The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.     

Daily Meteorological Observations in Cádiz – San Fernando. Analysis of the Documentary Sources and the Instrumental Data Content (1786–1996)

Meteorological observations in the city of Cádiz are acknowledged as having been made from the middle of the 18th century onwards although they were only recorded and preserved in documentary form from 1789 onwards. Data readings were taken at the new Naval Observatory in San Fernando, ten kilometres from Cádiz, from 1797 onwards. Continuous series for temperature and atmospheric pressure at a daily resolution have been compiled and constructed from 1817 until 1996. The data series is composed of thrice daily observations made at Cádiz (1821–1880) by local observers and hourly data from Naval Observatory at San Fernando (1870–1996).     

U–Pb evidence for a polyorogenic evolution of the HP–HT units of the NW Iberian Massif

. A isotope dilution thermal ionisation mass spectrometry U-Pb geochronological study was carried out on the high-pressure and high-temperature units (HP-HT units) overlying the oceanic suture in the Allochthonous Complexes of the NW Iberian Variscan Belt. The rocks investigated are seven granulite- to eclogite-facies paragneisses and one leucosome within mafic high-pressure granulites in the Ordenes and Cabo Ortegal Complexes of NW Spain. U-Pb dating of zircon, monazite, titanite and rutile reveal the presence of a pervasive Early Ordovician metamorphic event at ca. 500-480 Ma and a later Early Devonian event at ca. 400-380 Ma. The U-Pb ages, in conjunction with petrological and structural data, indicate that the high-pressure event recorded by these rocks is Early Ordovician in age. Monazite ages in the paragneisses suggest that peak metamorphic conditions were reached at ca. 500-485 Ma. Subsequently, the rock ensemble underwent exhumation accompanied by partial melting and zircon growth at ca. 485-470 Ma. Melting of mafic granulites was coeval with this latter episode as indicated by zircon crystallisation age in the leucosomes dated at ca. 486 Ma. Based on these data and on the general features of magmatism and metamorphic evolution, it is proposed that this process took place at a convergent plate boundary within a peri-Gondwanan oceanic domain. Monazite, titanite and rutile data in some of the samples studied show evidence of a second metamorphic episode that took place between ca. 400 and 380 Ma (with a peak at ca. 390-385 Ma). This Early Devonian event, at variance with the previous one, was not pervasive, but, rather, was localised in areas of intense Variscan tectonothermal reworking. It is claimed that this later metamorphic event was recorded by the U-Pb system in areas where monazite and titanite growth was enhanced by fluid circulation in highly strained rocks (Variscan shear zones). According to previous structural studies and Ar-Ar dating of fabrics, this Early Devonian episode took place as the HP-HT units were deformed and thrusted upon the ophiolitic units in the early stages of the Variscan collision.     

Petrology and geochemistry of orthoamphibolites from the Variscan metamorphic sequences of the South Tisia in Croatia – an overview with geodynamic implications

In the southern Pannonian Basin, the Variscan Barrovian- and overprinted Abukuma-type progressive metamorphic sequences of the South Tisia in Slavonian Mts. (SM) and Mt. Moslava)ka Gora (MG) are interlayered with orthoamphibolites. These sequences represent part of a disrupted Variscan belt that extends southeastwards of the Bohemian Massif through the Carpathians to the Caucasus. Orthoamphibolites contain hornblende (Mg-hornblende, tschermakite, pargasite, and edenite), plagioclase An_48-98 (MG) and An_26-35 (SM), biotite, grossular (MG) and almandine (SM) enriched garnet, diopside (MG), with accessory ilmenite, titanite, and clinozoisite. Based on major and trace element analyses and CIPW norms, these orthoamphibolites, which originally were olivine tholeiites to slightly alkalic basalts, can be correlated with tholeiites of consuming plate margins. '¹⁸O of orthoamphibolites varies from 5.8 to 7.1‰, the measured ⁸⁷Sr/⁸⁶Sr ratio from 0.70435 to 0.70665, which indicates slight continental crust contamination, and the calculated ratio from 0.70262 to 0.70535, indicating an upper mantle origin of the original basaltic melts. For associated penecontemporaneous I-type granitoids, the calculated initial ⁸⁷Sr/⁸⁶Sr ratio also have upper mantle values ranging between 0.70293 and 0.70368. Geochemical data for orthoamphibolites and the associated penecontemporaneous I-type granites, and the occurrence of alpine-type ultramafic bodies within the Barrovian sequence, indicate that they have many features in common with orogenic associations related to recent subduction-related settings. Some characteristic element ratios suggest back-arc basin environments and the Ce/K vs. Ce diagram suggests a pargasite-lherzolite source. Its partial melting gave primitive basaltic melts of olivine tholeiite to slight alkalic affinities that produced at first differentiated mafic rocks by olivine fractionation (future orthoamphibolites) and, afterwards, a strongly differentiated suite of I-type granitoids by amphibole fractionation. Magma emplacement and subsequent AFC processes took place in subduction environments preceding the main Variscan deformational metamorphic event during which orthoamphibolites were generated. This interpretation is compatible with geodynamic modeling of this part of the Paleotethys.     

