Radiation-induced defects in quartz. III. Single-crystal EPR,ENDOR and ESEEM study of a peroxy radical

The X- and W-band single-crystal electron paramagnetic resonance spectra of an electron-irradiated natural quartz permit quantitative analysis of a ²⁹Si hyperfine structure (A ~12.6 MHz) and an ²⁷Al hyperfine structure (A ≤ 0.8 MHz) for a previously reported hole-like center. The ²⁹Si hyperfine structure arises from interaction with two equivalent Si atoms and is characterized by the direction of the unique A axis close to a Si–O bond direction. The ²⁷Al hyperfine structure, confirmed by pulsed electron nuclear double resonance and electron spin echo envelope modulation spectra, is characterized by the unique A axis approximately along a twofold symmetry axis. These ²⁹Si and ²⁷Al hyperfine data, together with published theoretical results on peroxy radicals in SiO₂ as well as our own density functional theory (DFT) calculations on model peroxy centers, suggest this hole-like center to have the unpaired spin on a pair of oxygen atoms linked to two symmetrically equivalent Si atoms and a substitutional Al³⁺ ion across the c-axis channel, a first peroxy radical in quartz. The nuclear quadrupole matrix P also suggests that the Al³⁺ ion corresponds closely to the diamagnetic precursor to the [AlO₄]⁰ center. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

The influence of topography and land use on water quality of Xiangxi River in Three Gorges Reservoir region

A self-organizing map (SOM) was used to cluster the water quality data of Xiangxi River in the Three Gorges Reservoir region. The results showed that 81 sampling sites could be divided into several groups representing different land use types. The forest dominated region had low concentrations of most nutrient variables except COD, whereas the agricultural region had high concentrations of NO₃N, TN, Alkalinity, and Hardness. The sites downstream of an urban area were high in NH₃N, NO₂N, PO₄P and TP. Redundancy analysis was used to identify the individual effects of topography and land use on river water quality. The results revealed that the watershed factors accounted for 61.7% variations of water quality in the Xiangxi River. Specifically, topographical characteristics explained 26.0% variations of water quality, land use explained 10.2%, and topography and land use together explained 25.5%. More than 50% of the variation in most water quality variables was explained by watershed characteristics. However, water quality variables which are strongly influenced by urban and industrial point source pollution (NH₃N, NO₂N, PO₄P and TP) were not as well correlated with watershed characteristics.     

New observations on Rajahmundry Traps of the Krishna-Godavari Basin

The Rajahmundry Traps of the Krishna Godavari Basin (K-G Basin) consist of three distinct basalt flows interbedded with two intertrappean sedimentary horizons, which in turn are underlain by the late Cretaceous fossiliferous limestone bed (infratrappean) and overlain by the Cenozoic Rajahmundry Formation (conglomerate/sandstone). Among the three, the lower flow is characterized by the presence of the physical volcanological features such as rootless cones, tumuli and dyke like forms along with single to multitier columnar and radial jointing. The middle and upper flows are simple, massive and vesicular and exhibit spheroidal weathering. Physical volcanological features and lithological attributes indicate that the lower flow was formed by an explosive volcanic activity in hydrous environment, followed by sub aerial eruption to form the middle and upper flows. The fossiliferous limestone bed is a representative horizon for the K-T boundary mass extinction caused due to intense volcanism. Intertrappean sediments exhibit weathered soil profiles (palaeosols) with limestone beds denoting a distinct time gap during various phases of lava eruption. Evaluation of the palaeogeographic scenario of the Krishna and Godavari Rivers does not provide any evidence for the existence of Cretaceous palaeovalley which would have provided pathway for lava transportation from the Deccan volcanic province of western India to the K-G Basin situated along the east coast. The present study opens up an alternative approach to explain the origin of basalt flows at Rajahmundry. In all probability the lavas could be intrabasinal. NW-SE and NESW faults or their intersection zones are probable pathways for lava eruption in the K-G Basin.     

Atmospheric tracer monitoring and surface plume development at the ZERT pilot test in Bozeman,Montana, USA

A controlled release of CO₂ was conducted at a field site in Bozeman, Montana, USA in July of 2008 in a multi-laboratory study of near surface transport and detection technologies. The development of a subsurface CO₂ plume near the middle packer section of the horizontal release was studied using soil-gas and surface flux measurements of CO₂. A perfluorocarbon tracer was added to the CO₂ released from this section of the horizontal well, and the development of atmospheric plumes of the tracer was studied under various meteorological conditions using horizontal and vertical grids of monitors containing sorbent material to collect the tracer. This study demonstrated the feasibility of using remote sensing for the ultra low level detection of atmospheric plumes of tracers as means to monitor the near surface leakage of sequestered CO₂.     

