly used and the resultant spatial estimates were compared to those derived using a univariate technique (ordinary kriging). A factorial cokriging was effective to decompose the spatial correlation structures with different scales. Another important characteristic was that the sodium content shows distinct segregation: the low zones are concentrated near the boundary of the sedimentary basin, while the high zones are concentrated in the central part. The main component of sodium originates from the abundance of saline water. Therefore, it can be inferred that seawater had stronger effects on the coal depositional process in the central basin than in the border part. The geostatistical modeling results suggest that the thicknesses of all the major seams were controlled by the syncline structure, while the coal qualities chiefly were originated from the coal depositional and diagenetic processes.     

Geochemical evaluation and thermal modeling of the Eocene–Oligocene Pabdeh and Middle Cretaceous Gurpi Formations in the northern part of the Dezful Embayment

Rock–Eval pyrolysis analysis, burial history, and 1D thermal maturity modeling have allowed the evaluation of the source rock potential, thermal maturation state, and impacts of the Pabdeh and Gurpi Formations in Cretaceous–Miocene petroleum system in the Naft Safid (NS) and Zeloi (ZE) oilfields, North Dezful Embayment. The total organic carbon (TOC) content of the Pabdeh and Gurpi Formations ranges from 0.2 to 4.7 wt% and 0.3 to 5.3 wt%, respectively. S2 values of the Pabdeh Formation in the ZE and NS oilfields vary from 0.41 to 13.77 and 0.29 to 14.5 mg HC (Hydrocarbon)/g rock, with an average value of 4.48 and 4.14 mg HC/g rock, respectively. These values for the Gurpi Formation in the ZE and NS oilfields range from 0.31 to 16.96 and 0.26 to 1.44 mg HC/g rock, with an average value of 8.54 and 2.43 mg HC/g rock, respectively. The S2 versus TOC diagram reveals a fair to good hydrocarbon generation potential of the Pabdeh Formation and poor to fair potential of the Gurpi Formation. The high values of S2 (S2 > S1) for samples of the both formations in the ZE and NS oilfields show that the samples are not contaminated with petroleum generated from underlying source rocks. The samples of the Pabdeh Formation in the ZE oilfield are characterized by a relatively narrow range of activation energy values with principal activation energy of 46 kcal/mol and frequency factor of 5.27 × 10⁺¹¹ s^?1. It seems that the high sulfur content of the Pabdeh organic matter probably caused the frequency factor and principal activation energy to be lower than usual. Hydrogen index (HI) values of the Pabdeh and Gurpi Formations in the ZE oilfield vary from 71 to 786 and 97 to 398 mg HC/g TOC, with an average value of 310 and 277 mg HC/g TOC, respectively. These values in the NS oilfield range from 66 to 546 and 51 to 525 mg HC/g TOC, with an average value of 256 and 227 mg HC/g TOC, respectively. Plot of HI vs. T _max value indicates that the majority of the Pabdeh and Gurpi samples contain predominantly type II kerogen and their organofacies are directly related to the more homogeneous precursor materials. Based on thermal maturity modeling results, kinetic parameters, and Rock–Eval analysis, both formations in the ZE and NS oilfields are thermally mature and immature or early mature stage, respectively.     

Interactions of uranium with bacteria and kaolinite clay

We assessed the accumulation of uranium (VI) by a bacterium, Bacillus subtilis, suspended in a slurry of kaolinite clay, to elucidate the role of microbes on the mobility of U(VI). Various mixtures of bacteria and the koalinite were exposed to solutions of 8 × 10^− 6 M- and 4 × 10^− 4 M-U(VI) in 0.01 M NaCl at pH 4.7. After 48 h, the mixtures were separated from the solutions by centrifugation, and treated with a 1 M CH₃COOK for 24 h to determine the associations of U within the mixture. The mixture exposed to 4 × 10^− 4 M U was analyzed by transmission electron microscope (TEM) equipped with EDS. The accumulation of U by the mixture increased with an increase in the amount of B. subtilis cells present at both U concentrations. Treatment of kaolinite with CH₃COOK, removed approximately 80% of the associated uranium. However, in the presence of B. subtilis the amount of U removed was much less. TEM–EDS analysis confirmed that most of the U removed from solution was associated with B. subtilis. XANES analysis of the oxidation state of uranium associated with B. subtilis, kaolinite, and with the mixture containing both revealed that it was present as U(VI). These results suggest that the bacteria have a higher affinity for U than the kaolinite clay mineral under the experimental conditions tested, and that they can immobilize significant amount of uranium.     

The effect of climate and land use change on flow duration in the Maryland Piedmont region

This paper describes the use of a continuous streamflow model to examine the effects of climate and land use change on flow duration in six urbanizing watersheds in the Maryland Piedmont region. The hydrologic model is coupled with an optimization routine to achieve an agreement between observed and simulated streamflow. Future predictions are made for three scenarios: future climate change, land use change, and jointly varying climate and land use. Future climate is modelled using precipitation and temperature predictions for the Canadian Climate Centre (CCC) and Hadley climate models. Results show that a significant increase in temperature under the CCC climate predictions produces a decreasing trend in low flows. A significant increasing trend in precipitation under the Hadley climate predictions produces an increasing trend in peak flows. Land use change by itself, as simulated by an additional 10% increase in imperviousness (from 20·5 to 30·5%), produces no significant changes in the simulated flow durations. However, coupling the effects of land use change with climate change leads to more significant decreasing trends in low flows under the CCC climate predictions and more significant increasing trends in peak flows under Hadley climate predictions than when climate change alone is employed. These findings indicate that combined land use and climate change can result in more significant hydrologic change than either driver acting alone. Copyright © 2008 John Wiley & Sons, Ltd.     

