Density and magnetic models of the lithosphere along CELEBRATION 2000 profile CEL01

The paper presents 2D density and magnetic models of the crust and upper mantle along the DSS line profile of the CELEBRATION 2000 project that crosses the most important geological units in Central Europe. These are the Alps-Carpathians-Pannonian (ALCAPA) region, the SE part of the Paleozoic Platform (PLZ), the Trans-European Suture Zone (TESZ) and a fragment of the SW portion of the East European Craton (EEC). The density and magnetic models were constructed on the basis of a 2D model of P-wave velocity converted into density model, geological data as well as geothermal data and the results of integrated geophysical modelling for the lithosphere-asthenosphere boundary.     

3D inversion of gravity data by separation of sources and the method of local corrections: Kolarovo gravity high case study

We present a novel methodology for 3D gravity/magnetic data inversion. It combines two algorithms for preliminary separation of sources and an original approach to 3D inverse problem solution. The first algorithm is designed to separate sources in depth and to remove the shallow ones. It is based on subsequent upward and downward data continuation. For separation in the lateral sense, we approximate the given observed data by the field of several 3D line segments. For potential field data inversion we apply a new method of local corrections. The method is efficient and does not require trial-and-error forward modeling. It allows retrieving unknown 3D geometry of anomalous objects in terms of restricted bodies of arbitrary shape and contact surfaces. For restricted objects, we apply new integral equations of gravity and magnetic inverse problems. All steps of our methodology are demonstrated on the Kolarovo gravity anomaly in the Danube Basin of Slovakia.     

Nb-Ta-Ti oxides fractionation in rare-metal granites: Kr��sno-Horn�� Slavkov ore district, Czech Republic

Nb-Ta-Ti-bearing oxide minerals (Nb-Ta-bearing rutile, columbite-group minerals) represent the most common Nb-Ta host in topaz-albite granites and related rocks from the Krásno-Horní Slavkov ore district. Tungsten-bearing columbite-(Fe), W-bearing ixiolite, wodginite and tapiolite-(Fe) are extremely rare in these rocks. Rutile contains significant levels of Ta (up to 37?wt.% Ta₂O₅) and Nb (up to 24?wt.% Nb₂O₅), with Ta/(Ta?+?Nb) ratio ranging from 0.04 to 0.61. Columbite-group minerals are represented mostly by columbite-(Fe) and rarely by columbite-(Mn), with Mn/(Mn?+?Fe) ratio ranging from 0.23 to 0.94. The exceptionally rare Fe-rich, W-bearing ixiolite occurs only as inclusions in Nb-Ta-bearing rutile from quartz-free alkali-feldspar syenites (Vysoky Kámen stock). Wodginite was found only in the topaz-albite microgranite of gneissic breccia matrix that occurs in the upper most part of the Hub topaz-albite granite stock. In wodginite, the Mn/(Mn?+?Fe) ratio is 0.42?C0.51, whereas the coexisting tapiolite-(Fe) has a distinctly lower Mn/(Mn?+?Fe) ratio close to 0.06.     

Factors affecting the Nd3+ (REE3+) luminescence of minerals

In this paper, possibilities and limits of the application of REE³⁺ luminescence (especially the Nd^{3+ 4}F_3/2 → ⁴I_9/2 emission) as structural probe are evaluated. Important factors controlling the Nd³⁺ luminescence signal are discussed, including effects of the crystal-field, crystal orientation, structural state, and temperature. Particular attention was paid to the study of the accessory minerals zircon (ZrSiO₄), xenotime–(Y) (YPO₄), monazite–(Ce) (CePO₄) and their synthetic analogues. Based on these examples we review in short that (1) REE³⁺ luminescence can be used as non-destructive phase identification method, (2) the intensities of certain luminescence bands are strongly influenced by crystal orientation effects, and (3) increased widths of REE³⁺-related emission bands are a strong indicator for structural disorder. We discuss the potential of luminescence spectroscopy, complementary to Raman spectroscopy, for the quantitative estimation of chemical (and potentially also radiation-induced) disorder. For the latter, emissions of Nd³⁺-related centres are found to be promising candidates.     

Chemical Dynamics and Evaluation of Biogeochemical Processes in Alpine River Kamniška Bistrica, North Slovenia

