Excess protactinium in phosphate nodules from a coastal upwelling zone

Measurements of²³¹Pa/²³⁵U and²³⁰Th/²³⁴U activity ratios have been made for a suite of Quaternary age phosphate nodules from the upwelling zone off Peru and Chile. Many of these samples contain more²³¹Pa than would be predicted based on closed-system²³⁰Th/²³⁴U ages unlike samples from non-upwelling environments which have been shown to have concordant²³¹Pa and²³⁰Th ages. Peru/Chile phosphate nodules apparently pick up²³¹Pa preferentially to²³⁰Th. This is most likely a result of prior fractionation of protactinium and thorium in the open ocean. Highly productive coastal upwelling zones may be added to the growing list of localities where fractionation between thorium and protactinium isotopes has been observed in marine sediments.     

Reductive dechlorination of polychlorinated biphenyls (PCBs) by ultrasound-assisted chemical process (UACP)

The dechlorination of aqueous polychlorinated biphenyls (PCBs) using the ultrasound-assisted chemical process (UACP), which is a combination of ultrasonic irradiation and radical generations using di-tert-butyl peroxide as a radical initiator and ferrous ion as a catalyst at moderate temperature in alkaline 2-propanol, was demonstrated with a high reduction of PCBs. A commercial PCB-containing compound, Aroclor 1260, was also decomposed with the removal efficiency of 97 % achieved within 3 h of UACP. The gas chromatograph was used as a quantitative method to measure the decomposition rate of PCBs. The competitive elimination among the ortho (2-position), meta (3-position), and para (4-position) chlorine atoms of PCB was also identified.     

Seismically induced changes in groundwater levels and temperatures following the ML5.8 (ML5.1) Gyeongju earthquake in South Korea

Hydrogeological responses to earthquakes such as changes in groundwater level, temperature, and chemistry, have been observed for several decades. This study examines behavior associated with M_L 5.8 and M_L 5.1 earthquakes that occurred on 12 September 2016 near Gyeongju, a city located on the southeast coast of the Korean peninsula. The M_L 5.8 event stands as the largest recorded earthquake in South Korea since the advent of modern recording systems. There was considerable damage associated with the earthquakes and many aftershocks. Records from monitoring wells located about 135 km west of the epicenter displayed various patterns of change in both water level and temperature. There were transient-type, step-like-type (up and down), and persistent-type (rise and fall) changes in water levels. The water temperature changes were of transient, shift-change, and tendency-change types. Transient changes in the groundwater level and temperature were particularly well developed in monitoring wells installed along a major boundary fault that bisected the study area. These changes were interpreted as representing an aquifer system deformed by seismic waves. The various patterns in groundwater level and temperature, therefore, suggested that seismic waves impacted the fractured units through the reactivation of fractures, joints, and microcracks, which resulted from a pulse in fluid pressure. This study points to the value of long-term monitoring efforts, which in this case were able to provide detailed information needed to manage the groundwater resources in areas potentially affected by further earthquakes.

     

Dynamic freshwater–saline water interaction in the coastal zone of Jeju Island, South Korea

Freshwater–saline water interactions were evaluated in a coastal region influenced by external forces including tidal fluctuations and seasonal rainfall variations. Five different coastal zones were considered on Jeju Island, South Korea, and electrical conductivity (EC) profiles from the monitoring wells were examined to identify the configuration of the freshwater–saline water interface. There appeared to be discrepancies among EC profiles measured at different points in time. To analyze the dynamic behavior of freshwater–saline water interactions, groundwater level measurements and multi-depth EC and temperature probes were used to obtain time-series data; the data showed that water level, EC and temperature were influenced by both tidal fluctuations and heavy rainfall. The effects of oceanic tide on EC and temperature differed with depth due to hydraulic properties of geologic formations. A spectral filter was used to eliminate the effects of tidal forces and provide information on the influence of heavy rainfall on water level, EC and temperature. Heavy rainfall events caused different patterns and degrees of variation in EC and temperature with depth. The time-series data of EC and temperature in the subsurface at various depths enable greater understanding of the interaction processes between fresh and saline water.     

Direct measurements of cosmic-ray energy: The kinematical method revisited

At an energy scale of 10¹⁵-10¹⁶ eV, a direct measurement of the energy carried by charged cosmic radiation is a real challenge for balloon-borne and space based instruments. As a consequence of the very small fluxes, a large collecting power is required which is difficult to accommodate with weight-limited instruments equipped with calorimeters. A different approach has been proposed that might allow for a sizeable reduction of the instrument mass. It is based on a kinematical technique, whereby the energy of the cosmic-ray is estimated on the basis of the measured angular distribution of the secondaries resulting from its interaction in a target. In this paper, we review the basic principles of the method and study the properties of different energy estimators by means of a full simulation of the interaction of the incident particle in a conceptual instrument. We also discuss the intrinsic limitations of the method and investigate its possible application to direct measurements of the cosmic-ray spectrum in the region of the ‘knee’.     

Comparison of two physical sensor models for satellite images: Position–Rotation model and Orbit–Attitude model

The main objective of this paper is to compare two types of physical sensor models of linear pushbroom satellite images: one that uses position and rotation angles as model parameters and one that uses orbit and attitude angles as model parameters. Comparison is carried out by two accuracy measures: the accuracy of bundle adjustments and the accuracy of estimating exterior orientation parameters. The first measure has been used widely to indicate the mapping accuracy of sensor models. It is argued that the second measure is also important for certain applications. The two types were implemented with different sets of unknown parameters and tested with two KOMPSAT-1 Earth Observing Camera (EOC) scenes and GPS-derived control points. In terms of the first measure the two models produced similar results whereas in terms of the second measure the one based on orbit and attitude outperformed the other. It seems better to use this model if one wishes to retrieve satellite orbit or attitude through bundle adjustments.     

