Madagascar

Untreated domestic and industrial wastes are discharged into Tolo Harbour via several major streams entering the harbour. These untreated wastes will cause a harmful effect because Tolo Harbour is a land-locked sea with only a narrow outlet and an ever-decreasing volume caused by the construction of Plover Cove Reservoir and the reclamation of Shatin New Town. In order to study the effect of polluted water discharged into the harbour, water samples and sediments near the mouths of the major rivers were collected. The analysis of the total organic carbon, total nitrogen, and water soluble phosphate contents of the samples showed that Lam Tsuen River, Tai Po Kau River, and Shing Mon River were grossly polluted by organic and inorganic wastes. Blue Snake River which passes through the iron ore tailings accumulated high contents of metal contaminants.     

Micellar-Enhanced Ultrafiltration and Air Stripping for Surfactant-Contaminant Separation and Surfactant Reuse

Micellar-enhanced ultrafiltration (MELT) and air stripping were evaluated for surfactant-contaminant separation and surfactant recovery. Two linear alkyl diphenyloxide disulfonate (DPDS) surfactants were evaluated with the contaminants naphthalene and trichloroethylene. A separation model developed from micellar partitioning principles showed a good correlation to batch MEUF studies, whereas flux analysis highlighted concentration polarization effects in relation to hydrophobe length. MEUF effectively concentrated the surfactant-contaminant system (93 to 99 percent retention); however, this did not result in surfactant-contaminant separation. Batch and continuous flow air stripping models were developed based upon air/water ratio, surfactant concentration, and Micellar partitioning; model predictions were validated by experimental data. Sensitivity analyses illustrated the decline in contaminant-surfactant separation with increasing surfactant concentration (e.g., TCE removal efficiency declines from 83 percent to 37 percent as C-16 DPDS concentration increases from 0 to 55 mM). This effect is greater for more hydrophobic contaminants (naphthalene vs. TCE) and surfactants with greater solubilization potential (C16-DPDS vs. C-12 DPDS). The resulting design equations can account for this effect and thus properly size air strippers to achieve the desired removal efficiency in the presence of surfactant micelles. Proper selection and design of surfactant-contaminant separation and surfactant recovery systems are integral to optimizing surfactant-enhanced subsurface remediation.     

Outlying plasmasphere structure detected by whistlers

Whistlers recorded at Eights ($\text{L ? 4}$) and Byrd ($\text{f ? 7}$), Antarctica have been used to study large-scale structure in equatorial plasma density at geocentric distances $\text{?3–6}\text{R}{}_{\mathrm{E}}$. The observations were made during conditions of magnetic quieting following moderate disturbance. The structures were detected by a “scanning” process involving relative motion, at about one tenth of the Earth's angular velocity or greater, between the observed density features and the observing whistler station or stations. Three case studies are described, from 26 March 1965, 11 May 1965 and 29 August 1966. The cases support satellite results by showing outlying high density regions at $\text{?4–6}\text{R}{}_{\mathrm{E}}$ that are separated from the main plasmasphere by trough-like depressions ranging in width from $\text{?0.2}$ to 1 R_E. The structures evidently endured for periods of 12 hr or more. In the cases of deepest quieting their slow east-west motions with respect to the Earth are probably of dynamo origin. The cases observed during deep quieting (11 May 1965 and 29 August 1966) suggest the approximate rotation with the Earth of structure formed during previous moderate disturbance activity in the dusk sector. The third case, from 26 March 1965, may represent a structure formed near local midnight. The reported structures appear to be closely related to the bulge phenomenon. The present work supports other experimental and theoretical evidence that the dusk sector is one of major importance in the generation of outlying density structure. It is inferred that irregularities of the type reported here regularly develop near 4–5 R_E during moderate substorm activity. This research suggests that at least a major class of the density structures that develop near 4 R_E are tail-like in nature, joined to the main body of the plasmasphere. The apparent disagreement with Chappell's results from OGO 5, which are interpreted as showing regions of “detached” plasma beyond 5 R_E, may be related to the pronounced spatial structure of electric fields observed in high-latitude ionospheric regions that are conjugate to the magnetospheric regions in which the OGO-5 observations were made.     

