Weathering of the black limestone of historical monuments (Ljubljana,Slovenia): Oxygen and sulfur isotope composition of sulfate salts

The black limestone widely used in Slovenian monuments, particularly in the baroque architecture, is deteriorating extensively due to salt crystallization. Samples of soluble salts from two important historical monuments (in Ljubljana, Slovenia) were investigated in terms of their mineral and isotopic (S and O) compositions. Results revealed the presence of gypsum and soluble salts of the MgSO₄·nH₂O series, such as starkeyite (MgSO₄·4H₂O), pentahydrite (MgSO₄·5H₂O) and hexahydrite (MgSO₄·6H₂O). Whereas black crusts and subflorescences consisted of gypsum, efflorescences appeared to be an assemblage of gypsum and MgSO₄ hydrates. Sample δ¹⁸O_sulfate values varied from ?1.9‰ to +5.5‰ vs. V-SMOW and δ³⁴S_sulfate values from ?19.8‰ to +3.2‰ vs. V-CDT. The respective isotopic composition of analysed outdoor and indoor monument samples indicated different sources of contamination.     

Optical spectra of supernova remnant candidates in the Sculptor Group galaxy NGC 300

We present moderate-resolution (<5 Å) long-slit optical spectra of 51 nebular objects in the nearby Sculptor Group galaxy NGC 300 obtained with the 2.3 meter Advanced Technology Telescope at Siding Spring Observatory, Australia. Adopting the criterion of [S?ii]_Total:Hα≥0.4 to confirm supernova remnants (SNRs) from optical spectra, we find that of 28 objects previously proposed as SNRs from optical observations, 22 meet this criterion with six showing [S?ii]_Total:Hα of less than 0.4. Of 27 objects suggested as SNRs from radio data, four are associated with the 28 previously proposed SNRs. Of these four, three (included in the 22 above) meet the criterion. In all, 22 of the 51 nebular objects meet the [S ii]_Total:Hα criterion as SNRs while the nature of the remaining 29 objects remains undetermined by these observations.     

Meteotsunami in the Great Lakes and on the Atlantic coast of the United States generated by the “derecho” of June 29–30, 2012

Tsunami-like intense sea-level oscillations, associated with atmospheric activity (meteorological tsunamis), are common in the Great Lakes and on the East Coast of the United States. They are generated by various types of atmospheric disturbances including hurricanes, frontal passages, tornados, trains of atmospheric gravity waves, and derechos. “Derecho” is a rapidly moving line of convectively induced intense thunder storm fronts producing widespread damaging winds and squalls. The derecho of June 29–30, 2012 devastatingly propagated from western Iowa to the Atlantic coast, passing more than 1,000 km and producing wind gusts up to 35 m/s. This derecho induced pronounced seiche oscillations in Lake Michigan, Chesapeake Bay, and along the US Atlantic coast. Sea-level records from the updated National Oceanic and Atmospheric Administration (NOAA) tide gauge network, together with the NOAA and automated surface-observing system air pressure and wind records, enabled us to examine physical properties and temporal/spatial variations of the generated waves. Our findings indicate that the generation mechanisms of extreme seiches in the basins under study are significantly different: energetic winds play the main role in seiche formation in Chesapeake Bay; atmospheric pressure disturbances are most important for the Atlantic coast; and the combined effect of pressure oscillations and wind is responsible for pronounced events in the Great Lakes. The “generation coefficient,” which is the ratio of the maximum observed sea-level height and the height of air pressure disturbance, was used to map the sea-level response and to identify “hot spots” for this particular event, i.e., harbors and bays with amplified seiche oscillations. The Froude number, Fr = U/c, where U is the speed of the atmospheric disturbance and c is the long-wave speed, is the key parameter influencing the water response to specific atmospheric disturbances; the maximum response was found for those regions and disturbance parameters for which Fr ~1.0.     

Relationship between MODIS based Aerosol Optical Depth and PM10 over Croatia

This study analyzes the relationship between Aerosol Optical Depth (AOD) obtained from Terra and Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) and ground-based PM10 mass concentration distribution over a period of 5 years (2008–2012), and investigates the applicability of satellite AOD data for ground PM10 mapping for the Croatian territory. Many studies have shown that satellite AOD data are correlated to ground-based PM mass concentration. However, the relationship between AOD and PM is not explicit and there are unknowns that cause uncertainties in this relationship. The relationship between MODIS AOD and ground-based PM10 has been studied on the basis of a large data set where daily averaged PM10 data from the 12 air quality stations across Croatia over the 5 year period are correlated with AODs retrieved from MODIS Terra and Aqua. A database was developed to associate coincident MODIS AOD (independent) and PM10 data (dependent variable). Additional tested independent variables (predictors, estimators) included season, cloud fraction, and meteorological parameters — including temperature, air pressure, relative humidity, wind speed, wind direction, as well as planetary boundary layer height — using meteorological data from WRF (Weather Research and Forecast) model. It has been found that 1) a univariate linear regression model fails at explaining the data variability well which suggests nonlinearity of the AOD-PM10 relationship, and 2) explanation of data variability can be improved with multivariate linear modeling and a neural network approach, using additional independent variables.     