Alpujarride attribution of the supposed ‘Almagride Complex’ (Betic Internal Zone,Almerı́a Province,Spain)Appartenance Alpujarride du prétendu « Complexe almagride » (Zones internes bétiques,province d'Almeria,Espagne)

The differentiation of units in the Sierra de Almagro has been a source of controversy. There were defined the Almagride and Ballabona–Cucharón complexes, the former considered by several authors as part of a Subbetic metamorphosed and outcropping in a tectonic window. In this study, the units of Ballabona, Almagro and Cucharón are integrated into a single one, that of Tres Pacos, because they correspond to different parts of the same stratigraphic series. This unit is tectonically over the Nevado–Filabride Complex. The existence of the Almagride and Ballabona–Cucharón complexes is discarded and their units form part of the Alpujarride Complex. To cite this article: C. Sanz de Galdeano, F.J. Garc??a Tortosa, C. R. Geoscience 334 (2002) 355–362.     

Seasonal variation of the soil seed bank of grasses in central Argentina as related to grazing and shrub cover

The objectives of this research were to (a) study seasonal variation of the seed bank of grasses in two areas with different grazing history, (b) analyse the effect of the presence of shrubs on the seed bank and (c) study seed viability and dormancy in buried seeds of Piptochaetium napostaense and Stipa tenuis. The seed density of grasses was in general low and showed seasonal variation. Most of the grasses showed maximum seed density in December when seed dispersal occurs. Shrub cover did not show a marked influence in seed accumulation. The relatively high number of damaged seeds suggests that predation may be an important factor in seed bank dynamics in the Caldenal. Seeds of dominant perennial forage grasses showed dormancy that could explain, at least in part, persistence of these species in spite of periodical disturbance.     

Inelastic displacement ratios for evaluation of existing structures

Results of a detailed statistical study of constant relative strength inelastic displacement ratios to estimate maximum lateral inelastic displacement demands on existing structures from maximum lateral elastic displacement demands are presented. These ratios were computed for single‐degree‐of‐freedom systems with different levels of lateral strength normalized to the strength required to remain elastic when subjected to a relatively large ensemble of recorded earthquake ground motions. Three groups of soil conditions with shear wave velocities higher than 180m/s are considered. The influence of period of vibration, level of lateral yielding strength, site conditions, earthquake magnitude, distance to the source, and strain‐hardening ratio are evaluated and discussed. Mean inelastic displacement ratios and those associated with various percentiles are presented. A special emphasis is given to the dispersion of these ratios. It is concluded that distance to the source has a negligible influence on constant relative strength inelastic displacement ratios. However, for periods smaller than 1s earthquake magnitude and soil conditions have a moderate influence on these ratios. Strain hardening decreases maximum inelastic displacement at a fairly constant rate depending on the level of relative strength for periods of vibration longer than about 1.0s while it decreases maximum inelastic displacement non‐linearly as the period of vibration shortens and as the relative‐strength ratio increases for periods of vibration shorter than 1.0s. Finally, results from non‐linear regression analyses are presented that provide a simplified expression to be used to approximate mean inelastic displacement ratios during the evaluation of existing structures built on firm sites. Copyright © 2003 John Wiley & Sons, Ltd.