Distribution of dinoflagellate cysts in Yellow Sea sediments

To investigate the distribution,abundance,and species composition of dinoflagellate cysts in the Yellow Sea,surface sediment samples were collected at 37 sites,including the Korean dump site.Twenty-one dinoflagellate cyst taxa were identified,with the assemblages dominated mainly by Spiniferites bulloideus,Operculodinium centrocarpum,and cyst of Alexandrium catenella/tamarense type.A high frequency of O.centrocarpum in the Yellow Sea was observed for the first time,and it is likely that this can be attributed to the dynamics of the Yellow Sea Cold Water Mass and the Changjiang(Yangtze) River runoff.Total cyst concentrations ranged from 23 to 48 442 cysts/g dry weight,and high cyst concentrations were recorded adjacent to the dumping site.This result suggests that anthropogenic activities such as ocean dumping stimulate the growth of dinoflagellates in the Yellow Sea,which in turn leads to high levels of dinoflagellate cyst production.     

Evaluating Tidal Wetland Restoration Performance Using National Estuarine Research Reserve System Reference Sites and the Restoration Performance Index (RPI)

Evaluations of tidal wetland restoration efforts suffer from a lack of appropriate reference sites and standardized methods among projects. To help address these issues, the National Estuarine Research Reserve System (NERRS) and the NOAA Restoration Center engaged in a partnership to monitor ecological responses and evaluate 17 tidal wetland restoration projects associated with five reserves. The goals of this study were to (1) determine the level of restoration achieved at each project using the restoration performance index (RPI), which compares change in parameters over time between reference and restoration sites, (2) compare hydrologic and excavation restoration projects using the RPI, (3) identify key indicator parameters for assessing restoration effectiveness, and (4) evaluate the value of the NERRS as reference sites for local restoration projects. We found that the RPI, modified for this study, was an effective tool for evaluating relative differences in restoration performance; most projects achieved an intermediate level of restoration from 2008 to 2010, and two sites became very similar to their paired reference sites, indicating that the restoration efforts were highly effective. There were no differences in RPI scores between hydrologic and excavation restoration project types. Two abiotic parameters (marsh platform elevation and groundwater level) were significantly correlated with vegetation community structure and thus can potentially influence restoration performance. Our results highlight the value of the NERRS as reference sites for assessing tidal wetland restoration projects and provide improved guidance for scientists and restoration practitioners by highlighting the RPI as a trajectory analysis tool and identifying key monitoring parameters.     

Impact of adsorbed petroleum hydrocarbons on marine organisms

Adsorptions of south Louisiana crude oil from seawater by clays, non-clay minerals and sediments were conducted in the laboratory. Effect of sediment-adsorbed and water dispersed crude oil on adult oysters were investigated in aquaria. Hydrocarbons in oyster tissues and surrounding water were identified by gas chromatography. Field specimens from an area of a new oil spill and an area five months after an oil spill were also analysed. Evidence of secondary chemical effect of aged oil in sediments on oyster mortality is presented. Oil coated asbestos surfaces severely reduced recruitment of sedentary larval organisms.     

Environmental effects on the reproduction and fecundity of the introduced calcareous sponge Paraleucilla magna in Rio de Janeiro,Brazil

The calcareous sponge Paraleucilla magna (Porifera, Calcarea) has been the subject of several studies in the last decade. It was first described along the Brazilian coast, where it is considered cryptogenic, and was subsequently found in the Mediterranean, where it is considered invasive. The wide artificial distribution of this species allows us to compare different aspects of the biology of an introduced species in different locations. Here, we analysed the effects of selected environmental parameters on the reproductive dynamics of P. magna in Rio de Janeiro (Brazil) over 18 months and compared our results with those obtained for the same species in the Mediterranean Sea. Specimens were collected monthly and analysed through histological methods. The density of reproductive elements in each month was calculated, and the effects of environmental parameters (photoperiod, precipitation, temperature, phytoplankton and bacterioplankton) were analysed using a regression tree analysis. Paraleucilla magna was reproductive throughout the study period. The densities of the reproductive elements (oocytes, embryos and larvae) showed no seasonality, and this species presented one of the highest reproductive efforts documented to date in the phylum Porifera (99.0 oocytes · mm^?3; 89.0 embryos · mm^?3; 319.0 larvae · mm^?3). The main environmental parameters related to the reproduction of P. magna were temperature, photoperiod and bacterioplankton. Temperature was the main driver associated with the densities of oocytes and embryos, while bacterioplankton was the main driver of larvae (positive relationships). In Rio de Janeiro, larvae were present and continuously released. This strategy is different from that observed in the Mediterranean, where a larger larval output was observed but only during the summer months. Our results show that P. magna is a species with a strong invasive potential, considering its high and continuous reproductive effort. This high fecundity stimulated by high temperatures may be a key factor contributing to the growth of P. magna populations and its invasion of new areas.     

