Combined Sr,Nd, Pb and Li isotope geochemistry of alkaline lavas from northern James Ross Island (Antarctic Peninsula) and implications for back-arc magma formation

We present a comprehensive geochemical data set for a suite of back-arc alkaline volcanic rocks from James Ross Island Volcanic Group (JRIVG), Antarctic Peninsula. The elemental and isotopic (Sr, Nd, Pb and Li) composition of these Cenozoic basalts emplaced east of the Antarctic Peninsula is different from the compositions of the fore-arc alkaline volcanic rocks in Southern Shetlands and nearby Bransfield Strait. The variability in elemental and isotopic composition is not consistent with the JRIVG derivation from a single mantle source but rather it suggests that the magma was mainly derived from a depleted mantle with subordinate OIB-like enriched mantle component (EM II). The isotopic data are consistent with mantle melting during extension and possible roll-back of the subducted lithosphere of the Antarctic plate. Magma contamination by Triassic–Early Tertiary clastic sediments deposited in the back-arc basin was only localized and affected Li isotopic composition in two of the samples, while most of the basalts show very little variation in δ⁷Li values, as anticipated for “mantle-driven” Li isotopic composition. These variations are difficult to resolve with radiogenic isotope systematics but Li isotopes may prove sensitive in tracking complex geochemical processes acting through the oceanic crust pile, including hydrothermal leaching and seawater equilibration.     

Modelling climate change impacts on maize growth and development in the Czech Republic

Summary The crop growth model CERES-Maize is used to estimate the direct (through enhanced fertilisation effect of ambient CO₂) and indirect (through changed climate conditions) effects of increased concentration of atmospheric CO₂ on maize yields. The analysis is based on multi-year crop model simulations run with daily weather series obtained alternatively by a direct modification of observed weather series and by a stochastic weather generator. The crop model is run in two settings: stressed yields are simulated in water and nutrient limited conditions, potential yields in water and nutrient unlimited conditions. The climate change scenario was constructed using the output from the ECHAM3/T42 model (temperature), regression relationships between temperature and solar radiation, and an expert judgement (precipitation). Results: (i) After omitting the two most extreme misfits, the standard error between the observed and modelled yields is 11%. (ii) The direct effect of doubled CO₂: The stressed yields would increase by 36–41% in the present climate and by 61–66% in the 2 × CO₂ climate. The potential yields would increase only by 9–10% as the improved water use efficiency does not apply. (iii) The indirect effect of doubled CO₂: The stressed yields would decrease by 27–29% (14–16%) at present (doubled) ambient CO₂ concentration. The increased temperature shortens the phenological phases and does not allow for the optimal development of the crop. The simultaneous decrease of precipitation and increase of temperature and solar radiation deepen the water stress, thereby reducing the yields. The reduction of the potential yields is significantly smaller as the effect of the increased water stress does not apply. (iv) If both direct and indirect effects of doubled CO₂ are considered, the stressed yields should increase by 17–18%, and the potential yields by 5–14%. (v) The decrease of the stressed yields due to the indirect effect may be reduced by applying earlier planting dates. Received March 9, 2001 Revised September 25, 2001     

Detecting,sourcing, and age-dating dredged sediments on the open shelf,southern California,using dead mollusk shells

Molluscan shell debris is an under-exploited means of detecting, sourcing, and age-dating dredged sediments in open-shelf settings. Backscatter features on the Southern California shelf are suggestive of dredged sediment hauled from San Diego Bay but deposited significantly inshore of the EPA-designated ocean disposal site. We find that 36% of all identifiable bivalve shells > 2 mm (44% of shells > 4 mm) in sediment samples from this 'short dump' area are from species known to live exclusively in the Bay; such shells are absent at reference sites of comparable water depth, indicating that their presence in the short-dump area signals non-compliant disposal rather than natural offshore transport or sea level rise. These sediments lack the shells of species that invaded California bays in the 1970s, suggesting that disposal preceded federal regulations. This inexpensive, low-tech method, with its protocol for rejecting alternative hypotheses, will be easy to adapt in other settings.     

Palaeo- and rock-magnetic investigations across Jurassic-Cretaceous boundary at St Bertrand’s Spring,Drôme,France: applications to magnetostratigraphy

Palaeo- and rock-magnetic investigations of the St Bertrand’s Spring (Le Ravin de Font de St Bertrand) locality in France were carried out in order to contribute to, and improve, the stratigraphy of the Jurassic-Cretaceous boundary interval. Magnetic susceptibility shows slightly diamagnetic behaviour in the lowermost part of the profile and an increase (paramagnetic) towards its middle and upper parts. Rock-magnetic measurements throughout the section show magnetite as the main magnetic fraction, together with traces of hematite. Additionally, thermal demagnetization indicates the presence of goethite. Our magnetostratigraphy indicates three normal/reversed polarity sequences; possibly encompassing the magnetozones M19r to the M17n. This suggests that the St Bertrand section straddles the Tithonian/Berriasian boundary and reaches the middle Berriasian sensu lato.     