Early Cambrian eclogites in SW Mongolia: evidence that the Palaeo‐Asian Ocean suture extends further east than expected

Newly discovered eclogites, Early Cambrian carbonates and chloritoid‐bearing metapelites form the Tsakhir Uul accretionary wedge, which was thrust during the Early Cambrian over the Mesoproterozoic Dzabkhan‐Baydrag continent. The rock association of the wedge forms a tectonic window emerging through the hangingwall Khantaishir ophiolite unit, which preserves a typical Tethyan‐type ophiolitic sequence. The eclogites correspond geochemically to T‐MORB modified by fluid circulation. They are composed of garnet, omphacite, amphibole, rutile ±muscovite ±quartz ±epidote and exhibit well‐equilibrated matrix textures. Jadeite content of the omphacite reaches up to 45 mol.%, the Si content of muscovite is between 3.40 and 3.45 p.f.u., amphibole is winchite to barroisite, but reaches tschermakitic composition at some rims, and garnet composition is grs_0.24–0.36, alm_0.43–0.56, py_0.05–0.18, sps_0.00–0.18, . The peak assemblage, together with the composition of garnet rims, omphacite, amphibole and muscovite, correspond in a pseudosection to 20?22.5 kbar and 590?610 °C. The tschermakitic rim of amphibole is interpreted as partial reequilibration on decompression below 16 kbar and ～600?630 °C. Two muscovite separates from the eclogite yielded an Ar–Ar plateau age of 543.1 ± 3.9 Ma (1σ) and a mean age of 547.9 ± 2.6 Ma (1σ), whereas muscovite from an interbedded garnet‐chloritoid micaschist yielded an Ar–Ar plateau age of 536.9 ± 2.7 Ma (1σ); these ages are interpreted as cooling ages. The P–T data, geochemistry of eclogites and cooling ages suggest an affinity between the Tsakhir Uul wedge and the Gorny Altai and the north Mongolian blueschist belt, which are believed typical for subduction of warm oceanic lithosphere and closure of small oceanic basins. Thus, the discovery of the Tsakhir Uul eclogites represents an important finding suggesting extension of the Early Cambrian subduction system of the Central Asian Orogenic Belt far to the east in a region where it was not expected.     

The Jurassic Prehodavci Formation of the Julian Alps: easternmost outcrops of Rosso Ammonitico in the Southern Alps (NW Slovenia)

The Julian Alps are located in NW Slovenia and structurally belong to the Julian Nappe where the Southern Alps intersect with the Dinarides. In the Jurassic, the area was a part of the southern Tethyan continental margin and experienced extensional faulting and differential subsidence during rifting of the future margin. The Mesozoic succession in the Julian Alps is characterized by a thick pile of Upper Triassic to Lower Jurassic platform limestones of the Julian Carbonate Platform, unconformably overlain by Bajocian to Tithonian strongly condensed limestones of the Prehodavci Formation of the Julian High. The Prehodavci Formation is up to 15 m thick, consists of Rosso Ammonitico type limestone and is subdivided into three members. The Lower Member consists of a condensed red, well-bedded bioclastic limestone with Fe–Mn nodules, passing into light-grey, faintly nodular limestone. The Middle Member occurs discontinuously and consists of thin-bedded micritic limestone. The Upper Member unconformably overlies the Lower or Middle Members. It is represented by red nodular limestone, and by red-marly limestone with abundant Saccocoma sp. The Prehodavci Formation unconformably overlies the Upper Triassic to Lower Jurassic platform limestone of the Julian Carbonate Platform; the contact is marked by a very irregular unconformity. It is overlain by the upper Tithonian pelagic Biancone (Maiolica) limestone. The sedimentary evolution of the Julian High is similar to that of Trento Plateau in the west and records: (1) emergence and karstification of part of the Julian Carbonate Platform in the Pliensbachian, or alternatively drowning of the platform and development of the surface by sea-floor dissolution; (2) accelerated subsidence and drowning in the Bajocian, and onset of the condensed pelagic sedimentation (Prehodavci Formation) on the Julian High; (3) beginning of sedimentation of the Biancone limestone in the late Tithonian.     

Orbital Parameters of the Binary Companion in o and Using Spectrum Disentangling

o And is one of the most frequently observed Be stars, both in photometry and spectroscopy. It is a multiple system of at least four stars (a Be star, a close binary of spectral types B7 and B8, and an A star). For over a century, numerous observers report a highly variable spectrum, photometric changes, and a substantial range of radial velocity. The star has changed back and forth between a shell-type and a normal B-type star. The last emission phase started in 1992 and ended in 2000. Analysis of the dynamical spectra at spectral lines Mg II 4481 Å and He I 6678 Å and radial velocity curves shows that the two binary components can be resolved. We decomposed the triple star spectra and computed orbital parameters of the binary companion using the KOREL code for spectrum disentangling.     

Multichannel Blind Deconvolution As A Tool For Solar Image Restoration

A principle of restoration methods based on multichannel blind deconvolution (MBD) is introduced. The methods assume that for every un-degraded unobservable image several degraded observed images are available. It is better conditioned than classical single channel approach. The first algorithm represents a generalization of iterative deconvolution scheme introduced for single images. The second MBD algorithm is based on so-called subspace technique. The subspace method is not iterative and this possibly implies an implementation that can be computationally more efficient. Both methods are presented in applications to artificial image data (computer-generated multichannel degraded data) with known ideal image to get a comparison with restored one. Performance in a real situation on solar photosphere images is shown.     

Numerical search for periodic solutions in the vicinity of the figure-eight orbit: slaloming around singularities on the shape sphere

We present the results of a numerical search for periodic orbits with zero angular momentum in the Newtonian planar three-body problem with equal masses focused on a (narrow) search window bracketing the figure-eight initial conditions. We found eleven solutions that can be described as some power of the “figure-eight” solution in the sense of the topological classification method. One of these solutions, with the seventh power of the “figure-eight”, is a choreography. We show numerical evidence of its stability.