Distribution of nitrate over sea-salt and soil derived particles — Implications from a field study

A method for determining the distribution of supermicrometer nitrate between size-segregated sea-salt and soil derived particles is presented. The analysis is based on field data from six measurements at a coastal site in southern Finland, and on a theoretical treatment taking into account the transfer of gaseous species onto particle surfaces and their subsequent reaction. Significant amounts of nitrate were found in both the particle types, with the fraction of nitrate associated with soil particles varying from 20–50% in the 1–2 m size to near 90% in particles larger than 10 m. Overall, the nitrate accumulation followed closely the relative abundances of these two particle types. Two overlapping modes in supermicron nitrate mass size distributions could be identified. The lower mode, associated with sea-salt, was located between the surface-area and volume distribution of sodium peaking at about 2–3 m of EAD. The upper mode peaked at 3–5 m and followed more closely the surface-area distribution of calcium in all samples. At our site, the accumulation of nitrate into both particle types was shown to be limited by an effective surface reaction rate rather than by gas-phase diffusion. This rate was estimated to be considerably larger for sea-salt particles. Strong evidence in support of the saturation of nitrate in sea-salt particles were obtained.     

A 1-D model of the formation and evolution of Polar Stratospheric Clouds

A 1-D model of the formation and seasonal evolution of Polar Stratospheric Clouds (PSCs) is described. The model considers PSCs of types 1 and 2 in the vertical range from 8 to 30 km and utilizes real temperature data. The micro-physical processes included in the model are the heterogeneous nucleation and condensation (or evaporation), while sedimentation, gas diffusion and vertical wind velocity are the processes responsible for transport. Model simulations have been compared with PSC data obtained by lidar at the South Pole: results for the winter 1990 are discussed. The different contribution of type 1 and type 2 PSCs to the measured backscattering coefficient has been evidenced. In the simulations, layers of NAT particles form when low values of the backscattering coefficient are measured; similarly, ice particles form when sharper and rapidly changeable structures with higher values of the backscattering coefficient are observed. Significant results on the condensation and depletion of HNO₃ and H₂O are presented. Water vapor profiles measured during winter 1990 are reproduced quite well.     

Photoelectric photometry of asteroids 45, 120, 776, 804, 814, and 1982DV

Photoelectric lightcurves of six asteroids, observed at the ESO 50-cm photometric telescope, are presented. 45 Eugenia, observed for pole determination program, showed a small amplitude of light variation, i.e., about 0.09÷0.10 mag. For 120 Lachesis, no period of rotation was deduced from three observing nights; it is probably longer than 20 hr. 776 Berbericia was observed again to eliminate the ambiguity between 23^h and 15^h.3 periods, as pointed out by Schober (1979). The longer period is ruled out, but we suggest a very plausible shorter period of 7^h.762, implying, at least at this opposition, one maximum and one minimum per cycle. A similar ambiguity is present for 804 Hispania also. The period could be either 14.^h.84 or 7^h.42. These two objects are typical of a class of asteroids whose periods are uncertain by a factor two. A short discussion on this problem is given. For 814 Tauris a long period of 35.8 hr is found, confirming the tendency of dark asteroids of intermediate size to rotate more slowly than larger ones. Finally a single-night lightcurve of the fast-moving object 1982DV is presented. Our observations agree very well with Harris' results (1982, private communication).     

Dynamical Behavior of Asteroids Near Resonance: the 4:1 gap and the 7:2 Group

A comparative study of the evolution of the Sun–Jupiter–Asteroid system near the 4:1 and 7:2 resonances is performed by means of two techniques that proceed differently from the Hamiltonian corresponding to the planar restricted elliptic three-body problem. One technique is based on the classical Schubart averaging while the other is based on a mapping method in which the perturbing part of the Hamiltonian is expanded and the resulting terms are ordered according to a weight function that depends on the powers of eccentricities and the coefficients of the terms. For the mapping method the effect of Saturn on the asteroidal evolution is introduced and the degree of chaos is estimated by means of the Lyapunov time. Both methods are shown to lead to similar results and can be considered a suitable tool for describing the evolution of asteroids in the Kirkwood gap and the group corresponding to the 4:1 and 7:2 Jovian resonances, respectively. This revised version was published online in July 2006 with corrections to the Cover Date.     

Surface studies of asteroids from earthbound observations

The angular diameter of minor planets compared with best observation conditions of about one arcsec (seeing) at ground-based observatories, though situated at high sea levels with best climate conditions, usually is too small to be resolved for surface studies or diameter determinations with direct photographic or similar imaging methods.Nevertheless the rough geometry and/or small scale structures on the asteroid's surface can be studied with light-curve observations using high precision photoelectric photometry and the fact that the rotation of an asteroid during a spin period is now determined for slightly more than 200 minor planets.On only a few selected asteroids (63 Ausonia, 88 Thisbe, 92 Undina, 110 Lydia, 118 Peitho, 128 Nemesis, 139 Juewa, 337 Devosa and 599 Luisa) do we show, from details detected in the light-curves, how observations of this type were carried out successfully. From the small scale features we get the rough linear extensions on the asteroid surface from differences in magnitude and time. Such observations will be more useful and important in future with respect to an optimum selection of objects for a possible direct asteroid spacecraft mission.Paper presented at the European Workshop on Planetary Sciences, organised by the Laboratorio di Astrofisica Spaziale di Frascati, and held between April 23–27, 1979, at the Accademia Nazionale del Lincei in Rome, Italy.Visiting Astronomer, Kitt Peak National Observatory, USA, Operated by the Association of Universities for Research in Astronomy Inc., under contract with the National Science Foundation. A part of the observations was carried out at the Observatoire de Haute Provence (OHP), France.     

