In the processes of discrimination between oil-cracked gases and kerogen-cracked gases, Behar and Pinzgofer et al.’s results were adopted in the former researches, in which the ratio of C2/C3 is basically a constant while the ratio of C1/C2 gradually increases in the course of primary cracking of kerogen. Otherwise in the course of secondary cracking of oil, the ratio of C2/C3 increases rapidly while C1/C2 keeps relatively stable. Our study on analogue experiment shows that, whether it is oil or kerogen, in its process of gas generating by cracking, the ratios of C2/C3, C1/C2 or C1/C3 will all be increased with the growth of thermal conditions. In comparison, the ratio of C2/C3, which is affected by genetic type to some comparatively less extent, mainly responds to the maturity of gases, while the value of C2/C3 is about 2, and that of C2/iC4 is about 10, and the corresponding value of Ro is about 1.5%–1.6%. The influence of gas source on C2/C3 is less than that of gas maturity, otherwise C1/C2 (or C1/C3) is obviously affected by cracking matrices. The ratios of C1/C2, C1/C3 of oil-cracked gases are less than that of kerogen-cracked gases, under the condition that the ratios of C2/C3 are similar in value, so are the value of dryness indexes. There exists wide diffidence between this view and the former discrimination method in theory. The analysis of the spot sample indicates that we can apply the above basic view to dealing efficiently with the problem of the discrimination between oil-cracked gas and kerogen-cracked gas.
Phase equilibria for the NaCl/KCl-PEG400-H_2 O aqueous ternary systems at 298 K were studied using an isothermal dissolution method. In addition,the densities and refractive indices were determined. The corresponding phase diagrams,as well as the density vs. composition and refractive index vs.composition diagrams,were plotted. Results revealed that over the entire PEG400 composition range studied at 298 K only 1 liquid phase was obtained,without the formation of a biphase region. The phase diagrams of these 2 systems consist of 1 homogeneous area with unsaturated liquid( L) and an equilibrium area containing the solid phase of NaCl/KCl and the saturated liquid phase( S + L). The solubility of NaCl/KCl decreases with the addition of PEG400 at 298 K. 相似文献
The present study numerically investigates the characteristics of three-dimensional turbulent flow in a wavy channel. For the purpose of a careful observation of the effect of the wave amplitude on the turbulent flow, numerical simulations are performed at a various range of the wave amplitude to wavelength ratio (0.01?α/λ?0.05), where the wavelength is fixed with the same value of the mean channel height (H). The immersed boundary method is used to handle the wavy surface in a rectangular grid system, using the finite volume method. The Reynolds number (Re=UbH/ν) based on the bulk velocity (Ub) is fixed at 6760. The present computational results for a wavy surface are well compared with those of references. When α/λ=0.02, the small recirculating flow occurs near the trough at the instant, but the mean reverse flow is not observed. In the mean flow field, the reverse flow appears from α/λ=0.03 among the wave amplitude considered in this study. The domain of the mean reverse flow defined by the locations of separation and reattachment depends strongly on the wave amplitude. The pressure drag coefficient augments with increasing the wave amplitude. The friction drag coefficient shows the increase and decrease behavior according to the wave amplitude. The quantitative information about the flow variables such as the distribution of pressure and shear stress on the wavy surface is highlighted. 相似文献