Adaptation of climate variability/extreme in arid environment of the Arabian peninsula by rainwater harvesting and management

Water management in Saudi Arabia is facing major challenges due to the limited water resources and increasing uncertainties caused by climate change. The rainfall and temperature records of the Saudi meteorological data for more than three decades were analyzed for policy suggestions in water sectors based on the changing rainfall patterns. The trends in the annual aridity and rain indices were also examined to define the changing climate conditions and for determining the dry months in different cities of the Kingdom. An increased annual and maximum rainfall was observed for six cities while a decreasing trend in both annual and maximum rainfall was observed for the same number of cities highlighting the variability of rainfall in the whole region. An increasing maximum rainfall with decreasing annual rainfall was observed for the rest of the cities signifying the more extreme rainfall evens and resulting floods of short durations. The changing rainfall trends were also observed for different months during 31 years of the recorded period in addition to the varying climate pattern for different cities within the same district. Finally, these preliminary assessments of any systematic changes in view of the increased rain intensities and extreme climate events are viewed to demonstrate the value rainwater harvesting and management as a local adaptation to the climate variability and extreme in the Kingdom.     

Composition and source identification of polycyclic aromatic hydrocarbons in mangrove sediments of Peninsular Malaysia: indication of anthropogenic input

This is a comprehensive study of the composition, origin and sources of specific polycyclic aromatic hydrocarbons (PAHs) in sediments of mangrove estuary in the western part of Peninsular Malaysia. Mangrove sediments were analyzed for 17 PAHs by gas chromatography–mass spectrometry. Total PAH concentrations in the sediments ranged from 20 to 112 ng/g on a dry-weight basis. High molecular weight PAHs were abundant in the sediments. Parent PAH ratios revealed that pyrogenic input has important contribution to the sedimentary PAHs. Ratios of alkylated PAHs indicate that the sedimentary PAHs were influenced by petrogenic PAHs, which implies that petrogenic input has contribution to the sedimentary PAHs but that it is not a major factor in distribution of PAHs within the estuary. Combustion-derived PAHs show a positive and very strong correlation with total PAHs (R ² = 0.926, p < 0.05). Total methylphenanthrenes show very weak correlation with total PAHs (R ² = 0.0928, p < 0.05). The PAH concentrations were found to increase with distance from the upstream of the estuary to the coastal area of the Straits of Malacca. For the assessment of sediment contamination using biological thresholds, none of the individual studied PAH compounds exceeded the values of the effect range low–effect range median guideline and the threshold effects level–probable effects level guideline. This study demonstrates that the sediments of the mangrove ecosystem facing the Straits of Malacca and Sumatra are influenced by anthropogenic PAH inputs as a result of human activities such as biomass burning, vehicle emissions and boating activities.     

Sources of sedimentary PAHs in tropical Asian waters: Differentiation between pyrogenic and petrogenic sources by alkyl homolog abundance

We collected surface sediment samples from 174 locations in India, Indonesia, Malaysia, Thailand, Vietnam, Cambodia, Laos, and the Philippines and analyzed them for polycyclic aromatic hydrocarbons (PAHs) and hopanes. PAHs were widely distributed in the sediments, with comparatively higher concentrations in urban areas (∑PAHs: ∼1000 to ∼100 000 ng/g-dry) than in rural areas (∼10 to ∼100 g-dry), indicating large sources of PAHs in urban areas. To distinguish petrogenic and pyrogenic sources of PAHs, we calculated the ratios of alkyl PAHs to parent PAHs: methylphenanthrenes to phenanthrene (MP/P), methylpyrenes + methylfluoranthenes to pyrene + fluoranthene (MPy/Py), and methylchrysenes + methylbenz[a]anthracenes to chrysene + benz[a]anthracene (MC/C). Analysis of source materials (crude oil, automobile exhaust, and coal and wood combustion products) gave thresholds of MP/P = 0.4, MPy/Py = 0.5, and MC/C = 1.0 for exclusive combustion origin. All the combustion product samples had the ratios of alkyl PAHs to parent PAHs below these threshold values. Contributions of petrogenic and pyrogenic sources to the sedimentary PAHs were uneven among the homologs: the phenanthrene series had a greater petrogenic contribution, whereas the chrysene series had a greater pyrogenic contribution. All the Indian sediments showed a strong pyrogenic signature with MP/P ≈ 0.5, MPy/Py ≈ 0.1, and MC/C ≈ 0.2, together with depletion of hopanes indicating intensive inputs of combustion products of coal and/or wood, probably due to the heavy dependence on these fuels as sources of energy. In contrast, sedimentary PAHs from all other tropical Asian cities were abundant in alkylated PAHs with MP/P ≈ 1-4, MPy/Py ≈ 0.3-1, and MC/C ≈ 0.2-1.0, suggesting a ubiquitous input of petrogenic PAHs. Petrogenic contributions to PAH homologs varied among the countries: largest in Malaysia whereas inferior in Laos. The higher abundance of alkylated PAHs together with constant hopane profiles suggests widespread inputs of automobile-derived petrogenic PAHs to Asian waters.     