Driftwood deposition from debris flows at slit-check dams and fans

Experience shows that debris flows containing large woody debris (driftwood) can be more damaging than debris flows without driftwood. In this study, the deposition process of debris flows carrying driftwood was investigated using numerical simulations and flume experiments. Debris-flow trapping due to driftwood jamming in a slit-check dam was also investigated. A numerical model was developed with an interacting combination of Eulerian expression of the debris flow and Lagrangian expression of the driftwood, in which the fluctuating coordinates and rotation of the driftwood were treated stochastically. The calculated shapes and thicknesses of a debris-flow fan and the positions and orientations of the deposited driftwood on a debris-flow fan were consistent with experimental flume results. The jamming of driftwood in a slit-check dam was evaluated based on geometry and probability. The simulated results of outflow discharge and the proportion of driftwood passed through the slit-check dam also agreed with the experimental results.     

An innovative micro-scale approach for vulnerability and flood risk assessment with the application to property-level protection adoptions

Economic damage assessment for flood risk estimation is established in many countries, but attentions have been focused on macro- or meso-scale approaches and less on micro-scale approaches. Whilst the macro- or meso-scale approaches of flood damage assessment are suitable for regional- or national-oriented studies, micro-scale approaches are more suitable for cost–benefit analysis of engineered protection measures. Furthermore, there remains lack of systematic and automated approaches to estimate economic flood damage for multiple flood scenarios for the purpose of flood risk assessment. Studies on flood risk have also been driven by the assumption of stationary characteristic of flood hazard, hence the stationary-oriented vulnerability assessment. This study proposes a novel approach to assess vulnerability and flood risk and accounts for adaptability of the approach to nonstationary conditions of flood hazard. The approach is innovative in which an automated concurrent estimation of economic flood damage for a range of flood events on the basis of a micro-scale flood risk assessment is made possible. It accounts for the heterogeneous distribution of residential buildings of a community exposed to flood hazard. The feasibility of the methodology was tested using real historical flow records and spatial information of Teddington, London. Vulnerability curves and residual risk associated with a number of alternative extents of property-level protection adoptions are estimated by the application of the proposed methodology. It is found that the methodology has the capacity to provide valuable information on vulnerability and flood risk that can be integrated in a practical decision-making process for a reliable cost–benefit analysis of flood risk reduction options.     

Geochemistry and geochronology of Late Jurassic and Early Cretaceous intrusions related to some Au (Sb) deposits in southern Anhui: a case study and review

Some Au deposits in southern Anhui Province have recently been found to be closely associated with Late Mesozoic intrusions. Typical examples include the Huashan Au (Sb) deposit and Au deposits at Zhaojialing, Wuxi, and Liaojia. In order to understand the mechanisms that led the formation of these Au deposits, we make detailed reviews on the geological characteristics of these Au deposits. Specifically, we present new LA-ICP-MS zircon U–Pb dating, along with elemental and Hf isotopic data from the Huashan Au (Sb) deposit. Our data suggests that the Huashan ore-related intrusions were emplaced during the Late Jurassic and Early Cretaceous periods (144–148 Ma). They are characterized by arc-magma features and high oxygen fugacity and are rich in inherited zircons. Zircon U–Pb ages and Lu–Hf isotopes from intrusions suggest that Proterozoic juvenile lithosphere is the main source of these intrusions. The regional geological history implies that lithosphere beneath southern Anhui was produced during a Proterozoic subduction and was fertilized with Au (Cu) in the process. Integrated with the results of previous studies, we inferred that Late Mesozoic intrusions formed by the remelting of the lithosphere could provide the metal endowment for the Au-rich deposits in southern Anhui.     

Isolation of <Emphasis Type="Italic">Bacillus cereus</Emphasis> from botanical soil and subsequent biodegradation of waste engine oil

Waste engine oil causes a vital environmental pollution when it spill during change and transportation and products of waste engine oil causes lethal effects to the living systems. Thus, abiotic and biotic approaches are being extensively used for removal of waste engine oil pollution. Therefore in present study, waste engine oil degradation was accomplished by a new bacterial culture, isolated from the soil by an enrichment technique. Morphological, biochemical and gene sequence analysis revealed that isolate was Bacillus cereus. Subsequently, biodegradation potential of B. cereus for waste engine oil was studied. Experimental variables, such as pH, substrate concentration, inoculum size, temperature and time on the biodegradation, were checked in mineral salt medium. The biodegradation efficiency of B. cereus was determined by gravimetry, UV–visible spectrophotometry and gas chromatography. In addition, waste engine oil was also characterized by GC–MS and FTIR for its major constituents, which showed total 38 components in waste engine oil, including hopanes, benzopyrene, long-chain aliphatic hydrocarbons, dibenzothiophenes, biphenyl and their derivatives. Results of successive biodegradation indicated that B. cereus was capable to degrade 1% of waste engine oil with 98.6% degradation potential at pH 7 within 20 days. Hence, B. cereus presents an innovative tool for removing the engine oil from the contaminated area.