Geochemistry of volcanic and hydrothermal gases of Mutnovsky volcano,Kamchatka: evidence for mantle,slab and atmosphere contributions to fluids of a typical arc volcano

We report chemical compositions (major and trace components including light hydrocarbons), hydrogen, oxygen, helium and nitrogen isotope ratios of volcanic and geothermal fluids of Mutnovsky volcano, Kamchatka. Several aspects of the geochemistry of fluids are discussed: chemical equilibria, mixing of fluids from different sources, evaluation of the parent magmatic gas composition and contributions to magmatic vapors of fluids from different reservoirs of the Kamchatkan subduction zone. Among reactive species, hydrogen and carbon monoxide in volcanic vapors are chemically equilibrated at temperatures >300°C with the SO₂-H₂S redox-pair. A metastable equilibrium between saturated and unsaturated light hydrocarbons is attained at close to discharge temperatures. Methane is disequilibrated. Three different sources of fluids from three fumarolic fields in the Mutnovsky craters can be distinguished: (1) magmatic gas from a large convecting magma body discharging through Active Funnel, a young crater with the hottest fumaroles (up to 620°C) contributing ~80% to the total volcanic gas output; (2) volcanic fluid from a separate shallow magma body beneath the Bottom Field of the main crater (96–280°C fumaroles); and (3) hydrothermal fluid with a high relative and absolute concentrations of CH₄ from the Upper Field in the main crater (96–285°C fumaroles). The composition of the parent magmatic gas is estimated using water isotopes and correlations between He and other components in the Active Funnel gases. The He-Ar-N₂ systematics of volcanic and hydrothermal fluids of Mutnovsky are consistent with a large slab-derived sedimentary nitrogen input for the nitrogen inventory, and we calculate that only ~1% of the magmatic N₂ has a mantle origin and <<1% is derived from the arc crust.     

Appearance of the nonlinearity from the nonlocality in diffusion through multiscale fractured porous media

We shall consider diffusion or single-phase flow in a multiscale porous medium which represents an infinite set of self-similar double-porosity media. At each scale, the medium consists of a highly permeable network of connected channels and low-permeable blocks. The characteristic scale of heterogeneity is ε at the highest level of hierarchy, wherein ε is a small parameter. The ratio between the channel and block permeability at each scale is ε ². The process analyzed is described using a diffusion equation with an oscillating multiscale diffusion parameter. The macroscale behavior is of interest. The transition to the macroscale is performed by means of the two-scale homogenization procedure. One step of averaging at each level of hierarchy leads to the appearance of the memory terms in the averaged equation. The successive averaging steps lead to progressive memory accumulation, so at each step of averaging, the macroscale model changes its type, and even the result of the second step is unknown a priori. The objective was to determine the macroscopic limit model for the infinite number of scales. By the method of induction, we obtained the macroscale model for an arbitrary number of scales and its limit for the infinite hierarchy. The limit model represents the system of two equations with memory terms. The kernel of the memory operator is the solution of a nonlinear integro-differential equation. Its solution is obtained through Laplace transform.     

The Suavjärvi impact structure,NW Russia

Abstract– We present the geology and interpreted shock features of the Suavjärvi circular structure. Suavjärvi is a circular feature (illustrated by satellite imagery, topography, and magnetic data) located in the central part of the Karelian Craton (lat. 63°07′N, long. 33°23′E). To date, little information on the geologic and impact features of the Suavjärvi structure is available in the literature. The structure is characterized by gravity and magnetic lows and disruption of the regional magnetic fabric. In the northeastern and southwestern parts of the structure, several erosional remnants of highly disturbed rocks occur referred to as monomict and polymict megabreccia. These comprise blocks of both basement granitoids and supracrustal greenstone rocks. The impact origin of polymict megabreccia and therefore of the Suavjärvi structure is confirmed by observations of closely spaced planar microstructures at angles consistent with planes that have Miller indices indicative of impact shock effects, mostly of ω{10¯13}. The Suavjärvi is considered to be a remnant of a deeply eroded and metamorphosed impact structure, which has a diameter of 16 km and was formed during the Paleoproterozoic (older than 2.2 Ga); this is inferred from the age of the overlying volcanic‐sedimentary Jatulian sequence. Suavjärvi underwent regional metamorphism that resulted in obliteration or transformation of shock metamorphic effects. Massive sulfides occur within megabreccia; originating probably from postimpact redeposition of pre‐existing mineralization.     