Biogeochemical processes were investigated in alpine river—Kamni?ka Bistrica River (North Slovenia), which represents an ideal natural laboratory for studying anthropogenic impacts in catchments with high weathering capacity. The Kamni?ka Bistrica River water chemistry is dominated by HCO₃ ^?, Ca²⁺ and Mg²⁺, and Ca²⁺/Mg²⁺ molar ratios indicate that calcite weathering is the major source of solutes to the river system. The Kamni?ka Bistrica River and its tributaries are oversaturated with respect to calcite and dolomite. pCO₂ concentrations were on average up to 25 times over atmospheric values. δ¹³C_DIC values ranged from ?12.7 to ?2.7 ‰, controlled by biogeochemical processes in the catchment and within the stream; carbonate dissolution is the most important biogeochemical process affecting carbon isotopes in the upstream portions of the catchment, while carbonate dissolution and organic matter degradation control carbon isotope signatures downstream. Contributions of DIC from various biogeochemical processes were determined using steady state equations for different sampling seasons at the mouth of the Kamni?ka Bistrica River; results indicate that: (1) 1.9–2.2 % of DIC came from exchange with atmospheric CO₂, (2) 0–27.5 % of DIC came from degradation of organic matter, (3) 25.4–41.5 % of DIC came from dissolution of carbonates and (4) 33–85 % of DIC came from tributaries. δ¹⁵N values of nitrate ranged from ?5.2 ‰ at the headwater spring to 9.8 ‰ in the lower reaches. Higher δ¹⁵N values in the lower reaches of the river suggest anthropogenic pollution from agricultural activity. Based on seasonal and longitudinal changes of chemical and isotopic indicators of carbon and nitrogen in Kamni?ka Bistrica River, it can be concluded that seasonal changes are observed (higher concentrations are detected at low discharge conditions) and it turns from pristine alpine river to anthropogenic influenced river in central flow.     

Earthquake Swarms and Accompanying Phenomena in Intraplate Regions: A Review

The western part of the Bohemian Massif has played an exceptional role in recent geodynamic activity of the region. It is characterised by repeated occurrences of earthquake swarms and by other manifestations of deep tectonic processes (CO ₂ emissions, anomalous ³ He content, mineral waters, mofettes, etc.). The purpose of this paper is to introduce some other intraplate regions with earthquake swarm occurrence (French Massif Central; Colli Albani and Vulsini Mts., central Italy; Southern Apennines, Italy; the Danville and Long Valley regions, California; central Arkansas), and with artificially induced earthquake swarms (Larderello, Italy, geothermal field; Coso, California, geothermal field; NE Bavaria, Germany, deep drilling project). Although these areas represent different tectonic environments, the manifestations of recent geodynamic and/or man-made activity are similar in many aspects. This coincidence most probably issues from a common cause of both tectonic and artificially induced earthquake swarms – intrusions/injections of fluids. Since the regions with earthquake swarm occurrence of tectonic origin are situated as a rule in the close neighbourhood of Quaternary volcanoes, the intruding fluids seem to be derived from magma recently transported to upper crustal layers.     

A Raman spectroscopic study on the structural disorder of monazite–(Ce)

This study addresses whether Raman spectra can be used to estimate the degree of accumulated radiation damage in monazite-(Ce) samples whose chemical composition was previously determined. Our results indicate that the degree of disorder in monazite–(Ce), as observed from increasing Raman band broadening, generally depends on both the structural state (i.e., radiation damage) and the chemical composition (i.e., incorporation of non-formula elements). The chemical effects were studied on synthetic orthophosphates grown using the Li-Mo flux method, and non radiation-damaged analogues of the naturally radiation-damaged monazite–(Ce) samples, produced by dry annealing. We found that the “chemical” Raman-band broadening of natural monazite–(Ce) can be predicted by the empirical formula, $$ {\hbox{FWHM}} {\hbox{[c}}{{\hbox{m}}^{ - {1}}}{]} = {3}{.95} + {26}{.66} \times {\hbox{(Th}} + {\hbox{U}} + {\hbox{Ca}} + {\hbox{Pb)}} {\hbox{[apfu]}} $$ where, FWHM = full width at half maximum of the main Raman band of monazite–(Ce) (i.e., the symmetric PO₄ stretching near 970?cm^?1), and (Th+U+Ca+Pb) = sum of the four elements in apfu (atoms per formula unit). Provided the chemical composition of a natural monazite–(Ce) is known, this “chemical band broadening” can be used to estimate the degree of structural radiation damage from the observed FWHM of the ν₁(PO₄) band of that particular sample using Raman spectroscopy. Our annealing studies on a wide range of monazite–(Ce) reference materials and other monazite–(Ce) samples confirmed that this mineral virtually never becomes highly radiation damaged. Potential advantages and the practical use of the proposed method in the Earth sciences are discussed.     

PROJECTIONS OF CLIMATE CHANGE FOR THE CZECH REPUBLIC

The paper deals with a selection of the climatological baseline, GCM validity and construction of the climate change scenarios for an impact assessment in the Czech territory. The period of 1961–1990 has been selected as the climatological baseline. The corresponding database includes more than 50 monthly mean temperature and precipitation series, and 16 time series of daily meteorological data that contain also the solar radiation data. The 1× CO₂ outputs produced by four GCMs, provided by the CSMT (GISS, GFD30, GFD01, and CCCM), were compared with observed temperature and precipitation conditions in western and central Europe with a particular attention devoted to the Czech territory. The GCM ability to simulate annual cycles of temperature, precipitation and radiation was thoroughly examined. The GISS and CCCM were selected as a basis for constructing climate change scenarios as they simulated reasonably the observed patterns. According to the GISS variant, 2× CO₂ climate assumes a higher winter and lower summer warming, and an increase in annual precipitation amounts. A dangerous combination of the summer temperature increase and declining precipitation amounts is a specific feature of the CCCM scenario. An incremental scenario for temperature and precipitation is based on the combination of prescribed changes in both annual means and annual courses.