Extreme <Superscript>15</Superscript>N Depletion in Seagrasses

Seagrass beds form an important part of the coastal ecosystem in many parts of the world but are very sensitive to anthropogenic nutrient increases. In the last decades, stable isotopes have been used as tracers of anthropogenic nutrient sources and to distinguish these impacts from natural environmental change, as well as in the identification of food sources in isotopic food web reconstruction. Thus, it is important to establish the extent of natural variations on the stable isotope composition of seagrass, validating their ability to act as both tracers of nutrients and food sources. Around the world, depending on the seagrass species and ecosystem, values of seagrass N normally vary from 0 to 8?‰ δ¹⁵N. In this study, highly unusual seagrass N isotope values were observed on the east coast of Qatar, with significant spatial variation over a scale of a few metres, and with δ¹⁵N values ranging from +2.95 to ?12.39?‰ within a single bay during March 2012. This pattern of variation was consistent over a period of a year although there was a seasonal effect on the seagrass δ¹⁵N values. Seagrass, water column and sediment nutrient profiles were not correlated with seagrass δ¹⁵N values and neither were longer-term indicators of nutrient limitation such as seagrass biomass and height. Sediment δ¹⁵N values were correlated with Halodule uninervis δ¹⁵N values and this, together with the small spatial scale of variation, suggest that localised sediment processes may be responsible for the extreme isotopic values. Consistent differences in sediment to plant ¹⁵N discrimination between seagrass species also suggest that species-specific nutrient uptake mechanisms contribute to the observed δ¹⁵N values. This study reports some of the most extreme, negative δ¹⁵N values ever noted for seagrass (as low as ?12.4?‰) and some of the most highly spatially variable (values varied over 15.4?‰ in a relatively small area of only 655 ha). These results are widely relevant, as they demonstrate the need for adequate spatial and temporal sampling when working with N stable isotopes to identify food sources in food web studies or as tracers of anthropogenic nutrients.     

Concentrations of the elements Ag,Al, Ca,Cd, Cu,Fe, Mg,Mn, Pb and Zn,and the radionuclides 210Pb and 210Po in the digestive gland of the squid Nototodarus gouldi

Ag, Al, Ca, Cd, Cu, Fe, Mg, Mn, Pb and Zn concentrations and ²¹⁰Po and ²¹⁰Pb activities were measured in 26 specimens of the squid Nototodarus gouldi taken from the waters of Bass Strait in one jigging operation. All the elements show wide ranges in concentrations in specimens apparently subject to the same environmental conditions. Copper concentration was 27-1 200 μg/g, and ²¹⁰Po activity 4·8–24·2 Bq/g. The animal wet weights, the elements Ag, Al, Cd, Fe and Zn, and the radionuclide ²¹⁰Po have coefficients of variation in the range 40–60%; Ca, Mg and Mn show the smallest variability (CV = < 30%), and Cu the greatest (CV = 12%). Significant correlations (p < 0·001) were found between the following pairs of elements: Cd-Zn, Cd-Cu, Zn-Cu, Mg-Mn, Fe-Mn, Ca-Mg and Fe-²¹⁰Po.     

Enceladus' plume: Compositional evidence for a hot interior

The combined observations of Saturn's moon Enceladus by the Cassini CAPS, INMS and UVIS instruments detected water vapor geysers in which were present molecular nitrogen (N₂), carbon dioxide (CO₂), methane (CH₄), propane (C₃H₈), acetylene (C₂H₂), and several other species, together with all of the decomposition products of water. We propose that the presence of N₂ in the plume indicates thermal decomposition of ammonia, and hence high temperatures in the interior of the moon (e.g., 500 to 800 K). Such an environment also appears to be suitable for the production of methane (CH₄) from carbon monoxide (CO), or carbon dioxide (CO₂). The presence of C₂H₂ and C₃H₈ strongly suggest that catalytic reactions took place within a very hot environment. The internal environment of Enceladus is inferred to be or have been favorable for aqueous, catalytic chemistry. This permits the synthesis of many complex organic compounds that could be detected in future Cassini observations.     

Variation of seismic coupling with slab detachment and upper plate structure along the western Hellenic subduction zone

The western Hellenic subduction zone is characterized by a trenchward velocity of the upper plate. In the Ionian islands segment, complete seismic coupling is achieved, as is predicted by standard plate-tectonic models in which there is no slab pull force because the slab has broken off. The moderate local seismic moment rate relates to a shallow downdip limit for the seismogenic interface. This characteristic may be attributed to the ductility of the lower crust of the upper plate, which allows a décollement between the upper crust of the overriding plate and the subducting plate. Farther south, a deeper downdip limit of the seismogenic interface is indicated by thrust-faulting earthquakes, which persist much deeper in western Crete. A correspondingly larger downdip width of this seismogenic zone is consistent with the suggested larger maximum magnitude of earthquakes here. However, since the seismic moment release rate seems to be moderate in the Peloponnese and western Crete, like in in the Ionian islands, this seismically active interface cannot maintain complete seismic coupling across its larger downdip width. A cause may be the lateral addition of overweight to the part of the slab still attached in Crete, by the free fall of its part that has broken off from the surface further north. This increased slab pull reduces the compressive normal stress across the seismogenic interface and thus causes partial seismic coupling in its shallower part. However, the width of this part may provide an additional area contributing to slip in large earthquakes, which may nucleate deeper on stick-slip parts of the interface. Hints at anomalies in structure and seismicity, which need to be resolved, may relate to the present location of the edge of the tear in the slab.     

