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991.
Cyanoacetylene (HC3N) and diacetylene (C4H2) play an important role in the photochemistry of Titan's atmosphere, in part because of their strong absorption between 110 and 180 nm. Accurate photoabsorption cross-sections at temperatures representative of Titan's atmosphere are required to interprete Cassini observations and to calculate photolysis rates used in photochemical models. Using synchrotron radiation as a tunable vacuum ultraviolet (VUV) light source, we have measured absolute photoabsorption cross-sections of C4H2 and HC3N with a spectral resolution of 0.05 nm in the region between 80 and 225 nm and at different temperatures between 173 and 295 K. The measured cross-sections are used to model transmission spectra of Titan atmosphere in the VUV. 相似文献
992.
We derive a time series of two-dimensional velocity fields for a flare region on 1992 December 16, based on the asymmetries of the H line. The H spectra were obtained by an imaging spectrograph at the Solar Tower Telescope of Nanjing University. Four sites with evident chromospheric downflows are found to appear and decay consecutively in the studied region. The value of maximum velocities is 30–40 km s–1 and the lifetime of downflows is 2–3 min at these sites. It is also shown that the asymmetries only exist at the line wing, while the line center has nearly no shifts for this flare. Finally, we make a discussion on the characteristics of the velocity distribution and its correlations with the intensity distribution, as well as with the hard X-ray emission. 相似文献
993.
994.
Heather K. Gastineau‐Lyons Harry Y. McSween Michael J. Gaffey 《Meteoritics & planetary science》2002,37(1):75-89
Abstract— Modal mineralogies of individual, equilibrated (petrologic type 4–6 L and LL chondrites have been measured using an electron microprobe mapping technique, and the chemical compositions of coexisting silicate minerals have been analyzed. Progressive changes in the relative abundances and in the molar Fe/Mn and Fe/Mg ratios of olivine, low‐Ca pyroxene, and diopside occur with increasing metamorphic grade. Variations in olivine/low‐Ca pyroxene ratios (Ol/Px) and in metal abundances and compositions with petrologic type support the hypothesis that oxidation of metallic iron accompanied thermal metamorphism in ordinary chondrites. Modal Ol/Px ratios are systematically lower than normative Ol/Px ratios for the same meteorites, suggesting that the commonly used C.I.P.W. norm calculation procedure may not adequately estimate silicate mineral abundances in reduced chondrites. Ol/Px ratios calculated from visible and near‐infrared (VISNIR) reflectance spectra of the same meteorites are not in agreement with other Ol/Px determinations, possibly because of spectral complexities arising from other minerals in chondrites. Characteristic features in VISNIR spectra are sensitive to the proportions and compositions of olivine and pyroxenes, the minerals most affected by oxidative metamorphism. This work may allow spectral calibration for the determination of mineralogy and petrologic type, and thus may be useful for spectroscopic studies of asteroids. 相似文献
995.
This paper reports the study concerning the latitudinal dispalacement of the auroral oval as a function of the northward orientation of the Bz-component IMF and the relation between southward Bz and the auroral dynamics in the night sector. 相似文献
996.
G. Hillers P. M. Mai Y. Ben-Zion J.-P. Ampuero 《Geophysical Journal International》2007,169(2):515-533
We perform a systematic parameter space study of the seismic response of a large fault with different levels of heterogeneity, using a 3-D elastic framework within the continuum limit. The fault is governed by rate-and-state friction and simulations are performed for model realizations with frictional and large scale properties characterized by different ranges of size scales. We use a number of seismicity and stress functions to characterize different types of seismic responses and test the correlation between hypocenter locations and the employed distributions of model parameters. The simulated hypocenters are found to correlate significantly with small L values of the rate-and-state friction. The final sizes of earthquakes are correlated with physical properties at their nucleation sites. The obtained stacked scaling relations are overall self-similar and have good correspondence with properties of natural earthquakes. 相似文献
997.