Slope streaks on Mars: A new “wet” mechanism

Slope steaks are one of the most intriguing modern phenomena observed on Mars. They have been mostly interpreted as some specific type of granular flow. We propose another mechanism for slope streak formation on Mars. It involves natural seasonal formation of a modest amount of highly concentrated chloride brines within a seasonal thermal skin, and runaway propagation of percolation fronts. Given the current state of knowledge of temperature regimes and the composition and structure of the surface layer in the slope streak regions, this mechanism is consistent with the observational constraints; it requires an assumption that a significant part of the observed chlorine to be in form of calcium and ferric chloride, and a small part of the observed hydrogen to be in form of water ice. This “wet” mechanism has a number of appealing advantages in comparison to the widely accepted “dry” granular flow mechanism. Potential tests for the “wet” mechanism include better modeling of the temperature regime and observations of the seasonality of streak formation.     

Synoptic-scale anomalies of Lake Ladoga surface temperature fields

Results of studying characteristic features of variability of the water surface temperature fields of Lake Ladoga during the open water period are presented. Anomalies and extreme deviations of real spatial distributions from those typical of the scales of synoptic variability are estimated. Typical surface temperature distribution of Lake Ladoga during an open water period occupies not more than 20% of the lake area. The near-shore shallow water area is characterized as an area of most anomalous water temperature distribution. The abnormality extent changes from month to month. July is the most anomalous month of the open water period.     

Impact of non-outbreak insect damage on vegetation in northern Europe will be greater than expected during a changing climate

Background insect herbivory, in addition to insect outbreaks, can have an important long term influence on the performance of tree species. Since a projected warmer climate may favour insect herbivores, we use a dynamic ecosystem model to investigate the impacts of background herbivory on vegetation growth and productivity, as well as distribution and associated changes in terrestrial ecosystems of northern Europe. We used the GUESS ecosystem modelling framework and a simple linear model for including the leaf area loss of Betula pubescens in relation to mean July temperature. We tested the sensitivity of the responses of the simulated ecosystems to different, but realistic, degrees of insect damage. Predicted temperature increases are likely to enhance the potential insect impacts on vegetation. The impacts are strongest in the eastern areas, where potential insect damage to B. pubescens can increase by 4–5%. The increase in insect damage to B. pubescens results in a reduction of total birch leaf area (LAI), total birch biomass and birch productivity (Net Primary Production). This effect is stronger than the insect damage to leaf area alone would suggest, due to its second order effect on the competition between tree species. The model's demonstration that background herbivory may cause changes in vegetation structure suggests that insect damage, generally neglected by vegetation models, can change predictions of future forest composition. Carbon fluxes and albedo are only slightly influenced by background insect herbivory, indicating that background insect damage is of minor importance for estimating the feedback of terrestrial ecosystems to climate change.     

Morphometric Features of the Submarine Slope of the Southwestern Part of Valaam Island

Doklady Earth Sciences - A digital bathymetric model with a 10 × 10 m spatial resolution was created on the basis of the depth sounding on the southwestern slope of Valaam Island with the use...     

Improving the crescent visibility limits due to factors causing decrease in the sky twilight brightness

The measured sky twilight brightness of a site is believed to be connected with main factors such as geographical latitude, elevation of the site above sea level, the season of observations and the aerosol pollution. These factors may decrease the sky twilight brightness and thus improve the crescent visibility limits. The effect of these factors on the visibility conditions to see the new Moon are investigated in the present work. The results show that the visibility conditions has improved at sites situated at higher northern geographical latitudes and higher elevation above sea level. The conditions to see the new Moon in winter season is better than the summer season. The aerosol pollution has a great effect on the visibility of the new Moon at sun's depression 5°, while for sun's depression greater than 5° the aerosol pollution has a small effect.     

Decline in Length of the Summer Season on the Kola Peninsula, Russia

By analysing records made in the northern taiga forests of the Lapland Reserve (Kola Peninsula, Russia) during 1930–1998, we unexpectedly discovered a decline in the length of the snow-free and ice-free periods by 15–20 days due to both delayed spring and advanced autumn/winter. Respective seasonal temperatures best explained the dates of all phenological phases: 1 °C shift in temperature was approximately equal to 2–5 day shift in phenology. However the phenological shiftsduring the observation period are much larger than could be expected from the slight (0.56 °C) drop in temperatures during August–September, suggesting that the biotic effects of a very slight cooling have been enhanced by one or more unknown factors. Although emissions of sulphur dioxide from the nickel-copper smelter at Monchegorsk may have contributed to the observed trend (via changes in regional radiative budget), we found no evidence of direct pollution impact on dates of birch autumnal coloration or birch leaf fall, which exhibited the largest (22 days) shift between 1930 and 1998. The detected phenological trends agree with an increase in winter (snow) precipitation in the study area by 44%; however, effects of precipitation on any of the investigated phenological phases were far from significant. Our results highlight the importance of phenological records for the assessment of past regional environmental changes, and demonstrates that the prediction of even the simplest biotic responses to the Global Changes requires a profound understanding of the interactive impact of abiotic factors on the ecosystem.