Modelling the effects of land‐use change on water and salt delivery from a catchment affected by dryland salinity in south‐east Australia

A comprehensive framework for the assessment of water and salt balance for large catchments affected by dryland salinity is applied to the Boorowa River catchment (1550 km²), located in south‐eastern Australia. The framework comprised two models, each focusing on a different aspect and operating on a different scale. A quasi‐physical semi‐distributed model CATSALT was used to estimate runoff and salt fluxes from different source areas within the catchment. The effects of land use, climate, topography, soils and geology are included. A groundwater model FLOWTUBE was used to estimate the long‐term effects of land‐use change on groundwater discharge. Unlike conventional salinity studies that focus on groundwater alone, this study makes use of a new approach to explore surface and groundwater interactions with salt stores and the stream. Land‐use change scenarios based on increased perennial pasture and tree‐cover content of the vegetation, aimed at high leakage and saline discharge areas, are investigated. Likely downstream impacts of the reduction in flow and salt export are estimated. The water balance model was able to simulate both the daily observed stream flow and salt load at the catchment outlet for high and low flow conditions satisfactorily. Mean leakage rate of about 23·2 mm year^?1 under current land use for the Boorowa catchment was estimated. The corresponding mean runoff and salt export from the catchment were 89 382 ML year^?1 and 38 938 t year^?1, respectively. Investigation of various land‐use change scenarios indicates that changing annual pastures and cropping areas to perennial pastures is not likely to result in substantial improvement of water quality in the Boorowa River. A land‐use change of about 20% tree‐cover, specifically targeting high recharge and the saline discharge areas, would be needed to decrease stream salinity by 150 µS cm^?1 from its current level. Stream salinity reductions of about 20 µS cm^?1 in the main Lachlan River downstream of the confluence of the Boorowa River is predicted. The FLOWTUBE modelling within the Boorowa River catchment indicated that discharge areas under increased recharge conditions could re‐equilibrate in around 20 years for the catchment, and around 15 years for individual hillslopes. Copyright © 2004 John Wiley & Sons, Ltd.     

Statistical approach to determine the salinized ground water flow path and hydrogeochemical features around the underground LPG cavern,Korea

The ground water flow path of the coastal area in the Yellow Sea, Korea, was interpreted using both the cross‐correlation analysis of hydraulic properties and the principal component analysis (PCA) of ground water chemistry. Data was obtained from observation wells in the underground liquefied petroleum gas (LPG) cavern constructed in the coastal area of Pyeongtaek. Cross‐correlation results showed that the operating pressure became more influenced on artificial factors for the variation of the groundwater level of the study area (45–66% of correlation coefficient) even though its affecting area was limited to the region with fractures or faults, and also showed that the delay time from the variation of operating pressure to the fluctuation of ground water level were relatively long periods (28–31 days). Three hydrogeochemical events (encrusted cement dissolution, host rock dissolution, and seawater intrusion), which were dominantly influenced on ground water quality, could be induced from the result of PCA. Quantitative evaluation for these events using the mixed equation with principal component scores suggest that the dissolution of encrusted cement materials was the predominant factor (39·0% of the total mixed proportion) to change the chemical composition of the seepage water during the ground water flow from the observation wells to the cavern. Integration of the statistical results also imply that ground water flow and hydrogeochemistry were predominantly affected by artificial factors such as cavern operation pressure and dissolution of encrusted cement materials, which were interdependent factors on the observation wells with high cross‐correlation coefficients and pH. Copyright © 2007 John Wiley & Sons, Ltd.     

Statistical control chart for regime identification in volcanic time series

In an important paper, Mulargia et al. (1987) address the importance of quantitative and objective identification of different regimes of a volcano. They develop a procedure based on the two-sample Kolmogorov-Smirnov (K-S) statistic. The K-S test is a general-purpose test that discriminates between two data sets as belonging to two different regimes based on their empirical distribution functions. The empirical distribution function is designed to describe the aggregate behavior of the volcanic activity, and it is constructed from the orders of the length of the collected repose times in each data set. In this article, we use the idea of statistical process control to distinguish between the variation inherent in the observed repose times and the extraordinary variation that signals a real change in the regimes. We construct a table of control limits, and we demonstrate the procedure of regime identification based on a simple control chart. It shows a point outside the control limits almost as soon as the process enters a new regime. The basis of the statistical process control mechanism is a simple Poisson process, which is state of the art. The proposed control charting procedure is an eruption by eruption procedure, which follows the original chronological order of the eruptions. This procedure is applied to the eruptive history of the Mount Etna volcano. The application shows schematically that the procedure presents a visual interpretation of the identified regimes and can be practically translated for tabular or manual use.