Particulate barium fluxes on the continental margin: a study from the Alboran Sea (Western Mediterranean)

Particulate biogenic barium (bio-Ba) fluxes obtained from three instrumented arrays moored in the Alboran Sea, the westernmost basin in the Mediterranean Sea, are presented in this study. The mooring lines were deployed over almost 1 year, from July 1997 to May 1998, and were equipped with sediment traps at 500–700 m depth, 1000–1200 m depth and 30 m above the seafloor (1000–2200 m). The results obtained support the growing body of evidence that the relationship between particulate bio-Ba and Corg throughout the water column in margin systems is clearly different from this relation in the open ocean. In the Alboran Sea, the annual averaged bio-Ba fluxes range from 0.39 to 1.07 μmol m⁻² day⁻¹, with mean concentrations of 1.31–1.69 μmol g⁻¹ and bio-Ba/Corg ratios lower than in the open ocean. The low bio-Ba values obtained also indicate that calculating bio-Ba is extremely sensitive to the detrital Ba/Al ratio of each sample. The lithogenic Ba fraction in the Alboran Sea continental margin area contributes between 24% and 85% of the total Ba. Increased bio-Ba export efficiency was observed after periods of high primary productivity and suggests that the processes limiting the bio-Ba formation in the study area relate to settling dynamics of organic matter aggregates. Furthermore, the ballasting effect of the abundant lithogenic and carbonate particles may limit decomposition of organic matter aggregates and enhance the transfer of particles rich in Corg and relatively poor in bio-Ba to the deep seafloor. Lateral input of freshly sedimented biogenic material, including particulate bio-Ba, has been observed on the lower continental slope in the western Alboran Sea. These observations emphasize that the use of the bio-Ba as a proxy of export productivity from the surface ocean must be used cautiously in highly dynamic environments such as those in the Alboran Sea.     

Active oceanic spreading in the northern North Fiji Basin: Results of the NOFI cruise of R/V L'Atalante (newstarmer project)

The South Pandora and the Tripartite Ridges are active spreading centers located in the northern part of the North Fiji Basin. These spreading centers were surveyed over a distance of 750 km during the NOFI cruise of R/V L'Atalante (August–September 1994) which was conducted in the frame of the french-japanese Newstarmer cooperation project. SIMRAD EM12-dual full coverage swath bathymetric and imagery data as well as airgun 6-channel seismic, magnetics and gravity profiles were recorded along and offaxis from 170°40 E to 178° E. Dredging and piston coring were also performed along and off-axis. The axial domain of the South Pandora Ridge is divided into 5 first-order segments characterized by contrasted morphologies. The average width of the active domain is 20 km and corresponds either to bathymetric highs or to deep elongated grabens. The bathymetric highs are volcanic constructions, locally faulted and rifted, which can obstruct totally the axial valley. The grabens show the typical morphology of slow spreading axes, with two steep walls flanking a deep axial valley. Elongated lateral ridges may be present on both sides of the grabens. Numerous volcanoes, up to several kilometers in diameter, occur on both flanks of the South Pandora Ridge. The Tripartite Ridge consists of three main segments showing a sigmoid shape. Major changes in the direction of the active zones are observed at the segment discontinuities. These discontinuities show various geometrical patterns which suggest complex transform relay zones. Preliminary analysis of seismic reflection profiles suggest that the Tripartite Ridge is a very young feature which propagates into an older oceanic domain characterized by a significant sedimentary cover. By contrast, a very thin to absent sedimentary cover is observed about 100 km on both flanks of the South Pandora Ridge active axis. The magnetic anomaly profiles give evidence of long and continuous lineations, parallel to the South Pandora Ridge spreading axis. According to our preliminary interpretation, the spreading rate would have been very low (8 km/m.y. half rate) during the last 7 Ma. The South Pandora and Tripartite Ridges exhibit characteristics typical of active oceanic ridges: (1) a segmented pattern, with segments ranging from 80 to 100 km in length; (2) an axial tectonic and volcanic zone, 10 to 20 km wide; (3) well-organized magnetic lineations, parallel to the active axis; (4) clear signature on the free-air gravity anomaly map. However, no typical transform fault is observed; instead, complex relay zones are separating first-order segments.     