Geology, Geochemistry and U-Pb SHRIMP Age of the Tacloban Ophiolite Complex, Leyte Island (Central Philippines): Implications for the Existence and Extent of the Proto-Philippine Sea Plate

Abstract. The oceanic basement of the Central Philippines is exposed in ophiolitic massifs the age and origin of which remain debated. The Tacloban Ophiolite Complex (TOC) outcrops as a NW-SE trending massif in the northeastern portion of Leyte Island, Central Philippines. It is unconformably overlain by sedimentary sequences dated to Late Miocene-Pliocene and Pleistocene volcaniclastic deposits on its eastern and western flanks, respectively. Field, petrographic and trace element data suggest a subduction-related origin for this ophiolite. Sensitive High Resolution Ion Microprobe (SHRIMP) U-Pb dating of zircons from a gabbro yielded Early Cretaceous magmatic age for the TOC, which is very much older than a previously reported whole rock K-Ar derived Eocene age. The Early Cretaceous age of the TOC limits its possible progenitor to the proto-Philippine Sea Plate. Correlation with other Cretaceous ophiolites in Central Philippines reveals the possible extent of the proto-Philippine Sea Plate remnants now exposed onland.     

Petrogenesis of the Eocene and Mio–Pliocene alkaline basaltic magmatism in Meseta Chile Chico, southern Patagonia, Chile: Evidence for the participation of two slab windows

The Meseta Chile Chico (MCC, 46.4°S) is the westernmost exposure of Eocene (lower basaltic sequence, LBS; 55–40 Ma, K–Ar ages) and Mio–Pliocene (upper basaltic sequence, UBS; 16–4 Ma, K–Ar ages) flood basalt volcanism in Patagonia. The MCC is located south of the Lago General Carrera-Buenos Aires (LGCBA), southeast from the present day Chile Triple Junction (CTJ), east of the actual volcanic gap between Southern South Volcanic Zone and Austral Volcanic Zone (SSVZ and AVZ, respectively) and just above the inferred location of the South Chile Ridge segment subducted at 6 Ma (SCR-1). Erupted products consist of mainly ne-normative olivine basalt with minor hy-normative tholeiites basalt, trachybasalt and basanite. MCC lavas are alkaline (42.7–53.1 wt.% SiO₂, 3–8 wt.% Na₂O+K₂O) and relatively primitive (Ni: 133–360 ppm, Cr: 161–193 ppm, Co: 35–72 ppm, 4–16.5 MgO wt.%). They have a marked OIB-like signature, as shown by their isotopic compositions (⁸⁷Sr/⁸⁶Sr_o=0.70311–0.70414 and εNd=+4.7–+5.1) and their incompatible trace elements ratios (Ba/La=10–20, La/Nb=0.46–1.09, Ce/Pb=15.52–27.5, Sr/La<25), reflecting deep mantle origin. UBS-primitive lavas have characteristics similar to those of the Eocene LBS basalts, while UBS-intermediate lavas show geochemical imprints (La/Nb>1, Sr/La>25, low Ce/Pb, Nb/U) compatible with contamination by arc/slab-derived and/or crustal components. We propose that the genesis and extrusion of magmas is related to the opening of two slab windows due to the subduction of two active ridge segments beneath Patagonia during Eocene and Mio–Pliocene.     

Plate Motion of India and Interseismic Strain in the Nepal Himalaya from GPS and DORIS Measurements

We analyse geodetically estimated deformation across the Nepal Himalaya in order to determine the geodetic rate of shortening between Southern Tibet and India, previously proposed to range from 12 to 21 mm yr^?1. The dataset includes spirit-levelling data along a road going from the Indian to the Tibetan border across Central Nepal, data from the DORIS station on Everest, which has been analysed since 1993, GPS campaign measurements from surveys carried on between 1995 and 2001, as well as data from continuous GPS stations along a transect at the logitude of Kathmandu operated continuously since 1997. The GPS data were processed in International Terrestrial Reference Frame 2000 (ITRF2000), together with the data from 20 International GNSS Service (IGS) stations and then combined using quasi- observation combination analysis (QOCA). Finally, spatially complementary velocities at stations in Southern Tibet, initially determined in ITRF97, were expressed in ITRF2000. After analysing previous studies by different authors, we determined the pole of rotation of the Indian tectonic plate to be located in ITRF2000 at 51.409±1.560° N and ?10.915±5.556°E, with an angular velocity of 0.483±0.015°. Myr^?1. Internal deformation of India is found to be small, corresponding to less than about 2 mm yr^?1 of baseline change between Southern India and the Himalayan piedmont. Based on an elastic dislocation model of interseismic strain and taking into account the uncertainty on India plate motion, the mean convergence rate across Central and Eastern Nepal is estimated to 19±2.5 mm yr^?1, (at the 67% confidence level). The main himalayan thrust (MHT) fault was found to be locked from the surface to a depth of about 20 km over a width of about 115 km. In these regions, the model parameters are well constrained, thanks to the long and continuous time-series from the permanent GPS as well as DORIS data. Further west, a convergence rate of 13.4±5 mm yr^?1, as well as a fault zone, locked over 150 km, are proposed. The slight discrepancy between the geologically estimated deformation rate of 21±1.5 mm yr^?1 and the 19±2.5 mm yr^?1 geodetic rate in Central and Eastern Nepal, as well as the lower geodetic rate in Western Nepal compared to Eastern Nepal, places bounds on possible temporal variations of the pattern and rate of strain in the period between large earthquakes in this region.