Methane-derived authigenic carbonates from the Ulleung basin sediments,East Sea of Korea

Authigenic carbonates were sampled in methane-enriched piston core sediments collected from gas venting sites on the western continental slope of the Ulleung Basin, East Sea of Korea. Multidisciplinary investigations on these carbonates, including the scanning electronic microscope (SEM) observations and mineralogical-geochemical compositions, were carried out to identify the carbon and oxygen sources and the forming mechanism of these carbonates. The authigenic carbonates from the study area correspond to semi-consolidated, compact concretions or nodules ranging from 2 to 9 cm in size. X-ray diffraction and electron microprobe analyses showed that most of the sampled carbonate concretions were composed of almost purely authigenic high-Mg calcite (10.7–14.3 mol% MgCO₃). Characteristically, microbial structures such as filaments and rods, which were probably associated with the authigenic minerals, were abundantly observed within the carbonate matrix. The carbonates were strongly depleted in δ¹³C (−33.85‰ to −39.53‰ Peedee Belemnite (PDB)) and were enriched in δ¹⁸O (5.16–5.60‰ PDB), indicating that the primary source of carbon is mainly derived from the anaerobic oxidation of methane. Such methane probably originated from the destabilization of the underlying gas hydrates as strongly supporting from the enriched ¹⁸O levels. Furthermore, the strongly depleted δ¹³C values (−60.7‰ to −61.6‰ PDB) of the sediment void gases demonstrate that the majority of the gas venting at the Ulleung Basin is microbial methane by CO₂ reduction. This study provides another example for the formation mechanism of methane-derived authigenic carbonates associated with gas-hydrate decomposition in gas-seeping pockmark environments.     

Endogenous technological change and pollution abatement

Nonpoint source pollution control is a more complicated process than traditional analysis suggests. Whether a new pollution abatement technology is developed exogenously or endogenously and the per unit reduction in the rate at which a pollutant associated with the use of a factor of production needed to produce an agricultural commodity due to this technology enters the environment are critical factors in the determination of the effects of agricultural production on the pollutant stock. These are the issues addressed here. The optimal current period research and development expenditures on an endogenously induced abatement technology associated with the use of a factor of production giving rise to environmental externalities are shown to be a function of, among other things, the cumulation of all research and development expenditures, the probability of an abatement technology being developed, the level of use of the factor of production, the unit pollution tax on the factor, the rate of time preference (discount rate), the rate at which the pollutant associated with the factor enters the environment, the rate of discharge of the pollutant stock, and so forth. Finally, the analysis demonstrates that a reduction in pollution by the adoption of an abatement technology may lead to an increase in the pollutant stock as a result of endogenous technological change associated with the pollution abatement. When the rate of pollution reduction is greater than a threshold, however, the adoption of an endogenously determined abatement technology will unequivocally lead to a reduction in the pollutant stock.The views expressed are those of the authors and do not necessarily represent the policies of the US Department of Agriculture or the views of other US Department of Agriculture staff members.     

Energy solution or future pollution? Applying an energy justice perspective to coal seam gas in New South Wales

ABSTRACT

The emergence of an unconventional extractive industry of coal seam gas (CSG) in New South Wales, Australia has caused a range of social tensions. Although the industry has generally received strong support from state-level governments across Australia, an eclectic social movement has arisen in opposition. Critical questions of justice have emerged in these debates about CSG, particularly about the ‘winners' and ‘losers' that would emerge should large-scale CSG extraction be introduced into New South Wales. However, the question of justice in relation to CSG extraction is not altogether so simple. Actors on all sides of CSG development have mobilised the language of justice in their claims about this energy source in sophisticated ways and at different scales. In this paper, we draw upon ‘energy justice’ scholarship to tease out different energy justice dimensions of the CSG debate in New South Wales. We show how there are significant issues that will likely intensify regarding the recognition of different forms of knowledge, the access citizens have to forms of decision-making, and the risks that span geographic and temporal scales. We argue that it is vital to appreciate the significant and interrelated injustices faced by those challenging the industry.     

Metamorphic K-Feldspar in Low-grade Metasediments from the Ogcheon Metamorphic Belt in South Korea

Metamorphic K-feldspar was found in the low-grade pelitic rocks from the Ogcheon metamorphic belt in South Korea. It occurs as extremely fine-grained crystals (5-15 mm in width and 15-25 mm in length) closely associated with fine-grained muscovite and biotite. Their micro structural relations by X-ray mapping analyses using an electron-probe microanalyzer strongly suggest that K-feldspar has grown directly from the matrix phases as a stable phase coexisting with muscovite and biotite during the Ogcheon metamorphism. The phengite component in muscovite indicates about 4.2 kbar at 400°C, suggesting intermediate P/T type of metamorphism. Muscovite separates of two size fractions, 2-4 and 4-8 mm, give K-Ar ages of 153.4±3.3 and 156.7±3.4 Ma, respectively. The biotite separate is 156.5±3.3 Ma in age. Coarse-grained biotite crystal (ca. 0.5 mm) often occurs and it was analyzed by ⁴⁰Ar/³⁹Ar method using a laser probe step heating technique. It gives a plateau age of 158.2±0.5 Ma that is the same as the K-Ar muscovite and biotite ages. These data, including the previous works, suggest that intermediate P/T type of Ogcheon metamorphic belt exhumed in Middle Jurassic with the dextral strike-slip fault movement.