Micellar-Enhanced Ultrafiltration and Air Stripping for Surfactant-Contaminant Separation and Surfactant Reuse

Micellar-enhanced ultrafiltration (MELT) and air stripping were evaluated for surfactant-contaminant separation and surfactant recovery. Two linear alkyl diphenyloxide disulfonate (DPDS) surfactants were evaluated with the contaminants naphthalene and trichloroethylene. A separation model developed from micellar partitioning principles showed a good correlation to batch MEUF studies, whereas flux analysis highlighted concentration polarization effects in relation to hydrophobe length. MEUF effectively concentrated the surfactant-contaminant system (93 to 99 percent retention); however, this did not result in surfactant-contaminant separation. Batch and continuous flow air stripping models were developed based upon air/water ratio, surfactant concentration, and Micellar partitioning; model predictions were validated by experimental data. Sensitivity analyses illustrated the decline in contaminant-surfactant separation with increasing surfactant concentration (e.g., TCE removal efficiency declines from 83 percent to 37 percent as C-16 DPDS concentration increases from 0 to 55 mM). This effect is greater for more hydrophobic contaminants (naphthalene vs. TCE) and surfactants with greater solubilization potential (C16-DPDS vs. C-12 DPDS). The resulting design equations can account for this effect and thus properly size air strippers to achieve the desired removal efficiency in the presence of surfactant micelles. Proper selection and design of surfactant-contaminant separation and surfactant recovery systems are integral to optimizing surfactant-enhanced subsurface remediation.     

Effects of temperature-dependent material properties and radioactive heat production on simple basin subsidence models

The effects of applying laboratory-derived material parameters to simple thermal basin subsidence models are examined. The temperature-dependent properties of thermal conductivity, specific heat and the coefficient of thermal expansion are considered, as well as conductivity contrasts between the crust and mantle and lithosphere-scale radiogenic heat production. The effects of conductivity and radioactivity are complementary, and can be predicted from the way in which they influence the initial and final steady-state geothermal gradient. A convex-up initial gradient, such as is generated by the conductivity and radioactivity functions and is also assumed to be the case based on independent evidence, will lead to more initial subsidence than in a simple constant-parameter model. The final subsidence will also be greater in the modified model, due to the fact that the stretching event will result in a lithospheric column which is intrinsically cooler than in the pre-deformation case. Because the coefficient of thermal expansion rises with increasing temperature, including its temperature dependence will result in a model with substantially less initial subsidence than one with a constant value. When these parameters are combined into a single model, the initial subsidence is approximately 15–20% less than in the constant-parameter model if radioactivity is not included, and 10% less if it is, while the final subsidence is about 5% greater without radioactivity and 7–9% greater with radioactivity included. Depending on the magnitude of extension, these effects can translate into differences of tens to hundreds of meters when compared to the constant-parameter model.     

Field survey of the 1994 Mindoro Island,Philippines tsunami

This is a report of the field survey of the November 15, 1994 Mindoro Island, Philippines, tsunami generated by an earthquake (M=7.0) with a strike-slip motion. We will report runup heights from 54 locations on Luzon, Mindoro and other smaller islands in the Cape Verde passage between Mindoro and Luzon. Most of the damage was concentrated along the northern coast of Mindoro. Runup height distribution ranged 3–4 m at the most severely damaged areas and 2–4 in neighboring areas. The tsunami-affected area was limited to within 10 km of the epicenter. The largest recorded runup value of 7.3 m was measured on the southwestern coast of Baco Island while a runup of 6.1 m was detected on its northern coastline. The earthquake and tsunami killed 62 people, injured 248 and destroyed 800 houses. As observed in other recent tsunami disasters, most of the casualties were children. Nearly all eyewitnesses interviewed described the first wave as a leading-depression wave. Eyewitnesses reported that the main direction of tsunami propagation was SW in Subaang Bay, SE in Wawa and Calapan, NE on Baco Island and N on Verde Island, suggesting that the tsunami source area was in the southern Pass of Verde Island and that the wave propagated rapidly in all directions. The fault plane extended offshore to the N of Mindoro Island, with its rupture originating S of Verde Island and propagating almost directly south to the inland of Mindoro, thereby accounting for the relatively limited damage area observed on the N of Mindoro.     