Effects of Soft Corals on Scleractinian Coral Recruitment. II: Allelopathy, Spat Survivorship and Reef Community Structure

Abstract. Two field experiments were performed on the Great Barrier Reef, Australia, at Orpheus Island and Lizard Island, respectively, to investigate the effects of allelopathic soft corals on survivorship and community structure of scleractinian coral spat. Ceramic tiles were placed around the allelopathic soft corals Sinularia flexibilis (Quoy & Gaimard 1833) and Sarcophyton glaucum (Quoy & Gaimard 1833), and controls. One control consisted of settlement plates surrounding a scleractinian coral (non‐allelopathic planktivore); another control had no adult soft or scleractinian coral present. The experimental soft corals affected the recruitment of various taxonomic groups of coral spat differentially, as evidenced by the diversity of coral spat settling in treatments and controls. At Orpheus Island (O.I., n = 1038 spat) and Lizard Island (L.I., n = 7032 spat), there were significant differences between recruitment success of the two dominant coral taxa, Pocilloporidae (O.I., 61.4 %; L.I., 20.5 %) and Acroporidae (O.I., 33.7 %; L.I., 53 %). Settlement plates exposed to Sinularia flexibilis at either site had the lowest proportion of acroporid recruits. Diversity indices (Shannon‐Wiener Indices) varied significantly between treatments at both Orpheus and Lizard Islands. This appears to be due to selective inhibition of acroporid spat by Sinularia flexibilis at both sites. Growth of coral spat was higher on settlement plates in the presence of Sarcophyton at Lizard Island. Settlement of most associated epibiota was generally inhibited under these conditions. Coral spat survivorship was highest in the presence of Sinularia at Orpheus ­Island; at Lizard Island, this was the case with the Sarcophyton treatment. Higher survivorship, and in some cases growth, of coral spat near soft corals was apparently due to reduced competition for space between spat and associated epibiota. This hypothesis is supported by the results of a sister experiment where a coating of Sinularia flexibilis extract on settlement tiles significantly decreased fouling by sessile epibiota. Soft corals have an allelopathic effect on recruitment and early development of scleractinian corals and, consequently, on early coral reef community succession.     

Not only tourism: unravelling suburbanization,second-home expansion and “rural” sprawl in Catalonia,Spain

This study illustrates multifaceted urbanization patterns and processes in a coastal region of Catalonia (northeastern Spain) as a paradigmatic example of the socio-economic transformations typically observed in the northern Mediterranean basin since World War II. By focusing on the expanding tourism industry, second-home expansion, infrastructural development and sprawl around traditional rural centres, the paper assesses the effects of long-term economic, demographic, social and cultural transformations on rural landscapes in Alt Empordà, the so-called “Catalan Tuscany”. The stratification of distinct urbanization waves and the underlying socio-economic processes observed in Alt Empordà reflect population dynamics and settlement morphologies typical of rural districts moving rapidly towards a suburban spatial organization. Recent urban dynamics in Mediterranean rural systems deserve further investigation in order to shed light on latent suburbanization processes involving marginal European regions.     

Variability of the axial morphology and of the gravity structure along the Central Spreading Ridge (North Fiji Basin): evidence for contrasting thermal regimes

The Central Spreading Ridge (CSR) is located in the central part of the North Fiji Basin, a complex back-arc basin created 12 Ma ago between the Pacific and Indo-Australian plates. The 3.5 Ma old CSR is the best developed, for both structure and magmatism, of all the spreading centers identified in the basin, and may be one of the largest spreading systems of the west Pacific back-arc basins. It is more than 800 km long and 50–60 km wide, and has been intensively explored during the French-Japanese STARMER project (1987–1991).The CSR is segmented into three first order segments named, from north to south, N160°, N15° and N-S according to their orientation. This segmentation pattern is similar to that found at mid-ocean ridges. The calculated spreading rate is intermediate and ranges from 83 mm/yr at 20°30 S to 50 mm/yr at 17°S. In addition, there is a change in the axial ridge morphology and gravity structure between the northern and southern sections of the CSR. The axial morphology changes from a deep rift valley (N160° segment), to a dome split by an axial graben (N15° segment) and to a rectangular flat top high (N-S segment). The Mantle Bouguer Anomalies obtained on the northern part of the CSR (N160°/N15° segments) show bull's eye structures associated with mantle upwelling at the 16°50S triple junction and also in the middle of the segments. The Mantle Bouguer Anomalies of the southern part of the ridge (N-S segment) are more homogeneous and consistent with the observed smooth topography associated with axial isostatic compensation.At these intermediate spreading rates the contrast in bathymetry and gravity structure between the segments may reflect differences in heat supply. We suggest that the N160° and N15° segments are cold with respect to the hot N-S segment. We use a non-steady-state thermal model to test this hypothesis. In this model, the accretion is simulated as a nearly steady-state seafloor spreading upon which are superimposed periodic thermal inputs. With the measured spreading rate of 50 mm/yr, a cooling cycle of 200,000 yr develops a thermal state that permits to explain the axial morphology and gravity structure observed on the N160° segment. A spreading rate of 83 mm/yr and a cooling cycle of 120,000 yr would generate the optimal thermal structure to explain the characteristics of the N-S segment. The boundaries between the hot N-S segment and its cold bounding segments are the 18°10 S and 20°30 S propagating rifts. A heat propagation event along the N-S segment at the expense of the adjacent colder failing segments, can explain the sharp changes in the observed morphology and structure between the segments.