Low-field variation of magnetic susceptibility measured by the KLY-4S Kappabridge and KLF-4A magnetic susceptibility meter: Accuracy and interpretational programme

The KLY-4S Kappabridge and KLF-4A Magnetic Susceptibility Meter enable automated measurement of susceptibility variation with field in the ranges of 2–450 A/m and 5–300 A/m (in effective values), respectively. Unfortunately, the measurement accuracy decreases with decreasing field and it is not easy to decide whether the susceptibility variation at the lowest fields is natural phenomenon or results from measuring errors. To overcome this problem, the accuracies of both the above instruments were investigated experimentally using artificial specimens (mixture of pure magnetite and plaster of Paris) with variable susceptibilities ranging from 1 × 10⁻⁵ to 5 × 10⁻². The complete curve of the field variation of susceptibility of each specimen was measured 10 times and the relative error was calculated for each field. In the KLY-4S Kappabridge, in specimens with susceptibilities higher than 100 × 10⁻⁶, the relative errors are lower than 3% in all fields and lower than 1% in the fields stronger than 10 A/m. In the KLF-4A Magnetic Susceptibility Meter, in relatively strongly magnetic specimens with susceptibilities 5 × 10⁻⁴ to 5 × 10⁻², the relative error is less than 1.5% in the entire field range. While the former instrument is convenient for investigating almost all rock types, the latter instrument is convenient for measuring moderately and strongly magnetic specimens. To facilitate work with field variation of susceptibility curves, showing variable accuracies with field, the programme FieldVar was written. One of its options is plotting the measured data with corresponding field-variable error bars. In this way, a tool is offered for interpreting such susceptibility changes that are sound and reasonable from the point of view of measuring accuracy.     

An analytical migration method for crustal wide angle reflections

Summary An analytical migration method is developed for inverting wide angle seismic reflection travel time data with proper migration. In this method the concept of effective velocity (V _eff ) in the vertically inhomogeneous earth has been used, which takes into account the refraction effect. It is shown that the migration process in this case becomes extremely rapid as curved ray paths are replaced by equivalent straight paths. A post migration sliding correction is found to be necessary, which arises due to the non-collinearity of the recording point, reflection point and the image point in the equivalent straight path geometry for dipping reflectors. Calculations for some representative dips show that, for the depths and recording ranges of interest in DSS, the vertical component of the sliding correction is negligible compared to the horizontal component. However, even the horizontal component is not significant for reflectors with gentle dips. The effect of certain simplifying assumptions in the estimation of V _eff is shown to be within the error limits of velocity determination. A computer programme package has been written for carrying out the migration. The method yields more accurate results in various theoretical and field cases than the conventional graphical wave front methods which are at present widely used for crustal reflection work.     

Hydrogeochemistry of a deep gas-storage cavern,Czech Republic

Groundwater was occasionally found during the construction of a deep gas-storage cavern at approximately 1 km below land surface near Pribram, Czech Republic. The individual groundwater seeps, with a discharge not exceeding 0.01 l/s and T?=?23°C, were usually a strongly alkali natural solution with maximum pH values of 9.9 and TDS concentrations from 0.2 to 0.86 g/l; Na⁺, \({\text{HCO}}^{ - }_{3}\), and Cl^? ions were the major dissolved chemical constituents. Two main groundwater quality groups were defined: Na–Cl and Na–HCO₃. Based on the stable isotope (¹⁸O/¹⁶O, D/H), tritium and radiocarbon analyses, some groundwater originated from rainwater infiltrating during the Upper Pleistocene Epoch. Strontium in the groundwater of the crystalline aquifer was isotopically homogenous and equilibrates with strontium in the granite and granodiorite of the gas-storage cavern. Based on the information, the deep groundwater seeps were associated with slow or ‘stagnant’ groundwater circulation, without direct relation to the recent groundwater of faster circulation near the surface, which is periodically recharged by precipitation. The results of the water-quality monitoring of the deep groundwater seeps have been used in estimating the insulating properties of the neighboring rocks near the gas-storage cavern. This information will be important in the safe operation of the gas-storage cavern.     

Heat risk assessment based on mobile phone data: case study of Bratislava,Slovakia

The aim of this interdisciplinary study is to assess the heat risk for Bratislava. The following layers were created to compute the risk index: the hazard layer of air temperature, a mitigation layer of tree vegetation, an exposure layer of population and a vulnerability layer of individuals over 65 years of age. The MUKLIMO_3 model was used to evaluate the field of mean surface air temperature at 9 PM during selected days of the summer heat wave in August 2018. The tree vegetation layer, in the form of percentage per grid cell, was derived from Sentinel-2 satellite data. Population density data are based on mobile positioning data, and elderly population data are based on a gridded database from the statistical census. Input layers were unified into a resolution of 500 × 500 m, and the heat risk index was calculated by summation of the weighted input layers. The results reflect the variability of the population and the elderly population within the city, as well as the variability of the temperature field, which is caused by the joint effect of an urban heat island and topography. The highest values of risk index occur within the broader city centre, with specific hot spots at several places.

     

Spectral accuracy of Jgm3 from satellite crossover altimetry

A detailed accuracy assessment of the geopotential model Jgm3 is made based on independent single- and dual-satellite sea-height differences at crossovers from altimetry with Jgm3-based orbits. These differences, averaged over long time spans and in latitude bands, are converted to spectra (latitude-lumped coefficients) by least-squares estimation. The observed error spectra so obtained are then compared directly to error projections for them from the Jgm3 variance–covariance matrix. It is found from these comparisons that Jgm3 is generally well calibrated with respect to the crossover altimetry of and between Geosat, TOPEX/Poseidon (T/P), and Ers 1. Some significant discrepancies at a few lower orders (namely m=1 and 3) indicate a need for further improvement of Jgm3. A companion calibration (by order) of the geopotential model Jgm2 shows its variance–covariance matrix also to be generally well calibrated for the same single- and dual-satellite altimeter data sets (but based on Jgm2 orbits), except that the error projections for Geosat are too pessimistic. The analysis of the dual-satellite crossovers reveals possible relative coordinate system offsets (particularly for Geosat with respect to T/P) which have been discussed previously. The long-term detailed seasonally averaged Geosat sea level with respect to T/P (covering 1985–1996) should be useful in gauging the relative change in sea level between different parts of the ocean over the single 4-year gap between these missions (1988–1992). Received: 16 February 1998 / Accepted: 25 November 1998