Separation of Vanillin from Oil Palm Empty Fruit Bunch Lignin

The separation of vanillin from the lignin of empty fruit bunch oil palm is presented in this study. The lignin was extracted from soda black liquor derived from oil palm empty fruit bunches (EFB) using 20% sulfuric acid. Nitrobenzene oxidation was carried out by adding 50 mg of dry EFB lignin into a mixture of 7 mL of 2 M NaOH and 4 mL of nitrobenzene in a 15 mL steel autoclave. The autoclave was sealed tightly with a screw cap fitted with a Teflon gasket and heated to 165°C for 3 h in a preheated thermostatic oil bath. High performance liquid chromatography (HPLC) was used to determine the concentration of each compound present in the lignin. There were eight compounds detected in the HPLC chromatogram. The crystallization process was then used as a method to separate vanillin from other compounds. Based on the solubility of vanillin in acetone, 15 mL of acetone was added to the residue of the oxidized products and heated to 60°C for 10 min. A yield of 1.6% vanillin was isolated from a 50 mg lignin sample. The isolated compound was analyzed with HPLC, Fourier transform infrared spectrophotometry (FT‐IR) and nuclear magnetic resonance (¹³C‐NMR) for structural verification. The results of the characterization studies proved that the isolated compound is vanillin.     

Biosorption of Cd(II), Ni(II) and Pb(II) from Aqueous Solution by Dried Biomass of Aspergillus niger: Application of Response Surface Methodology to the Optimization of Process Parameters

In this study, the biosorption of Cd(II), Ni(II) and Pb(II) on Aspergillus niger in a batch system was investigated, and optimal condition determined by means of central composite design (CCD) under response surface methodology (RSM). Biomass inactivated by heat and pretreated by alkali solution was used in the determination of optimal conditions. The effect of initial solution pH, biomass dose and initial ion concentration on the removal efficiency of metal ions by A. niger was optimized using a design of experiment (DOE) method. Experimental results indicated that the optimal conditions for biosorption were 5.22 g/L, 89.93 mg/L and 6.01 for biomass dose, initial ion concentration and solution pH, respectively. Enhancement of metal biosorption capacity of the dried biomass by pretreatment with sodium hydroxide was observed. Maximal removal efficiencies for Cd(II), Ni(III) and Pb(II) ions of 98, 80 and 99% were achieved, respectively. The biosorption capacity of A. niger biomass obtained for Cd(II), Ni(II) and Pb(II) ions was 2.2, 1.6 and 4.7 mg/g, respectively. According to these observations the fungal biomass of A. niger is a suitable biosorbent for the removal of heavy metals from aqueous solutions. Multiple response optimization was applied to the experimental data to discover the optimal conditions for a set of responses, simultaneously, by using a desirability function.     

Time dependent chemical study of contracting interstellar clouds. II. abundances of oxygen- and sulphur-bearing molecules

Abstract. We have constructed a chemical reaction system in a contracting interstellar cloud. In paper (I) we have presented the details of the physical and chemical scheme and the method of solution. The results of our chemical model produce fractional abundances of H₂CO, CO, OH, H₂O, SO and OCS which are in good agreement with the results of observations. On the other hand, the results of chlorine-bearing species are not in agreement with those of the observations. The calculated abundances of H₂CO, CO, OH, H₂O, SO, OCS and Cl⁺ are in agreement with the results of previous theoretical studies.     

Temporal variations of tides on the west coast of Great Britain

Summary. Temporal variations of tides are investigated by analysing tidal observations from five ports on the west coast of Great Britain. Variations considered here are those occurring in the semi-diurnal species daily, in the tidal constituents resolved from analyses of 29 day sets over a period of two years, 1980–81, and in the tidal constituents resolved from 1 yr sets over a period of 19 yr. The time variations of tidal constituents are mainly due to inseparable terms grouping with the principal term due to the short length of data and the insufficiency of the procedures to account for them. Surges and surge-tide interaction are affecting the resolution of tides. Time variations of constituents of the diurnal species induced by non-tidal forces are spatially consistent. The use of equilibrium relationships to account for modulations of principal constituents by waves separable in an 18.61 yr nodal cycle improves the analysis. However, the modulation is smaller in the real tide than in the equilibrium tide. When the application of this principle is extended to a wider frequency band to cover constituents which cannot be resolved from one month of observations, it may produce the opposite effect. These problems start compounding with decreasing length of data, i.e. increasing band width of resolution.
Functional approximations of interaction coefficients (bi-admittance) of non-linear tides, similar to the response (admittance) of linear tides are computed for semi-diurnal, fourth-diurnal and sixth-diurnal bands. These functional estimates may be used to interpolate unseparable constituents to improve the quality of analyses. The results are consistent with the fact that the response of the sea does not change in a narrow frequency band covering a nodal cycle of the Moon. The change in the equilibrium relationship between the principal term and its nodal term can be interpreted in terms of the damping effect of bottom friction.     

An approach to the problem of coastal erosion in quaternary sediments

Approximately 40 per cent of the shorelines of the lower Great Lakes are backed by relatively weak Quaternary sediments, and similar shorelines are found on many middle and high-latitude coasts. The high rates of bluff recession which are characteristic of these areas lead to economic losses through erosion of land and damage to buildings, and may prompt a wide range of measures designed to reduce erosion and protect property. Assessment of the physical problem and of possible solutions to it can best be achieved through a sediment budget approach. This is illustrated through a case study of an area near Grimsby, Ontario. The volume of sediment supply to the beach was calculated from measurements of bluff height and annual recession rates. The potential volume of longshore sediment transport was determined from the wave climate of the area and computer modelling of wave refraction. The relationship between sediment supply and potential transport rate can be used to assess the magnitude of the sediment deficit or surplus at points along the shoreline, and this provides an insight into the controls on alongshore variations in recession rates.