Hydraulic conductivity prediction based on grain-size distribution using M5 model tree

The hydraulic conductivity, K_s, is one of the most important hydraulic properties which controls the water and solute movement into the soil. It is measured on soil specimens in the laboratory. On the other hand, sometimes it is obtained by tests carried out in the field by a number of researchers. Therefore, several experimental formulas have developed to predict it. Recently, soft computing tools have been used to evaluate the hydraulic conductivity. However, these tools are not as transparent as empirical formulas. In this study, another soft computing approach, i.e. model trees, have been used for predicting the hydraulic conductivity. The main advantage of model trees is that, unlike the other data learning tools, they are easier to use and represent understandable mathematical rules more clearly. In this paper, a new formula that includes some parameters is derived to estimate the hydraulic conductivity. To develop the new formulas, experimental data sets of hydraulic conductivity were used. A comparison is made between the estimated hydraulic conductivity by this new formula and formulas given by other’s researches.     

Effects of mellowing sulfate-bearing clay soil stabilized with wastepaper sludge ash for road construction

The main objective of this research was to investigate the effect of mellowing on the swelling properties of stabilized Lower Oxford Clay (LOC), a sulfate-bearing clay soil that has caused concern in the past due to expansion upon stabilization. Two stabilizers were used, quicklime and a more sustainable stabilizer — wastepaper sludge ash (WSA), an industrial by-product used on its own and in combination with either quicklime (CaO) or ground granulated blastfurnace slag (GGBS). Quicklime was used on its own as a control. Compacted cylinders of LOC stabilized with the various stabilizers were made either mellowed (compacted 3 days after mixing with stabilizer) or unmellowed (compacted immediately after mixing with stabilizer). The linear expansion of the stabilized cylinders during moist curing and subsequent soaking was monitored for a total of 100 days. The results obtained showed that the linear expansion of unmellowed stabilized LOC was significantly reduced, and thus in terms of swelling potential, mellowing was not beneficial in the LOC system investigated. The results observed also suggest that there are technological, economic as well as environmental advantages of utilizing WSA and similar industrial by-products, in the stabilization of sulfate-bearing and other clay soils, as an alternative to the traditional stabilizers of lime and/or Portland Cement.     

The strength of Malaysian maritime cluster: The development of maritime policy

A comprehensive maritime industry policy that can be adequately monitored to achieve a competitive advantage is important. The Malaysian maritime industry comprises multifaceted sectors that are governed by fragmented governmental agencies. In this research, we investigated the Malaysian maritime industry cluster comprising three main sectors: Shipping, Ship Industry, Ports and Terminals. The Strength Indicator Model has been developed to reveals the maritime industry cluster. We find that the Competitions, Locations, Connections, Government and Chances factors affect the capability of the Malaysian maritime industry cluster. The result of this study will give a framework for Regulatory bodies and the various stakeholders to support the Malaysia maritime industry progressing toward a more competitive and sustainable development of the industry with the aim to become the developed maritime nation.     

Evaluation of earthquake activity along the Serghaya fault, Syria, from instrumental seismic data

This is a tentative study in order to characterize and identify the Serghaya fault in Syria through an analysis of its instrumentally observed earthquake activity for the period of 1995–2009. Different approaches are used to evaluate a- and b-values of the Gutenberg-Richter relation. It has been found that the computed b-values (around 1.5) are bigger than usually expected, which could be related either to incompleteness of earthquake catalogue or to invalidity of the Gutenberg-Richter model in the case of Serghaya fault. Based on several explanations of high b-values, existing in the literature, it can be inferred that the events recorded on the Serghaya fault occurred at small depths in the heterogeneous milieus under low stresses. A relative seismic quiescence from 1900 up to now is observed, whereas the biggest earthquake recorded during the study period does not exceed magnitude 3.9. Such quiescence does not reflect accurately an earthquake potential of the Serghaya fault and can probably indicate a large-magnitude earthquake occurrence in near future. The established earthquake catalogue must be necessarily completed in order to deeper characterize the real behavior of the Serghaya fault. Such a characterization, accompanied with seismic activity evaluation, could be used in the assessment of seismic hazard.     

Active crustal shortening in NE Syria revealed by deformed terraces of the River Euphrates

The Africa–Arabia plate boundary comprises the Red Sea oceanic spreading centre and the left‐lateral Dead Sea Fault Zone (DSFZ); however, previous work has indicated kinematic inconsistency between its continental and oceanic parts. The Palmyra Fold Belt (PFB) splays ENE from the DSFZ in SW Syria and persists for ～400 km to the River Euphrates, but its significance within the regional pattern of active crustal deformation has hitherto been unclear. We report deformation of Euphrates terraces consistent with Quaternary right‐lateral transpression within the PFB, indicating anticlockwise rotation (estimated as 0.3° Ma^?1 about 36.0°N 39.8°E) of the block between the PFB and the northern DSFZ relative to the Arabian Plate interior. The northern DSFZ is shown to be kinematically consistent with the combination of Euler vectors for the PFB and the Red Sea spreading, resolving the inconsistency previously evident. The SW PFB causes a significant earthquake hazard, previously unrecognized, to the city of Damascus.