Dissolution of secondary copper sulphides using complex-forming agents (EDTA,EDA). Part II: Chalcocite dissolution in EDTA and EDA

This work is immediate continuation of Part I, using an identical method and evaluation for kinetic studies. The systems chalcocite-ethylene diamine tetra-acetic acid and chalcocite-ethylene diamine were studied. It was necessary to refine the geometrical model method for chalcocite in order to establish dissolution kinetics of polydispersions. This work confirms that chalcocite leaching proceeds through covellite even in the medium of complex-forming agents and kinetic equations for both leaching stages were evaluated with an attempt at physical interpretation.     

On the observations of Mount St Helens volcanic emissions: Research note

Abstract

The envelopes of dust clouds from the May 18, 1980 eruption of Mount St Helens in Washington State, U.S.A. were plotted as they traversed the northern United States and southern Canada. Visibility observations at many meteorological stations indicated the presence of volcanic ash and smoke and verified trajectory calculations. In addition, sulphur dioxide released by the volcano was detected as it passed over Toronto, Ontario, while satellite photographs showed dust clouds in the upper atmosphere.     

Pre‐Alpine discordant granitic dikes in the metamorphic core of the Betic Cordillera: tectonic implications

Pegmatite dikes bearing andalusite crosscut foliation S₂ in Alpujarride gneisses and schists. Post‐S₂ andalusite is transposed by a foliation S₃, defined by fibrolite, which affects the dikes. The dikes represent highly differentiated granitic magmas with low REE and Zr contents and a positive Eu anomaly. U‐Pb SHRIMP dating of magmatic zircons provided Pan‐African ages (cores) and late Variscan ages (rims). However, U‐rich rims also provided metamorphic Alpine ages, supporting a polyorogenic tectonometamorphic history for pre‐Mesozoic Alpujarride rocks.     

Changes in the onset and length of seasons from an ensemble of regional climate models over Spain for future climate conditions

This study analyses the length and onset of the four seasons based on the annual climatic cycle of maximum and minimum temperatures. Previous studies focused over climatically homogeneous mid-high latitude areas, employing fixed temperature thresholds (related to climatic features such as freezing point) that can be inadequate when different climate conditions are present. We propose a method related to the daily minimum and maximum temperature 25th and 75th point-dependent climatic percentiles. It is applied to an ensemble of regional climate models (RCMs) of 25-km horizontal resolution over the peninsular Spain and Balearic Islands, where a large variety of climatic regimes, from alpine to semi-desertic conditions, are present. First, baseline climate (1961–2000) ERA40-forced RCM simulations are successfully compared with the Spain02 daily observational database, following astronomical season length (around 90 days). This result confirms the validity of the proposed method and capability of the RCMs to describe the seasonal features. Future climate global climate model-forced RCMs (2071–2100) compared with present climate (1961–1990) simulations indicate the disappearance of winter season, a summer enlargement (onset and end) and a slight spring and autumn increase.     

Hydration shell structures in a LiI solution at elevated temperature and pressure: a molecular dynamics study

Molecular dynamics simulations of a 0.55 molal aqueous LiI solution have been performed at 508 K and 308 K and a density of 1.05 g/cm³. The structural changes resulting from increased temperature and pressure are discussed.     

Earthquake hazard of the northern parts of the Bohemian Massif and Western Carpathians

The new procedure of earthquake hazard evaluation developed by Kijko and Sellevoll is tested and applied for the border region of Czechoslovakia and Poland. The new method differs from the conventional approach. It incorporates the uncertainty of earthquake magnitudes, and accepts mixed data containing only large historical events and recent, complete catalogues. Seismic hazard has been calculated for nine regions determined in the border area. In the investigated area, data of historical catalogues are uncertain or, in many cases, the epicentral intensities are unknown. Thus, a number of assumptions have to be adopted in data preparation of catalogues since the year 1200. The calculated values of parameters b in the Gutenberg-Richter frequency-intensity relation as well as the return periods, seem to be reasonable and are generally confirmed by the results obtained from catalogues for the last 80–130 years.     

European floods during the winter 1783/1784: scenarios of an extreme event during the ‘Little Ice Age’

The Lakagígar eruption in Iceland during 1783 was followed by the severe winter of 1783/1784, which was characterised by low temperatures, frozen soils, ice-bound watercourses and high rates of snow accumulation across much of Europe. Sudden warming coupled with rainfall led to rapid snowmelt, resulting in a series of flooding phases across much of Europe. The first phase of flooding occurred in late December 1783–early January 1784 in England, France, the Low Countries and historical Hungary. The second phase at the turn of February–March 1784 was of greater extent, generated by the melting of an unusually large accumulation of snow and river ice, affecting catchments across France and Central Europe (where it is still considered as one of the most disastrous known floods), throughout the Danube catchment and in southeast Central Europe. The third and final phase of flooding occurred mainly in historical Hungary during late March and early April 1784. The different impacts and consequences of the above floods on both local and regional scales were reflected in the economic and societal responses, material damage and human losses. The winter of 1783/1784 can be considered as typical, if severe, for the Little Ice Age period across much of Europe.     

Micromechanical approach to effective viscoelastic properties of micro‐fractured geomaterials

The aim of this paper is to formulate a micromechanics‐based approach to non‐aging viscoelastic behavior of materials with randomly distributed micro‐fractures. Unlike cracks, fractures are discontinuities that are able to transfer stresses and can therefore be regarded from a mechanical viewpoint as interfaces endowed with a specific behavior under normal and shear loading. Making use of the elastic‐viscoelastic correspondence principle together with a Mori‐Tanka homogenization scheme, the effective viscoelastic behavior is assessed from properties of the material constituents and damage parameters related to density and size of fractures. It is notably shown that the homogenized behavior thus formulated can be described in most cases by means of a generalized Maxwell rheological model. For practical implementation in structural analyses, an approximate model for the isotropic homogenized fractured medium is formulated within the class of Burger models. Although the approximation is basically developed for short‐term and long‐term behaviors, numerical applications indicate that the approximate Burger model accurately reproduce the homogenized viscoelastic behavior also in the transient conditions.