Aquifer Characterization Using Fiber Bragg Grating Multi-Level Monitoring System

Groundwater responses measured from multiple wells at different depths are essential for delineating the aquifer heterogeneity using hydraulic tomography (HT). In general, conducting HT requires many wells because traditional well monitoring is usually partially open at a specific depth interval or is fully penetrating. Accordingly, conducting an HT survey is typically costly and time-consuming. To tackle these issues, a new multi-level monitoring system (MLMS) for the HT survey was developed using the fiber Bragg grating (FBG) technique. This FBG MLMS could collect the depth-discrete groundwater observations from a fully penetrated 2-inch well. Three field campaigns were conducted to validate the capability of the FBG MLMS for HT surveys. The results show that the accuracy and stability of this MLMS are reliable and that FBG MLMS is beneficial for conducting an HT survey. Specifically, compared to the traditional monitoring well in an injection event, this FBG MLMS can concurrently cause an increase in the number of cross-hole tests several times and collect many more head observations than the standard methods, resulting in the observed flow fields efficiently reaching ergodic conditions and effectively improving the accuracy of the estimated hydraulic heterogeneity. Therefore, the FBG MLMS could be an alternative MLMS for efficiently and economically conducting an HT survey.     

Variation in biogeochemical parameters across intertidal seagrass meadows in the central Great Barrier Reef region

This survey provides baseline information on sediment characteristics, porewater, adsorbed and plant tissue nutrients from intertidal coastal seagrass meadows in the central region of the Great Barrier Reef World Heritage Area. Data collected from 11 locations, representative of intertidal coastal seagrass beds across the region, indicated that the chemical environment was typical of other tropical intertidal areas. Results using two different extraction methods highlight the need for caution when choosing an adsorbed phosphate extraction technique, as sediment type affects the analytical outcome. Comparison with published values indicates that the range of nutrient parameters measured is equivalent to those measured across tropical systems globally. However, the nutrient values in seagrass leaves and their molar ratios for Halophila ovalis and Halodule uninervis were much higher than the values from the literature from this and other regions, obtained using the same techniques, suggesting that these species act as nutrient sponges, in contrast with Zostera capricorni. The limited historical data from this region suggest that the nitrogen and phosphorus content of seagrass leaves has increased since the 1970s concomitant with changing land use practice.     

Seismic isolation for low‐to‐medium‐rise buildings using granulated rubber–soil mixtures: numerical study

This paper presents the preliminary research works on a potential seismic isolation method that makes use of scrap rubber tires for the protection of low‐to‐medium‐rise buildings. The method involves mixing shredded rubber tire particles with soil materials and placing the mixtures around building foundations, which provides a function similar to that of a cushion. Meanwhile, the stockpiling of scrap tires is a significant threat to our environment, and the engineering community has been looking for long‐term viable solutions to the recycling and reuse of rubber. A finite element program has been developed for modeling the time‐domain dynamic responses of soil–foundation–structure system, by which the effectiveness and robustness of the proposed method have been evaluated. In general, the structural responses, in terms of acceleration and inter‐story drift, can be reduced by 40–60%. Copyright © 2012 John Wiley & Sons, Ltd.     

Frequency‐domain acoustic‐elastic coupled waveform inversion using the Gauss‐Newton conjugate gradient method

We developed a frequency‐domain acoustic‐elastic coupled waveform inversion based on the Gauss‐Newton conjugate gradient method. Despite the use of a high‐performance computer system and a state‐of‐the‐art parallel computation algorithm, it remained computationally prohibitive to calculate the approximate Hessian explicitly for a large‐scale inverse problem. Therefore, we adopted the conjugate gradient least‐squares algorithm, which is frequently used for geophysical inverse problems, to implement the Gauss‐Newton method so that the approximate Hessian is calculated implicitly. Thus, there was no need to store the Hessian matrix. By simultaneously back‐propagating multi‐components consisting of the pressure and displacements, we could efficiently extract information on the subsurface structures. To verify our algorithm, we applied it to synthetic data sets generated from the Marmousi‐2 model and the modified SEG/EAGE salt model. We also extended our algorithm to the ocean‐bottom cable environment and verified it using ocean‐bottom cable data generated from the Marmousi‐2 model. With the assumption of a hard seafloor, we recovered both the P‐wave velocity of complicated subsurface structures as well as the S‐wave velocity. Although the inversion of the S‐wave velocity is not feasible for the high Poisson's ratios used to simulate a soft seafloor, several strategies exist to treat this problem. Our example using multi‐component data showed some promise in mitigating the soft seafloor effect. However, this issue still remains open.     

