Geomorphological processes and landforms in the southern part of the Polická vrchovina Highland (Czech Republic)

The paper examines relations among geomorphological processes and the landforms of the Polická vrchovina Highland in the Bohemian Massif. Geologically, the Polická vrchovina Highland is a part of the Intra-Sudetic Basin on the boundary between Bohemia and Poland. The basin structure of the Highland developed during the neotectonic period. In the outer parts of the Highland, Mesozoic rocks dip gently to the centre of the basin to form cuestas. In the central part, layers are horizontal or subhorizontal. Mesas (Hejda and Osta Mesa) provide evidence of the erosion of the Mesozoic deposits. The relative uplift of the Highland resulted in the incision of the Metuje River and its tributaries. Unloading of rocks and erosion initiated typical geomorphological processes such as deep- seated creep, cambering, rockfalls, landslides and pseudokarst processes. These processes produced some typical forms controlled by rock properties, jointing, relative differences in height and climatic changes in the Tertiary and Quaternary.     

New insights into aggregation and conformational behaviour of humic substances: Application of high resolution ultrasonic spectroscopy

The potential of high resolution ultrasonic analysis (HRUS) in humic acid colloidal properties research has been demonstrated. Sodium salts of humic acids from soil and lignite showed similar behaviour, supporting the hypothesis that, at both neutral and alkaline pH, they aggregate from very low concentration. The same conclusion can be reached for solutions at high ionic strength. We tried to apply the same procedure as used for the study of micellization and determination of critical micelle concentration of common surfactants. As expected, our experiments did not show the same break as demonstrated on the HRUS records for sodium dodecyl sulfate, at least in the range of measured concentration (i.e. from 0.001 up to 10 g L⁻¹). The colloidal state of humic acids in aqueous solution is very sensitive to the presence of other, both charged and neutral, molecules. Aggregation of humic acids can be disturbed or promoted, depending on the concentration, by electrostatic or other weak interactions with extraneous molecules. Structures of varying mechanical strength (rigidity) can be formed in solutions of the same components but at different concentration. Such behaviour reflects mechanisms which occur during the sequestration of hydrophobic organic compounds and has several implications for the protection/transportation of labile structures and contaminants which are hypothesized to be encapsulated within hydrophobic pockets of soluble humic aggregates.     

Reflection/transmission laws for slowness vectors in viscoelastic anisotropic media

The reflection/transmission laws (R/T laws) of plane waves at a plane interface between two homogeneous anisotropic viscoelastic (dissipative) halfspaces are discussed. Algorithms for determining the slowness vectors of reflected/transmitted plane waves from the known slowness vector of the incident wave are proposed. In viscoelastic media, the slowness vectors of plane waves are complex-valued, p = P + iA, where P is the propagation vector, and A the attenuation vector. The proposed algorithms may be applied to bulk plane waves (A = 0), homogeneous plane waves (A ≠ 0, P and A parallel), and inhomogeneous plane waves (A ≠ 0, P and A non-parallel). The manner, in which the slowness vector is specified, plays an important role in the algorithms. For unrestricted anisotropy and viscoelasticity, the algorithms require an algebraic equation of the sixth degree to be solved in each halfspace. The degree of the algebraic equation decreases to four or two for simpler cases (isotropic media, plane waves in symmetry planes of anisotropic media). The physical consequences of the proposed algorithms are discussed in detail. vcerveny@seis.karlov.mff.cuni.cz     

Formaldehyde polymers in comets

The possibility that crystalline formaldehyde polymers are present in cometary dust is discussed. In common with most other parent molecules proposed for comets, (H₂CO) _n is difficult to detect, even if it is present in relatively high concentrations. The optical properties of these polymers in the visual and infrared regions are similar to those of silicate grains, and crystalline formaldehyde polymers provide no emission at 6 cm wavelength. The lifetime of gaseous H₂CO in the solar radiation field is too short, and the expected transitions in the microwave region would be too weak to be detected. However, the available data concerning the physical properties of comets indicate that polymerized formaldehyde cannot be ruled out as a major constituent of cometary material.