Mathematical modeling of PCB bioaccumulation in Perna viridis

In the present work, we built a mathematical model of polychlorinated biphenyl (PCB) bioaccumulation in Perna viridis, namely, a one-compartment model with a time dependent incorporation rate R (μg g⁻¹ lipid per ppb water per day), with positive substrate cooperativity as the underlying physical mechanism. The temporal change of the PCB concentration Q (μg g⁻¹ lipid) in the soft tissues of the mussel depends on the competition of the input rate RW and the output rate kQ, where W is the concentration of PCB in water (ppb water) and k is the elimination rate (per day). From our experimental data, k=0.181±0.017 d⁻¹. The critical concentration in water W_c for positive substrate cooperativity was found to be 2.4 ppb. Below W_c, R is a constant. For a water concentration of 0.5 ppb Aroclor 1254, R=24.0±2.4 μg g⁻¹ lipid ppb⁻¹ d⁻¹. Above W_c, positive substrate cooperativity comes into effect and R becomes a function of time and dependent on the concentration Q in a form R=γQ/(Q+δ). This is the case for a water concentration of 5 ppb Aroclor 1254, where γ=15.1 μg g⁻¹ lipid ppb⁻¹ d¹ and δ≈200 μg g⁻¹ lipid. From this model, the uptake is exponentially increasing when the PCB concentration in the mussel is small compared to 200 μg g⁻¹ lipid, and hyperbolically increasing when the concentration is large compared to 200 μg g⁻¹ lipid, which are consistent with the experimental data. The model is useful for understanding the true processes taking place during the bioaccumulation and for risk assessment with higher confidence. Future experimental data which challenge the present model are anticipated and in fact desirable for improvement and perfection of the model.     

ELF propagation parameters for uniform models of the Earth–ionosphere waveguide

Uniform models for the Earth–ionosphere cavity are considered with particular attention to the physical properties of the ionosphere for the extremely low frequency (ELF) range. Two consistent features have long been recognized for the range: the presence of two distinct altitude layers of maximum energy dissipation within the lower ionosphere, and a “knee”-like change in the vertical conductivity profile representing a transition in dominance from ion-dominated to electron-dominated conductivity. A simplified two-exponential version of the Greifinger and Greifinger (1978) technique widely used in ELF work identifies two slopes in the conductivity profile and, providing accurate results in the ELF communication band (45–75 Hz), simulates too flat a frequency dependence of the quality factor within the Schumann resonance frequency range (5–40 Hz). The problem is traced to the upward migration, with frequency increasing, of the lower dissipation layer through the “knee” region resulting in a pronounced decrease of the effective scale height for conductivity. To overcome this shortcoming of the two-exponential approximation and still retain valuable model analyticity, a more general approach (but still based on the Greifinger and Greifinger formalism) is presented in the form of a “knee” model whose predictions for the modal frequencies, the wave phase velocities and the quality factors reasonably represent observations in the Schumann resonance frequency range.     

Geoecological Characteristics of Lake Seliger

Data of hydrological and hydrochemical observations conducted in August 2000 at Lake Seliger and its major tributaries are presented. The analyzed characteristics included: O₂, H₂S, CH₄, microelements; mineral and organic compounds of P and N, ionic composition components (HCO₃ ^–, Cl^–, Na⁺, K⁺, dry residue, pH; color index, electrical conductivity. Bottom sediment samples were analyzed for microelement concentrations, CH₄, oil hydrocarbons. The influence of the basin on the ecological state of the lake was assessed, and tendencies in the evolution of its ecosystem are analyzed. It is shown that the ecological conditions of the lake has not changed significantly since 1960–1991, however, nutrient concentrations in the lake water was found to increase.     

Causes of Geochemical Diversity of Carbon Dioxide Water in Crystalline Rock Masses

The problem of the diversity of the geochemical types of carbon dioxide waters (CDW) in petrografically and mineralogically uniform crystalline rock masses is solved with allowance made for the effect of different boundary conditions (physicochemical parameters) on the geochemical effect of interaction in the rock–water system. The formation of the entire geochemical spectrum of CDW in crystalline rock masses is shown to be explicable on the basis of a model of interaction in granite–water systems at different mass ratios of reacting rock (S) and water (L), different temperatures T, and equilibrium concentrations of dissolved CO₂ (P _CO2).     

Soil degradation: a global problem endangering sustainable development

1 Introduction Soil is not only the major natural resource on which human being depends for the production of food, feed, fiber, renewable energy and raw materials, but also plays a key role in maintaining the complex terrestrial ecosystems and climate systems of this planet. Recent rapid increase in the human population is placing a great strain on the worlds soil resources. Only about 11% of the global land surface covered by the soils are being used to raise crops and livestock, in other …     

A general model for estimating actual evaporation from non-saturated surfaces

Based on energy balance equation and mass transfer equation, a general model to estimate actual evaporation from non-saturated surfaces was derived. Making use of two concepts, “relative evaporation” and “relative drying power”, a relationship was established to account for the departure from saturated conditions. Using this model, the actual evaporation (evapotranspiration) can be calculated without the need of potential evaporation estimation. Furthermore, the model requires only a few meteorological parameters that are readily and routinely obtainable at standard weather stations. Based on nearly 30 years data of 432 meteorological stations and 512 hydrological stations in China, in combined with GIS, nine typical river basins were selected. Using the data of the selected river basins, the model was tested. The results show that the actual evaporation rate can be estimated with an error of less than 10% in most areas of China, except few years in the Yellow River Basin.     

Some Aspects of Resource Uncertainty and Their Economic Consequences in Assessment of the 1002 Area of the Arctic National Wildlife Refuge

Natural Resources Research - Exploration ventures in frontier areas have high risks. Before committing to them, firms prepare regional resource assessments to evaluate the potential payoffs. With...     

A method to reduce the influence of ice-rafted debris on a grain size record from northern Fram Strait, Arctic Ocean

The granulometric composition of terrigenous deep-sea sediments provides information on current speed if certain frame conditions are fulfilled. These include that current transport is the only transport process. At high latitudes this type of investigation is impaired due to the influence of ice-rafted debris (IRD) which contaminates the current-sorted grain size fractions. This study presents a new method that addresses this problem by setting the ice-rafted sand in relation to the silt of both current- and ice-transported origin. Deviations from the resulting regression function are then used to determine the behaviour of the silt mean grain size as a function of current speed largely independent from IRD bias. The study is based on sediments from the Yermak Plateau, Arctic Ocean, a region influenced by IRD brought with the south-headed Transpolar Drift and by north-directed bottom currents. The IRD correction results in displaying changes of current speed at much higher clarity; climate forcing of the currents becomes more evident. For example, the 8200 year cold event shows up as a major event in the corrected record whereas it is hardly visible in the original record.