Rocky desertification and its causes in karst areas: a case study in Yongshun County,Hunan Province,China 总被引:9,自引:0,他引:9
Y.?J.?Xiong G.?Y.?QiuEmail author D.?K.?Mo H.?Lin H.?Sun Q.?X.?Wang S.?H.?Zhao J.?Yin 《Environmental Geology》2009,57(7):1481-1488
Rocky desertification, a process of land degradation characterized by soil erosion and bedrock exposure, is one of the most
serious land degradation problems in karst areas, and is regarded as an obstacle to local sustainable development. It is well
known that human activities can accelerate rocky desertification; however, the effects of climate change on rocky desertification
in karst areas are still unclear. This study focused on the effects of temperature and precipitation changes and human activities
on rocky desertification in karst areas to determine the impacts of climate change and human disturbances on rocky desertification.
Areas of different level of rocky desertification were obtained from Landsat TM (1987) and Landsat ETM+ (2000) images. The
results show that, although the total desertification area increased by only 1.27% between 1987 and 2000, 17.73% of the slightly
desertified land had degraded to a moderate or intense level, 2.01 and 15.71%, respectively. Meanwhile, between 1987 and 2000,
the air temperature increased by 0.7°C, and precipitation increased by 170 mm. Statistical results indicate that the increase
in precipitation was caused by heavy rainfall. In addition, under the interactive influences of heavy rainfall and temperature,
the average karst dissolution rate was about 87 m3 km−2 a−1 during the 14 years in the study area. Further analysis indicated that rocky desertification was positively related with
the increase in temperature and precipitation and especially with the heavy rainfall events. Climate change accelerated rocky
desertification in the karst areas.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
998.
999.
M. Koch-Müller P. Dera Y. Fei H. Hellwig Z. Liu J. Van Orman R. Wirth 《Physics and Chemistry of Minerals》2005,32(5-6):349-361
We synthesized superhydrous phase B (shy-B) at 22 GPa and two different temperatures: 1200°C (LT) and 1400°C (HT) using a
multi-anvil apparatus. The samples were investigated by transmission electron microscopy (TEM), single crystal X-ray diffraction,
Raman and IR spectroscopy. The IR spectra were collected on polycrystalline thin-films and single crystals using synchrotron
radiation, as well as a conventional IR source at ambient conditions and in situ at various pressures (up to 15 GPa) and temperatures
(down to −180°C). Our studies show that shy-B exists in two polymorphic forms. As expected from crystal chemistry, the LT
polymorph crystallizes in a lower symmetry space group (Pnn2), whereas the HT polymorph assumes a higher symmetry space group (Pnnm). TEM shows that both modifications consist of nearly perfect crystals with almost no lattice defects or inclusions of additional
phases. IR spectra taken on polycrystalline thin films exhibit just one symmetric OH band and 29 lattice modes for the HT
polymorph in contrast to two intense but asymmetric OH stretching bands and at least 48 lattice modes for the LT sample. The
IR spectra differ not only in the number of bands, but also in the response of the bands to changes in pressure. The pressure
derivatives for the IR bands are higher for the HT polymorph indicating that the high symmetry form is more compressible than
the low symmetry form. Polarized, low-temperature single-crystal IR spectra indicate that in the LT-polymorph extensive ordering
occurs not only at the Mg sites but also at the hydrogen sites. 相似文献
1000.
A thermal ionisation mass spectrometric technique enabled the abundance of Zn in geological and biological reference materials and water samples to be measured by double spiking isotope dilution mass spectrometry enriched in the 67Zn and 70Zn isotopes. In the past, thermal ionisation mass spectrometry proved to be difficult for low-level zinc isotopic measurements. The size of Zn samples used for isotopic determination, in particular the biological RMs, represents an important breakthrough. These results represent the most accurate and precise concentrations measured for Zn in these samples. The maximum fractional uncertainty was that for TILL-3 (2%), while the minimum fractional uncertainty was 0.7% for both BCR-1 and W-2. The inhomogeneity of Zn in HISS-1 was revealed while other reference materials appeared homogeneous at the 95% confidence uncertainty. The certified concentration of Zn in HISS-1 and IMEP-19 by their producers are 28% and 3.8% higher than the values measured in this work. These are the first Zn concentration measurements in these materials by the isotope dilution-TIMS technique, except for BCR-1, NIES No 9 and IMEP-19. Reducing the blank enabled accurate measurement in water at the ng g-1 level demonstrating the applicability of the technique for low-level Zn samples. 相似文献