Biodegradation of Crude Oil by Individual Bacterial Strains and a Mixed Bacterial Consortium Isolated from Hydrocarbon Contaminated Areas

A preliminary study was undertaken to determine the optimal conditions for the biodegradation of a crude oil. Among 57 oil‐degrading bacterial cultures isolated from oil‐contaminated soil samples, Bacillus sp. IOS1‐7, Corynebacterium sp. BPS2‐6, Pseudomonas sp. HPS2‐5, and Pseudomonas sp. BPS1‐8 were selected for the study based on the efficiency of crude oil utilization. Along with the selected individual strains, a mixed bacterial consortium prepared using the above strains was also used for degradation studies. The mixed bacterial consortium showed more growth and degradation than did individual strains. At 1% crude oil concentration, the mixed bacterial consortium degraded a maximum of 77% of the crude oil. This was followed by 69% by Pseudomonas sp. BPS1‐8, 64% by Bacillus sp. IOS1‐7, 45% by Pseudomonas sp. HPS2‐5, and 41% by Corynebacterium sp. BPS2‐6. The percentage of degradation by the mixed bacterial consortium decreased from 77 to 45% as the concentration of crude oil was increased from 1 to 12%. Temperature of 35°C and pH 7 were found to be optimum for maximum degradation.     

Reconstruction of historical nutrient levels in Korean and Japanese coastal areas based on dinoflagellate cyst assemblages

Dinoflagellate cysts acquired from sediment cores were analyzed in order to reconstruct historical nutrient levels in Gamak Bay, Korea and Ariake Bay, Japan. Dinoflagellate cyst assemblages in Gamak Bay were characterized by high proportions of heterotrophic cysts such as Brigantedinium spp., Protoperidinium americanum and Polykrikos cysts, which suggested that nutrients levels may have already been high before 1970s, and then increased further to the hypertrophic conditions of the 1990s. In contrast, dinoflagellate cyst assemblages in Ariake Bay were characterized by high relative abundances of Lingulodinium machaerophorum and Spiniferites spp., which suggested that nutrient levels in Ariake Bay had increased gradually since the mid 1960s, and may have been significantly enhanced by the mid 1980s. Dinoflagellate cyst assemblages reflecting environmental changes in the two bays are contrasting, perhaps due to different nutrient enrichment mechanisms. This suggests that the indicators of nutrient levels encoded in dinoflagellate cyst assemblages may exhibit site-specific information.     

Hydraulic Performance of the Horizontal Reactive Media Treatment Well: Pilot and Numerical Study

This study is focused on a passive treatment system known as the horizontal reactive treatment well (HRX Well®) installed parallel to groundwater flow, which operates on the principle of flow focusing that results from the hydraulic conductivity (K) ratio of the well and aquifer media. Passive flow and capture in the HRX Well are described by simplified equations adapted from Darcy's Law. A field pilot-scale study (PSS) and numerical simulations using a finite element method (FEM) were conducted to verify the HRX Well concept and test the validity of the HRX Well-simplified equations. The hydraulic performance results from both studies were observed to be within a close agreement to the simplified equations and their hydraulic capture width approximately five times greater than the well diameter (0.20 m). Key parameters affecting capture included the aquifer thickness, well diameter, and permeability ratio of the HRX Well treatment media and aquifer material. During pilot testing, the HRX Well captured 39% of flow while representing 0.5% of the test pit cross-sectional volume, indicating that the well captures a substantial amount of surrounding groundwater. While uncertainty in the aquifer and well properties (porosity, K, well losses), including the effects of boundary conditions, may have caused minor differences in the results, data from this study indicate that the simplified equations are valid for the conceptual design of a field study. A full-scale HRX Well was installed at Site SS003 at Vanderberg Air Force Base, California, in July/August 2018 based on outcomes from this study.